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<strong>AU</strong> J.T. 10(1): 29-37 (Jul. 2006)<br />

<strong>Environmental</strong> <strong>Pollution</strong> -Especially Air <strong>Pollution</strong> - <strong>and</strong> <strong>Public</strong> Health<br />

Sr. Little Flower<br />

Department of General Education, Faculty of Arts, Assumption University<br />

Bangkok, Thail<strong>and</strong><br />

Abstract<br />

<strong>Pollution</strong> is a necessary evil of all development. It is an undesirable change in the<br />

physical, chemical or biological characteristics of air, water <strong>and</strong> soil that may harmfully<br />

affect the life or create a potential <strong>health</strong> hazard of any living organism <strong>and</strong> in<br />

particular for man. Industrialized countries of the world release in to the atmosphere<br />

pesticides, detergents, plastics, solvents, fuels, paints, dyes, food additives etc. are some<br />

of the examples. Besides these there are a number of industrial effluents emissions of<br />

poisonous gases in the atmosphere. Mining activities also added to this problem,<br />

particularly as solid waste. The unfavorable conditions created by man himself<br />

threatened the survival not only of man himself but also other living organisms.<br />

Keywords: Pollutant, poisonous gases, industrial effluents, atmosphere, global<br />

warming, environment, green house effect, natural resource, chemicals.<br />

Environment on 14 June 1972 in Stockholm,<br />

Introduction<br />

Sweden, the late Prime Minister of India, Indira<br />

The ‘mad rat race’ among nations over<br />

the globe for development jeopardized the<br />

heath of man itself. Progress in agriculture <strong>and</strong><br />

industry is taken a general criterion of<br />

development of any country. This craze<br />

resulted into unlimited exploitation of every bit<br />

of natural resource. Such activities of man had<br />

adverse effect on all forms of living organisms<br />

in the biosphere. Unlimited exploitation of<br />

nature by man disturbed the ecological balance<br />

between living <strong>and</strong> non living component of<br />

the biosphere. Due to lack of development of a<br />

culture of pollution control, there has resulted a<br />

heavy backlog of gaseous, liquid <strong>and</strong> solid<br />

pollution in all over the world. It is to be<br />

cleaned. Thus pollution control is a recent<br />

environmental concern.<br />

The developed countries have been in a<br />

mad race to exploit every bit of natural<br />

resource to convert them into goods for their<br />

comfort, <strong>and</strong> to export them to needy<br />

developing world. In doing so, the<br />

industrialized countries dump lot of materials<br />

in their environment which become polluted.<br />

In a way, pollution has been ‘exported’<br />

to developing countries. UN Conference on<br />

G<strong>and</strong>hi had said, “Modern man must re-establish<br />

an unbroken link with nature <strong>and</strong> with life. He<br />

must again learn to invoke the energy for growing<br />

things <strong>and</strong> to recognize, as did the ancients<br />

in India centuries ago, that one can take from<br />

the earth <strong>and</strong> the atmosphere only so much as<br />

one put back in the them” (Sharma1998).<br />

<strong>Pollution</strong> is an undesirable change in the<br />

physical, chemical or biological characteristics<br />

of air, water <strong>and</strong> soil that may harmfully affect<br />

the life or create a potential <strong>health</strong> hazard of<br />

any living organism <strong>and</strong> in particular for man.<br />

What are pollutants? Any substance that<br />

caused pollution is called a pollutant. A<br />

pollutant may thus include any chemical or<br />

agrochemical substance, biotic component or<br />

its products or physical factor (heat) that is<br />

released by man into the environment, that may<br />

have adverse harmful or unpleasant effects. A<br />

pollutant has also been defined as any solid,<br />

liquid, or gaseous substance present in such<br />

concentration as may be or tend to be injurious<br />

to the environment”. Pollutants are the<br />

residues of things we make, use <strong>and</strong> throw<br />

away. There are many sources of such<br />

pollutants. The lake <strong>and</strong> rivers are polluted by<br />

wastes from chemical <strong>and</strong> other factories,


waste from human <strong>and</strong> the air by gases of<br />

automobile exhausts, industries, thermal power<br />

plants, etc.<br />

Air <strong>Pollution</strong><br />

The atmosphere is an insulating blanket<br />

around the earth. It is source of essential gases,<br />

maintains a narrow difference of day <strong>and</strong> night<br />

temperatures <strong>and</strong> provides a medium for long<br />

distance radio communication. It also acts as<br />

shield around the earth against lethal UV<br />

radiations. With out atmosphere, there will be<br />

no lightening, no wind, no clouds, no rains, no<br />

snow <strong>and</strong> no fire.<br />

Sources <strong>and</strong> Pollutants<br />

Air pollution results mainly from<br />

gaseous emissions of industry thermal power<br />

stations, automobiles, domestic combustions,<br />

smoke from the fire etc. From the different<br />

sources of air pollution, a variety of pollutants<br />

are released in to atmosphere. The main air<br />

pollutants emitted from these different sources<br />

<strong>and</strong> how these pollutants affect the human <strong>and</strong><br />

