EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels APPENDIX 1: Category Justification Document Category Justification for Petroleum Substances Vacuum Gas Oils, Hydrocracked Gas Oils & Distillate Fuels Crude oil (Petroleum, CAS Registry Number (CAS RN) 8002-05-9) is a complex combination of hydrocarbons extracted in its natural state from the ground. It consists predominantly of aliphatic, alicyclic and aromatic hydrocarbons, but may also contain small amounts of nitrogen, oxygen and sulphur compounds. It is used as a feedstock for petroleum refining operations, which separates and converts it into fractions (streams). Petroleum refinery streams are used in a variety of applications, with the major proportion being used in the production of hydrocarbon transport fuels. Due to their method of production, and complex composition, it is not possible to characterise petroleum substances in terms of their exact chemical composition, molecular formula or structure. They are grouped together according to the process by which they are being manufactured and basic physical-chemical properties. Similar conversion and/or separation processes will result in streams of broadly similar composition. The resulting groups of petroleum substances have been used by the European Commission for the purposes of compiling Annex 1 to the Existing Substances Regulation (published in the Official Journal L84 on 5 April 1993), Annex XVII of REACH and Annex VI of CLP. The groups have also been used during discussions on EU harmonised classification and labelling and for some endpoints (particularly carcinogenicity) harmonised ‘group’ classifications have been applied to individual petroleum substances and are listed in both Annex 1 to 67/548/EC and Annex VI to CLP. In the USA, petroleum substances have also been grouped in categories for the purposes of the High Production Volume (HPV) Chemicals programme. The approach is broadly similar to that used in Europe, and has been accepted by the US EPA. This category justification has been prepared in accordance with the REACH Technical Guidance Document (May 2007) prepared under RIP 3.3. 1. Category Definition 1.1 Category Hypothesis and Applicability Domain This category, Vacuum Gas Oils, Hydrocracked Gas Oils & Distillate Fuels, covers a group (17) of petroleum gas oil substances used in the manufacture of distillate fuels (automotive diesel fuels, home heating oils, marine gas oils), petrochemical intermediates or gas oils used as components of formulated industrial lubricants and additives. They are not intentional mixtures of chemicals but are complex combinations of hydrocarbon species, produced to meet physical-chemical and technical performance specifications. The domain of this category is established by the refining processes by which the category members are produced and the boiling point and the carbon number range as follows: Derived from crude petroleum Refinery processes o Atmospheric distillation o Vacuum distillation o Hydrocracking o Blending of petroleum substances to produce the following CASRNs • 68334-30-5 Fuels, Diesel • 68476-30-2 Fuel Oil No. 2 • 68476-31-3 Fuel Oil No 4 • 68476-34-6 Fuels Diesel No 2 2010-07-30 CSR Appendix 1

Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels Hydrocarbon types: straight and branched alkanes and alkenes, cycloalkanes and cycloalkenes, aromatics and mixed aromatic cycloalkanes. Boiling point range: 141- 500 o C Carbon number range: predominantly C9 to C30 The category is formed on the principle that vacuum gas oil, hydrocracked gas oil and distillate fuel substances have similar physical-chemical and technical characteristics and present similar health, safety and environmental hazards. 1.2 Category Members This category is comprised of seventeen UVCB substances (substances of Unknown or Variable compositions, Complex reaction products and Biological materials), each with a unique CAS Registry Number (CAS RN); see Appendix 1. The EINECS definition includes, inter alia, reference to method of refining (distillation), boiling point and carbon number ranges, and in some cases, final processing step. Category members are produced in a refinery as petrochemical intermediates, used in the manufacture of automotive diesel fuels, home heating oils, marine gas oils and gas oils or used as components of formulated industrial lubricants or additives. In general the individual substances are all produced in quantities of greater than 1,000t/a. The members of this category are shown in Appendix 1, some of these members are listed in REACH Annex XVII, to which Nota N 1 have been applied. Included in the category are six petroleum substances for which the EINECS number is not accompanied with a description providing information on the carbon number range and/or the boiling range. In practice, however, these substances show carbon number ranges and boiling ranges similar to other members of the category and within the category domain definition. 1.3 Purity / Impurities From a regulatory perspective, the category members are recognised as UVCB substances derived from the refining of crude oil (petroleum). Such chemical substances cannot be represented by simple or unique chemical structures or molecular formulae. As such, they contain constituents but do not contain impurities. 1.4 Category Order The category described consists of UVCB substances and a category order is therefore not relevant 2. Category justification The Vacuum Gas Oils, Hydrocracked Gas Oils & Distillate Fuels substances in this category are all produced by distillation and processing of crude petroleum. They are all liquids of varying viscosity, and have low volatility. They are complex combinations of straight and branched alkanes and alkenes, cycloalkanes and cycloalkenes, aromatics and mixed aromatic cycloalkanes with carbon numbers ranging from C9 - C30, and boiling range of 141 - 500 o C. The complex and variable composition of UVCB substances means that it is not possible to define precisely their physical-chemical, toxicological and environmental properties, but they will fall into a range, defined by the properties, and amounts present, of the individual hydrocarbon constituents. To take account of the variable composition, hazard properties are determined using a ‘worst case’ approach, except where specified. Where data do not exist for vacuum gas oils, hydrocracked gas 1 i.e. The classification as a carcinogen need not apply if the full refining history is known and it can be shown that the substance from which it was produced is not a carcinogen. This Nota applies only to certain complex oil-derived substances in Annex 1. 2010-07-30 CSR Appendix 1

Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels<br />

<br />

<br />

<br />

Hydrocarbon types: straight and branched alkanes and alkenes, cycloalkanes and<br />

cycloalkenes, aromatics and mixed aromatic cycloalkanes.<br />

Boiling point range: 141- 500 o C<br />

Carbon number range: predominantly C9 to C30<br />

The category is formed on the principle that vacuum gas oil, hydrocracked gas oil and distillate fuel<br />

substances have similar physical-chemical and technical characteristics and present similar health,<br />

safety and environmental hazards.<br />

1.2 Category Members<br />

This category is comprised of seventeen UVCB substances (substances of Unknown or Variable<br />

compositions, Complex reaction products and Biological materials), each with a unique CAS Registry<br />

Number (CAS RN); see Appendix 1. The EINECS definition includes, inter alia, reference to method<br />

of refining (distillation), boiling point and carbon number ranges, and in some cases, final processing<br />

step. Category members are produced in a refinery as petrochemical intermediates, used in the<br />

manufacture of automotive diesel fuels, home heating oils, marine gas oils and gas oils or used as<br />

components of formulated industrial lubricants or additives. In general the individual substances are<br />

all produced in quantities of greater than 1,000t/a.<br />

The members of this category are shown in Appendix 1, some of these members are listed in REACH<br />

Annex XVII, to which Nota N 1 have been applied.<br />

Included in the category are six petroleum substances for which the EINECS number is not<br />

accompanied with a description providing information on the carbon number range and/or the boiling<br />

range. In practice, however, these substances show carbon number ranges and boiling ranges similar<br />

to other members of the category and within the category domain definition.<br />

1.3 Purity / Impurities<br />

From a regulatory perspective, the category members are recognised as UVCB substances derived<br />

from the refining of crude oil (petroleum). Such chemical substances cannot be represented by simple<br />

or unique chemical structures or molecular formulae. As such, they contain constituents but do not<br />

contain impurities.<br />

1.4 Category Order<br />

The category described consists of UVCB substances and a category order is therefore not relevant<br />

2. Category justification<br />

The Vacuum Gas Oils, Hydrocracked Gas Oils & Distillate Fuels substances in this category are all<br />

produced by distillation and processing of crude petroleum. They are all liquids of varying viscosity,<br />

and have low volatility. They are complex combinations of straight and branched alkanes and<br />

alkenes, cycloalkanes and cycloalkenes, aromatics and mixed aromatic cycloalkanes with carbon<br />

numbers ranging from C9 - C30, and boiling range of 141 - 500 o C.<br />

The complex and variable composition of UVCB substances means that it is not possible to define<br />

precisely their physical-chemical, toxicological and environmental properties, but they will fall into a<br />

range, defined by the properties, and amounts present, of the individual hydrocarbon constituents. To<br />

take account of the variable composition, hazard properties are determined using a ‘worst case’<br />

approach, except where specified. Where data do not exist for vacuum gas oils, hydrocracked gas<br />

1 i.e. The classification as a carcinogen need not apply if the full refining history is known and it can be<br />

shown that the substance from which it was produced is not a carcinogen. This Nota applies only to<br />

certain complex oil-derived substances in Annex 1.<br />

2010-07-30 CSR Appendix 1

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