CORROSION RESISTANCE OF HASTEllOY®AllOYS - Haynes ...

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Type 316 Concen- Temperature HASTEllOY8 alloy Staintration. less Corrosive Media percent deg. F deg. C 8/8-2 C/C-276 G/G-3 Steel Conditions Scrubbing liquors - 176 80 - E - E power plant flue gas scrubbing liquor. Recycled and makeup 190 gil Sulfur Dioxide citric acid, 80 gil Na2COJ, pH 4-5 Scrubbing liquors - 176 80 - E - E power plant flue gas scrubbing liquor. H2S sparged into citric acid, Sulfur Dioxide sodium carbonate plus absorbed S02 solution to ppt sulfur. pH 4_5 Scrubbing liquors - 190 88 - E - E boiler flue gas, 0-400 ppm S02, 10% water vapor, fly ash after limestone Sulfur Dioxide slurry scrubbing, moderate aeration Scrubbing liquors - 200 93 - E - E power plant flue gas scrubbing. Decanted scrubbing liquor after removal Sulfur Dioxide of sulfur and during removal of Na2S04 by·product by XTALZN. , .•. Scrubbing liquors - 235 113 - E - E power plant flue gas scrubbing. Molten sulfur phase Sulfur Dioxide Scrubbing liquors - 235 113 - E - E power plant flue gas scrubbing. Sulfur slurry phase of sulfur decanter Sulfur Dioxide containing 30-50% solids Scrubbing liquors - 235 113 - E - E power plant flue gas scrubbing. Citrate solution phase of sulfur decanter. Sulfur Dioxide (Dilute and impure sodium citrate) Scrubbing liquors - 370 188 - E - - flue gas from a metallurgical roaster, typical .02 grains/cu. ft. dust, S02 Sulfur Dioxide 1500 ppm, SOJ 750 ppm, CO2 .7% H20 1-3%, bal. air Scrubbed Power Plant - 115-125 46-52 - E E E containing droplets of dbl. alkali scrubbing liquor, aeration F1uegas Scrubbed Power Plant - 120 49 - E E E aeration Fluegas Scrubbed Power Plant - 122 50 - E - G containing 300-500 ppm S02 and 15% H20. Joy Hi liquid energy lime· Fluegas stone scrubbing process for S02 and fly ash removal Aeration - extensive Agitation - gas and .Iiquid flow Total days - 100 Scrubbed Power Plant - 135·145 57-63 - E E E dbl. alkali process, aeration Fluegas Scrubbed Power Plant - 160-165 71-74 - - E E saturated with H20 and S02, aeration Fluegas Scrubbing Power Plant - 176 80 - E E E vapor phase of 190 gil citric acid, 80 gil Na2COJ, solution for absorption Fluegas of S02' pH 4-5 Aeration - moderate Agitation - by gas flow Total days - 91 Scrubbing Power Plant - 176 80 - E E E S02 being absorbed into solution of 190 gil citric acid, 80 gil Na2COJ' pH Fluegas 4.0-5.0, moderate aeration Scrubbing Power Plant - 200 93 - E E E decanted scrubbing liquor after removal of sulfur and during removal of Fluegas Na2S04 by-product by XTALZN. Citrate process for sulfur dioxide removal (and sulfur recovery), 91 days Scrubbing Power Plant - 235 113 - E E E citrate solution phase of sulfur decanter, (dilute and impure sodium cit· Fluegas rate). Citrate process for sulfur dioxide removal (and sulfur recovery). 91 days Scrubbing Power Plant - 235 113 - E E E molten sulfur phase. Citrate process for sulfur dioxide removal (and Fluegas sulfur recovery), 91 days Scrubbing Power Plant - 235 113 - E E E sulfur slurry phase of sulfur decanter containing 30-50% solids. Citrate Fluegas process for sulfur dioxide removal (and sulfur recovery). 91 days Scrubbed Recovery - 165 74 - E - E N2,° 2 , water vapor, CO2, traces of CO, H2S. S02, methyl mercaptan plus Boiler, Fluegas slight liquor carryover. Scrubbing of recovery boiler flue gas firing kraft process black liquor Aeration - extensive Agitation - 10-12 fUsec. Total days - 67 Scrubber Fluegas, - 240 116 U E E E Aeration - extensive Incineration of Agitation - by gas flow Sewage Sludge Total days - 65.9 Scrubber liquor for - 165 74 - E - E 20.5 gil Na2COJ, 21.5 gil NaHCOJ, 3.1 gil chloride solids, 15% traces Recovery Boiler Fluegas Na2S20J' Scrubbing of recovery boiler flue gas firing kraft process black liquor Aeration - extensive Agitation - moderate·violent Total days - 67.0 - E - Less than 2 mpy (0.05 mm/y) G- 2 mpy (0.05 mmly) to 10 mpy (0.25 mm/y) S - Over 10 mpy (0.25 mmly) to 20 mpy (0.51 mm/y) B - Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mmly) U- More than 50 mpy (1.27 mmly) 44