other living organisms on the planet are<br />

described:<br />

1. Carbon compounds: These are CO 2 <strong>and</strong><br />

Co, the former is released by complete<br />

combustion of fossil fuels, <strong>and</strong> the latter<br />

by automobile exhausts.<br />

2. Sulfur compounds: These include SO 2 ,<br />

HS <strong>and</strong> H 2 SO 4 mostly released by fossilfuel-based<br />

power generating plants,<br />

thermal plants, <strong>and</strong> refineries.<br />

3. Nitrogen oxides: These include NO, NO 2 ,<br />

HNO 3 mostly released by automobiles,<br />

power plants <strong>and</strong> industries.<br />

4. Ozone: Its level may rise in astrosphere<br />

due to human activities.<br />

5. Fluorides: These come from industries,<br />

insecticides spray etc.<br />

6. Hydrocarbons: These are chiefly benzene,<br />

benz pyrene etc which are released by<br />

automobiles <strong>and</strong> industries.<br />

7. Metals: These include lead, nickel arsenic,<br />

beryllium, tin, vanadium, titanium,<br />

cadmium, etc. present in the air as solid<br />

particles or liquid droplets or gases. They<br />

are produced mostly by metallurgical<br />

processes, automobiles, sea spray, etc.<br />

8. Photochemical products: These are<br />

photochemical smog, PAN, PB 2 N, etc.<br />

released by automobiles.<br />

9. Particulate matter: These are fly ash,<br />

dust, grit <strong>and</strong> other suspended particulate<br />

matter released from power plants <strong>and</strong><br />

industries (stone crushers)<br />

10. Biological particulate matters: Bacterial<br />

cells, fungal spores <strong>and</strong> pollens in air.<br />

11. Toxicants other than heavy metals: These<br />

are complex chemical substances released<br />

during manufacture of other goods.<br />

Carbon Compounds<br />

The two important pollutants are CO 2 <strong>and</strong> CO.<br />

Carbon Dioxide (CO 2 ): Major amount of<br />

CO 2 is released in the atmosphere from burning<br />

of fossil fuel (coal, oil, etc.) for domestic<br />

cooking, heating, etc. <strong>and</strong> the fuel consumed in<br />

furnaces of power plants, industries, hot mix<br />

plants, etc. Another reason is the destruction of<br />

the forest in the tropical regions of the world.<br />

These ecosystems are efficient in removing<br />

CO 2 <strong>and</strong> storing the C atoms in the structure of<br />

the plant. From fossil fuels alone more than 18<br />

x 10 2 ton of CO 2 are being released into<br />

atmosphere each year. This gas is also emitted<br />

during volcanic eruptions. An increase in CO 2<br />

concentration in atmosphere may result into<br />

disastrous effects as green house effect.<br />

Greenhouse Effect <strong>and</strong> Global Warming:<br />

Since CO 2 is confined exclusively to the<br />

troposphere, its higher concentration may act a<br />

serious pollutant. Under normal conditions the<br />

temperature at the surface of the earth is<br />

maintained by the energy balance of the sun<br />

rays that strike the planet <strong>and</strong> heat that is<br />

reradiated back in to space. However, when<br />

there is an increase in CO 2 concentration, the<br />

thick layer of this gas prevents the heat from<br />

being reradiated out. This thick CO 2 layer thus<br />

functions like the glass panels of a greenhouse<br />

(or the glass windows of a motorcar), allowing<br />

the sunlight to filter through but preventing the<br />

heat from being radiated in outer space. This is<br />

the so-called Greenhouse Effect.<br />

30


Thus, most heat is absorbed by CO 2 layer<br />

<strong>and</strong> water vapor in the atmosphere, which adds<br />

