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CORROSION RESISTANCE OF HASTEllOY®AllOYS - Haynes ...

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ISO<strong>CORROSION</strong> DIAGRAMS*<br />

HASTELLOY® Alloy G-30<br />

Resistance to Phosphoric Acid<br />

(<br />

Corrosion rates in parentheses are in mm/year.<br />

g Region of corrosion rate instability.<br />

(0.5)<br />

20 mpy 150<br />

(<br />

LL<br />

cj 250<br />

w<br />

o<br />

W<br />

0:<br />

~ 200<br />

«<br />

0:<br />

w<br />

Q...<br />

~<br />

~ 150<br />

Boiling Point Curve<br />

u<br />

cj<br />

w<br />

0<br />

W<br />

100 0:<br />

I-<br />

:::::><br />

«<br />

0:<br />

w<br />

Q...<br />

~<br />

w<br />

I-<br />

50<br />

100<br />

o<br />

10<br />

20<br />

30<br />

40<br />

50<br />

60<br />

70<br />

80<br />

CONCENTRATION, WEIGHT PERCENT<br />

Comparison of HASTELLOY®<br />

Alloy G-30 and Alloy 625<br />

in Commercial Phosphoric Acid*<br />

<strong>CORROSION</strong> RATE IN MM/YEAR<br />

0.25 2.5<br />

25<br />

250<br />

0 0<br />

10.0 6<br />

5.0<br />

a<br />

c;><br />

(')<br />

.......<br />

L{)<br />

C\J<br />

CD<br />

(f)<br />

I­<br />

W<br />

«<br />

.0:<br />

Z<br />

o<br />

(jj<br />

o<br />

0:<br />

0:<br />

o<br />

U<br />

LL<br />

o<br />

4.0 0 0<br />

cP6<br />

3.0 0<br />

00<br />

0<br />

2.0<br />

60<br />

Cb<br />

1.0<br />

OP 2 0 S<br />

t<br />

6 P 2 0 S + 2000 ppm CIo<br />

P 2 0 S + 0.5% HF<br />

o<br />

f=«0:<br />

1.0 10 100 1000 10,000<br />

0.8<br />

0.7<br />

<strong>CORROSION</strong> RATE <strong>OF</strong> ALLOY 625 (MPY)<br />

The corrosion resistance of HASTELLOY alloy G-30 in a variety of environments is shown in this<br />

charI. The corrosivity of commercial phosphoric acid is a result of several variables such as<br />

concentration, temperature, impurity levels (manufacturer) and origin of the phosphate rock. Wide<br />

variations in corrosion rates are possible in acids of the same concentration but from different<br />

sources. Hence, corrosion tests were conducted in acids from a number of suppliers and the<br />

performance of alloy G-30 relative to alloy 625 is shown as a function of the corrosion rate of alloy<br />

625. Within certain severity of the acid, alloy G-30 shows 2-3 times better corrosion resistance than<br />

alloy No. 625. In acids of high severity all the alloys exhibit corrosion rates in excess of 2.5mm/yr<br />

(100 mpy).<br />

•All test specimens were solution heat-treated and in the unwelded condition.<br />

73

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