Type 316 Concen- Temperature HASTEllOY~ alloy Staintration. less Corrosive Media percent deg. F deg. C 8/8-2 C/C-276 G/G-3 Steel Conditions Scrubber Liquor, - 120 49 - E E E gas from oil fired sodium sulfate flash drying steam. Liquor contains Sodium Sulfate dilute Na2S04, H2SO), pH 2-3, extensive aeration Scrubbed Municipal - 170 77 - E G G 90% water saturated, downstream of scrubber and demister. pH 3-4. Garbage Incinerator Municipal garbage incinerator flue gas scrubbing; agitation high, aeration Fluegas extensive; 51 days \ Scrubbed Power Plant - 143 63 - - E G gas 10% CO2, 13% O2, Bal N2(H 20 Satd). Fly ash carryover, pH below O. Fluegas &Condensate Scrubbing of S02 and fly ash from power plant flue gas. Aeration - extensive Agitation - 5-10 fUsee. Total days - 135.6 Scrubbing Solution & - 110-115 43-46 - E E E plus fly ash, aeration Quenched Boiler Stack Gas Scrubber Water - 155 68 S G E U defluorination system. HF solution 0.6% as F, 2000 ppm P20 S , 700 ppm S04, pH 3.0, 92 days Scrubber Water Effluent - 200 93 - E E E from prequench chamber of municipal refuse incinerator scrubber. pH about 1 Seawater Mixtures - 240 116 - E - E hydrogen sulfide gas with mist of de-aerated sea water Sea Water - 196 91 - E - - 5 months, flow rate - 5 gpm Sea Water and Diesel - Ambient Ambient - E - - containing chlorides, sodium, sulfur, carbon Fuel Exhaust Products Sebacic Acid 10 90 32 B E - - plus small amounts of H2S04, Na2S04 and K2S04 10 B.P. B.P. B E - - Sebacic Acid 10 90-220 32-104 S E - - plus 0.05-2 percent max. H2S04 and traces of Na2S04, K2S04, H2O balance_ Alloy C = 0.4 mpy Sebacic Acid (Crude) - 428 220 - E - - in still. Alloy C = 0.4 mpy Secondary Discharge - 170 77 - E E E municipal garbage incinerator flue gas from secondary chamber after Effluent passing through scrubber, marble bed plus entrained liquor at pH 3-4. Agitation moderate; aeration extensive, 51 days Secondary Discharge - 200 93 - E E E municipal refuse incinerator flue gas effluent after H20 scrubbing. En- Effluent vironment should be mainly steam with entrained impurities, extensive aeration Secondary Discharge - 300 149 - E E G municipal refuse incinerator water quenched flue gas, acid chloride en- Effluent vironment, pH range about 1.6, extensive aeration Separate Water Solutions - 55-104 13-40 B E E S 5-30% HCI, 10-40% H2S04, 10-25% HNO), 1-40% NaOH, 127 days, aeration and agitation moderate Sewage Gas - 85-95 29-35 E - - - moisture laden gas from anaerobic digestion of packing house waste. 63 percent CO2, 36 percent CH 4 and 1 percent H2S, pH =7.4 approx. Sewage, Raw - 240 116 - E - - avg. composition of brine: NH) 5 ppm, CI 100 ppm. B.O.D. 200 mg/I, and Processed moderate aeration, pH 6.0 Sewage (Scrubbed) - 100-160 38-71 E E E E aeration Sludge Incinerator Fluegas Sewage Sludge Incin- - 66-72 19·22 G E E E sewage sludge incinerator flue gas being scrubbed by once thru water era tor Fluegas E E E E plant effluent water, aeration Sewage Sludge Incin- - 100-210 38·99 E E E E sewage sludge incinerator flue gas being scrubbed by once thru water erator Fluegas E E E E plant effluent water, aeration Sewage Sludge Incin- - 150 66 - E - E extensive aeration era tor Fluegas and Scrubbing Liquor Sewage Sludge Incin- - 190-220 88-104 E E E E sewage sludge incinerator flue gas being scrubbed by once thru water era tor Fluegas E E E E plant effluent water, aeration Silica, Acidified - 700-900 371-482 E E - - in deacidification of silica by rotary kiln. Alloy C = 0.04 mpy Silicon Tetrachloride 100 140 60 E E - - with dry HCI and CI2bubbled through. In production of high purity silica of pigment. Alloy C=0.1 mpy Silicon Tetrafluoride - 113 45 - G - G acid spray of droplets containing phosphoric acid, hydrofluosilicic acid, phosphate rock dust, water. E - less than 2 mpy (0.05 mm/y) G- 2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y) S - Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y) B - Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y) U - More than 50 mpy (1.27 mm/y) B.P. - Boiling POint 45
Page 1 and 2: OUR NEW NAME Haynes International,
Page 3 and 4: COMPARATIVE CHEMICAL COMPOSITIONS,
Page 5 and 6: 'A~0~A~~ Alloy / q,~ "'.>~~~Cfj 0.5
Page 7 and 8: Type 316 Concen- Temperature HASTEL
Page 9 and 10: Type 316 Concen- Temperature HASTEl
Page 43: Type 316 Coneen- Temperature HASTEl
Page 61 and 62: ( Type 316 Concen- Temperature HAST
Page 63 and 64: ISOCORROSION DIAGRAMS· HASTELLOY®
Page 65 and 66: ISOCORROSION DIAGRAMS* HASTELLOY®
Page 69 and 70: ISOCORROSION DIAGRAMS· r HASTELLOY
Page 71 and 72: PHOSPHORIC ACID ISOCORROSION DIAGRA
Page 75 and 76: ISOCORROSION DIAGRAMS· HASTELLOY®
Page 79 and 80: ACETIC AND FORMIC ACIDS Acetic and
Page 81 and 82: EFFECT OF TEMPERATURE ON PITTING RE
Page 83 and 84: CREVICE-CORROSION DATA IN 10% FERRI
Page 85 and 86: CORROSION RESISTANCE OF HAYNES® AL
Page 87 and 88: TYPICAL PENETRATION RATES IN CORROS

CORROSION RESISTANCE OF HASTEllOY®AllOYS - Haynes ...

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