to the heat that is already present. The net<br />

result is the heating up of the earth’s<br />

atmosphere. Thus increasing CO 2 levels tends<br />

to warm the air in the lower layers of<br />

atmosphere on a global scale. Nearly 100 years<br />

age the CO 2 level was 275 ppm. Today it is<br />

350 ppm <strong>and</strong> by the year 2035 <strong>and</strong> 2040 it is<br />

expected to reach 450 ppm. CO 2 increases the<br />

earth temperature by 50% while CFCs are<br />

responsible for another 20% increase. There<br />

are enough (CFCs up there to last 120 years)<br />

(Sharma 1999).<br />

The excess CO 2 to some extent is<br />

absorbed by the oceans. But with the<br />

industrialization of the west <strong>and</strong> increased<br />

consumption of energy, CO 2 was released in to<br />

the atmosphere at a faster rate than the capacity<br />

of oceans to absorb it. Thus its concentration<br />

increased. There are other gases also which<br />

contributed to green house effect. These are<br />

SO 2 , NOx, CFCs discharged by industry <strong>and</strong><br />

agriculture. CFCs were widely used as<br />

refrigerant gases in refrigeration’s <strong>and</strong> air<br />

conditioners. There is a strong correlation<br />

between the increase in temperature <strong>and</strong> the<br />

amount of green house gases.<br />

According to one projection, changes<br />

will be the least in the tropics, <strong>and</strong> the most at<br />

the poles. So Greenl<strong>and</strong>, Icel<strong>and</strong>, Norway,<br />

Sweden, Finl<strong>and</strong>, Siberia <strong>and</strong> Alaska will be<br />

among the most affected. The polar icecaps<br />

would melt. The floating Western Antarctica<br />

ice sheet could begin to melt. A rise of five<br />

degrees would raise the sea level by five meters<br />

within a few decades, threatening all the<br />

densely populated coastal cities from Shanghai<br />

to San Francisco.<br />

According to an estimate, if all the ice on<br />

earth should melt 200 feet of water would be<br />

added to surface of all oceans, <strong>and</strong> low lying<br />

coastal cities as Bangkok <strong>and</strong> Venice Would be<br />

inundated. Due to green house effect, there<br />

may occur more hurricanes <strong>and</strong> Ceylonese <strong>and</strong><br />

early snow melts in mountains causing more<br />

floods during monsoon.<br />

During the 1980s, scientists, governments,<br />

<strong>and</strong> the public became concerned about the<br />

possibility that the world may be getting<br />

warmer. UNEP, for exmple, established the<br />

Inter-governmental Panel on Climate Change<br />

(IPCC) to study the issue <strong>and</strong> make<br />

recommendations. Its first assessment was<br />

published in 1990. In 1996, the IPCC<br />

published its second assessment <strong>and</strong> concluded<br />

that climate change is occurring <strong>and</strong> that it is<br />

highly probable that human activity is an<br />

important cause of the change. The UNEP had<br />

appropriately chosen the slogan “Global<br />

Warming” to alter the people on World<br />

Environment Day - June 5, 1989. The<br />

problem is that most vulnerable areas in the<br />

developing world do not have economic<br />

resources. The hardest hit may be developing<br />

world, which discharge two fifths the of the<br />

global carbon emissions each year. The effect<br />

of global warming will be worsening human<br />

<strong>health</strong>, rising sea level, disruptive of water<br />

cycle, changing forest <strong>and</strong> natural areas <strong>and</strong><br />

challenges to agriculture <strong>and</strong> food supply<br />

(Smith 2000).<br />

Carbon Monoxide (CO): The chief source<br />

are automobiles, though other involving a<br />

combustion process as stoves, furnaces, open<br />

fires, forest <strong>and</strong> bush fires, burning coal mines,<br />

factories, power plants etc also give off co.<br />

The principal source of this pollutant is the<br />

exhaust product from motor vehicles in<br />

common busy routes. Natural sources of this<br />

gas are various plants <strong>and</strong> animals. Higher<br />

animals produce some CO from hemoglobin<br />

break down. Some CO is also liberated from<br />

bile Juice. Break down of photosynthetic<br />

pigments in algae also release some CO. The<br />

smoke of automobiles <strong>and</strong> thermal power <strong>and</strong><br />

hot mix plants, stone crushers etc also<br />

contribute to CO. level in air.<br />

In the USA in 1965, 66 million tons of<br />

CO. was emitted by automobile exhaust,<br />

roughly 91% of this gas from all sources. In<br />

Los Angels in 1971, the CO. emission from<br />

automobiles was 8,960 tons daily <strong>and</strong><br />

comprised 98% of CO. from all sources. In the<br />

air, its concentration is from traces to 0.5 ppm<br />

(Sharma1999)<br />

CO is harmful to those persons exposed<br />

to congested high ways. Thus drivers are the<br />

most affected people. CO causes difficulty in<br />

breathing, causes headache, <strong>and</strong> irritation -1 of<br />

mucous membranes. It combines with<br />

hemoglobin of blood, reducing its O 2 –<br />

31


carrying capacity. (cigarette smokers have<br />

increased hematocrit (per cent volume of red<br />

blood cells), Within minutes of smoking. In<br />

developed countries cigarettes are linked to at<br />

least 80% of all death from lung cancer.<br />

Sulfur Dioxide<br />

The major source of SO 2 emission is<br />

burning of fossil fuels in thermal Power plants,<br />

smelting industries, <strong>and</strong> other process as<br />

manufacture of sulfuric acid <strong>and</strong> fertilizers.<br />

These account for about 75% of the total SO 2<br />

emission. The rest 25% emission is from<br />

automobiles <strong>and</strong> petroleum refineries. In<br />

U.S.A in 1970 there was emitted 37 million<br />

tons of SO 2 , which is likely to go up to 95<br />

million tons by 1990. It is believed that about<br />

10 9 million tons SO 2 are added each year in to<br />

the global environment.<br />

SO 2 causes intense irritation to eyes <strong>and</strong><br />

respiratory tract. It is absorbed in the moist<br />

passage of upper respiratory tract, leading to<br />

swelling <strong>and</strong> stimulated mucus secretion.<br />

This gas causes damage to higher plants,<br />

forming necrotic areas on leaf. In most plants<br />

leaf are collapses under intense exposure to<br />

SO 2 . SO 2 is also involved in the erosion of<br />

building materials as limestone Marble, the<br />

slate use in roofing, mortar <strong>and</strong> deterioration of<br />

statues. Petroleum refineries, Smelters, Kraft<br />

paper mills deteriorate the adjoining historic<br />

movements.<br />

Hydrogen Sulphide<br />

The chief source of H 2 S is decaying<br />

vegetation <strong>and</strong> animal matter, especially in<br />

aquatic habitats. Sulfur springs, volcanic<br />

eruptions, coal pits <strong>and</strong> sewers also give of this<br />

gas. About 30 million tons of H 2 S every year<br />

is released by oceans <strong>and</strong> 60 to 80 million tons<br />

per year by l<strong>and</strong>. Industries emit 3 million ton<br />

5 every year. The chief industrial sources of<br />

H 2 S are, users of sulfur containing fuels.<br />

At low concentration H 2 S causes<br />

headaches, nausea, collapse, coma <strong>and</strong> final<br />

death. Un pleasant odor may destroy the appetite<br />

at 5 ppm level in some people. A concentration<br />

of 150 ppm may cause conjunctivitis <strong>and</strong><br />

irritation of mucus membranes. This gas<br />

readily passes through alveolar membrane of<br />

the lung <strong>and</strong> penetrates the blood stream. Death<br />

occurs due to respiratory failures.<br />

Nitrogen Oxides (NO x )<br />

Even in unpolluted atmosphere, there are<br />

present measurable amounts of nitrous oxide,<br />

nitric oxide <strong>and</strong> nitrogen dioxide. Of these,<br />

nitric oxide (NO) is the pivot compound. It is<br />

produced by combustion of O 2 <strong>and</strong> N 2 during<br />

lightning discharges <strong>and</strong> by bacterial oxidation<br />

of NH 3 to form poisonous NO 2 . NO 2 may react<br />

with water vapor in air to form HNO 3 . This<br />

acid combines with NH 3 to form ammonium<br />

nitrate. About 95% of the NO x is emitted as<br />

NO <strong>and</strong> remaining 5% as NO 2 . In metropolitan<br />

cities, vehicular exhaust is the most important<br />

source of nitrogen oxides.<br />

Nitrous Oxide (N 2 O): This gas has so far<br />

not been implicated in air pollution.<br />

Nitric Oxide (NO): The chief source of this<br />

gas is the industries manufacturing HNO 3 <strong>and</strong><br />

other chemicals, <strong>and</strong> the automobile exhausts.<br />

Nitric oxide, is responsible for several<br />

photochemical reactions in the atmosphere, in<br />

the formation of pollutants like PAN, O 3 ,<br />

carbonyl compounds etc. in the presence of<br />

other organic substances. There is little<br />

evidence o the direct role of this gas is causing<br />

a <strong>health</strong> hazard, at the levels found in urban air.<br />

Nitrogen Dioxide (NO 2 ): A deep reddish<br />

brown gas, which is the only widely prevalent<br />

colored pollutant gas. This gas is the chief<br />

constituent of photo chemical smog. NO 2<br />

causes irritation of alveoli, leading to<br />

symptoms resembling emphysema. Lung<br />

inflammation may be followed by edema <strong>and</strong><br />

final death.<br />

Acid Rains<br />

Oxides of sulfur <strong>and</strong> nitrogen are<br />

important gaseous pollutants of air. These<br />

oxides can travel thous<strong>and</strong>s of Kilometers in<br />

the atmosphere. They stay in the atmosphere<br />

<strong>and</strong> are to be oxidized in to acids. Sulfuric <strong>and</strong><br />

Nitric acids are the main acids, which dissolve<br />

in the water in the atmosphere <strong>and</strong> fall to the<br />

32


ground as acid rain or may remain in the<br />

atmosphere in clouds <strong>and</strong> fogs.<br />

The acid rain problem has increased due<br />

to industrialization. Burning of fossil fuels for<br />

power generation contributes to almost 60 –<br />

70% of total SO 2 emitted globally. Emission<br />

of NO x from human activity ranges between 20<br />

- 90 million tons annually over the globe.<br />

Acid rains are a great threat to British<br />

environment as to central Europe <strong>and</strong> Southern<br />

Sc<strong>and</strong>inavia. In 1974 acid rains over Scotl<strong>and</strong><br />

were found to be sourer than vinegar (pH 2.4).<br />

Much of the falling snow in Britain is now<br />

highly acidic.(Smith 2000) If it does not melt<br />

it may turn in to a pollution time bomb. Heavy<br />

winds pick up acid rain from factories in<br />

Britain <strong>and</strong> Frances to Sweden. Ninety percent<br />

of acid rains of Norway <strong>and</strong> 75% of Sweden<br />

are due to drifted acid rain oxides. It is a major<br />

political issue.<br />

Acid rains create complex problems <strong>and</strong><br />

their impacts are far reaching. They increase<br />

soil acidity, this affecting l<strong>and</strong> flora <strong>and</strong> fauna;<br />

cause acidification of lakes <strong>and</strong> streams thus<br />

affecting aquatic life, affects crop productivity<br />

<strong>and</strong> human <strong>health</strong>. Besides these they also<br />

corrode buildings, monuments, bridges, fences,<br />

railing, etc.<br />

Ozone (O 3 )<br />

Ozone layer in the stratosphere protects<br />

us from the harmful UV radiation from Sun.<br />

The depletion of this O 3 layer by human<br />

activities may have serious implications <strong>and</strong><br />

this has become a subject of much concern<br />

over the last few years. Ozone is also formed<br />

in the atmosphere through chemical reactions.<br />

The atmospheric ozone is now being regarded<br />

as potential danger to human <strong>health</strong> <strong>and</strong> crop<br />

growth.<br />

The ozone layer has two important <strong>and</strong><br />

interrelated effects. It absorbs UV light <strong>and</strong><br />

thus protects all life on earth from harmful<br />

effects of radiation. By absorbing the UV<br />

radiation the ozone layer heats the stratosphere,<br />

causing temperature inversion. It limits the<br />

vertical mixing of pollutants, there by causing<br />

the dispersal of pollutants over large areas <strong>and</strong><br />

near the earth’s surface. That is why a thick<br />

cloud of pollutants hangs over the atmosphere<br />

33<br />

in industrialized areas causing several un<br />

pleasant effects. The stratosphere could be<br />

regarded as a sink, but unfortunately, these<br />

pollutants (CFC s ) react with the ozone <strong>and</strong><br />

deplete it.<br />

The ozone near the earth’s surface in the<br />

troposphere creates pollution problems. Ozone<br />

<strong>and</strong> peroxy acetyl nitrate (PAN) <strong>and</strong> hydrogen<br />

peroxide are formed by the reaction between<br />

NO 2 <strong>and</strong> hydro carbon in sunlight. These<br />

pollutants cause photo chemical smog. Higher<br />

levels of O 3 in the atmosphere protect us, <strong>and</strong> is<br />

harmful when it comes in direct contact with us<br />

<strong>and</strong> plants at earth’s surface.<br />

Any depletion of ozone, have catastrophic<br />

effects on life systems of the earth. Major<br />

pollutants responsible for this depletion are<br />

chlorofluoro carbons, nitrogen oxides <strong>and</strong><br />

hydrocarbons. CFC s are used as coolants in air<br />

conditioners <strong>and</strong> refrigerators, cleaning<br />

solvents, aerosol propellants <strong>and</strong> in foam<br />

insulation. They escape as aerosol in the<br />

stratosphere. The threat to O 3 is mainly from<br />

CFCs. Depletion of O 3 cause temperature<br />

changes on the earth.<br />

Cancer is the best established threat to<br />

man, especially relating to skin like melanoma.<br />

The other disorders are cataracts, destruction of<br />

aquatic life <strong>and</strong> vegetation <strong>and</strong> loss of<br />

immunity. Nearly 6,000 people die of such<br />

cancers in USA each year.<br />

There are also indirect effects. If the<br />

plants exposed the UV radiation showed<br />

reduction in chlorophyll content, reduction in<br />

growth <strong>and</strong> increase in harmful mutations.<br />

Global efforts: The first global conference<br />

on the depletion of ozone layer was held in<br />

Vienna (Austria) in 1985, the year, scientists<br />

discovered hole in south pole. British team<br />

discovered a hole in ozone layer as large as that<br />

of the United States. This was followed by<br />

Montreal Protocol in 1987 which called for a<br />

50% cut in the use of CFC s by 1998 reducing<br />

to the level of 1986, 95% of CFCs is released<br />

by European countries, USA, USSR, <strong>and</strong><br />

Japan. The three-day international “Saving the<br />

ozone layer” conference was organized jointly<br />

in London in March 1989 by the British<br />

government <strong>and</strong> the UNEP.<br />

There was another international<br />

conference on ozone at Helsinki in may 1989


to revise the Montreal Protocol. As many as 80<br />

nations agreed to have a total ban on chemicals<br />

that cause ozone depletion by 2,000 A.D. The<br />

agreement for CFC elimination by 2,000 AD is<br />

needed as a major step towards environmental<br />

protection(.P.D.Sharma1999)<br />

Fluorides<br />

Fluorides in atmosphere come from<br />

industrial process of phosphate fertilizers,<br />

ceramics, aluminum, fluorinated hydrocarbons,<br />

uranium <strong>and</strong> other metals. The pollutant is in<br />

gaseous or particulate state. In air fluoride<br />

chiefly comes from smoke of industries,<br />

volcanic eruptions, <strong>and</strong> insecticide sprays. In<br />

plants it causes tip burn. Fluoride pollution in<br />

man <strong>and</strong> animals is mainly through water. In<br />

minute amounts, fluorides are beneficial<br />

helping prevention of tooth-decay in man.<br />

However, higher levels become toxic.<br />

Hydrocarbons<br />

Among the hydrocarbons the chief air<br />

pollutants are benzene, benzepyrene, <strong>and</strong><br />

methane. The Motor vehicles are their chief<br />

source. These are emitted by evaporation of<br />

gasoline through carburetors, crankcase etc.<br />

They have carcinogenic effects on lung.<br />

They combine with NOx under UV component<br />

of light to form other pollutants like PAN <strong>and</strong><br />

O 3 which cause irritation of eye, nose, throat<br />

<strong>and</strong> respiratory distress.<br />

Benzene<br />

It is a liquid pollutant emitted from<br />

gasoline. It causes lung cancer. Benzepyrene is<br />

most potent cancer inducing hydrocarbon<br />

pollutant. It is also present in small amounts in<br />

smoke, tobacco, charcoal boiled stakes <strong>and</strong><br />

gasoline exhaust.<br />

Methane<br />

concentration may cause explosions. At high<br />

levels in absence of oxygen, methane may be<br />

narcotic on man.<br />

Metals<br />

In air, the common metals present are<br />

mercury, lead, zinc <strong>and</strong> cadmium. They are<br />

released from industries <strong>and</strong> human activities<br />

in the atmosphere.<br />

Mercury: Mercury is a liquid volatile metal<br />

(found in rock <strong>and</strong> soil) is present in air, as a<br />

result of human activities. Human use mercury<br />

compounds in production of fungicides, paints,<br />

cosmetics, paper pulp etc. By inhalation<br />

nervous system, liver, eyes are damaged.<br />

Infant may be deformed. Other symptoms are<br />

headache, fatigue, anxiety, loss of appetite etc.<br />

Lead: Lead is added to gasoline to reduce<br />

Knocking are emitted in to the air with the<br />

exhaust as volatile lead halides (bromides &<br />

chloride) About 75% of lead burnt in gasoline<br />

comes out as lead halides through tail pipe in<br />

exhaust gases. Of this 40% settles an the<br />

ground 60% gels in to air. Lead inhalation<br />

causes reduced hemoglobin formation, thus<br />

leading to anemia. It also damage RBCs<br />

resulting in infections of liver & kidney in<br />

man.<br />

Zinc: Zinc in air occurs mostly as white zinc<br />

oxide fumes & is toxic to man.<br />

Cadmium: It occurs in air due to industries.<br />

Industries engage in extraction, refining,<br />

electroplating <strong>and</strong> welding of cadmium<br />

containing materials <strong>and</strong> refining of copper,<br />

lead <strong>and</strong> zinc are the major source of cadmium<br />

in air. This metal is emitted as vapor, it<br />

quickly reacts to form oxide, sulfate, or<br />

chloride compounds. It is poisonous <strong>and</strong><br />

accumulates in human liver <strong>and</strong> kidney. It<br />

causes hypertension, emphysema <strong>and</strong> kidney<br />

damage.<br />

Photochemical Products<br />

Methane is a gaseous pollutant, in<br />

minute quantity in air. In nature it is produced<br />

during decay of garbage, aquatic vegetation<br />

etc. This is also released due to burning of<br />

natural gas <strong>and</strong> from factories. Higher<br />

34<br />

NOx, hydrocarbons <strong>and</strong> O 3 in the<br />

atmosphere are air pollutants. These may react<br />

with each other the presence of sunlight,<br />

producing secondary pollutants in the air. The<br />

main photochemical products are olefins,


aldehydes, ozone, PAN, PB 2 N <strong>and</strong><br />

photochemical smog.<br />

Olefines: Olefines are produced directly<br />

from exhaust <strong>and</strong> in the atmosphere from<br />

ethylene. They affect plants, especially they<br />

wither sepals of orchid flowers, retard the<br />

opening of carnation flowers & also high level<br />

retard the growth of tomatoes.<br />

Among the photochemical products,<br />

benzepyrene, PAN, <strong>and</strong> peroxy benzoil nitrate<br />

(PB 2 N) are the most potent pollutants.<br />

Benzepyrene is carcinogenic. PAN is an eye<br />

irritant. PAN <strong>and</strong> O 3 cause respiratory distress.<br />

Photochemical Smog: It is produced as<br />

a result of photochemical reaction among NO x ,<br />

hydrocarbons <strong>and</strong> oxygen. Photochemical<br />

smog formation occurred only during night or<br />

cloudy days. Smog is formed by the<br />

combination of smoke <strong>and</strong> Fog which<br />

characterized air pollution episode in<br />

London, Glasgow, Manchester <strong>and</strong> other<br />

cities of U.K where sulfur rich coal was used.<br />

The U.K smog was a mixture of reducing<br />

pollutants <strong>and</strong> has been called reducing smog,<br />

where as Los Angeles smog a mixture of<br />

oxidizing pollutants is called oxidizing smog<br />

which is produced as a result of pollution by<br />

domestic fires <strong>and</strong> exhaust from motor<br />

vehicles.<br />

Photochemical smog adversely affects<br />

plants, human <strong>health</strong> <strong>and</strong> Materials. The<br />

oxidants enter as part of inhaled air, interfere<br />

with respiratory process causing asthma <strong>and</strong><br />

bronchitis in epidemic form. Another serious<br />

disease is emphysema.<br />

The smoke, fog, mist, dust, soot etc in<br />

the smog reduce the visibility, damage crop,<br />

<strong>and</strong> cause corrosion of metals, stones, building<br />

materials, painted surfaces, paper, leather etc.<br />

Particulate Matter: This is a discrete mass<br />

of any material, except pure water, that exist as<br />

solid or liquid in atmosphere <strong>and</strong> of<br />

microscopic or submicroscopic dimensions. It<br />

arises in atmosphere from natural as well as<br />

man made sources. Natural sources are soil<br />

<strong>and</strong> rock debris (dust) volcanic emission, forest<br />

fires <strong>and</strong> reaction between natural gas<br />

emissions.<br />

Human activities are industrial<br />

operations (mining, smelting, polishing,<br />

35<br />

textiles, pesticides, fertilizers <strong>and</strong> chemical<br />

production), industrial fugitive process<br />

(loading <strong>and</strong> transfer operations) non industrial<br />

fugitive process (road way dust, agricultural<br />

operations, construction, fire etc.) vehicles<br />

exhaust, clutch <strong>and</strong> break wear.<br />

Particulate matter is injurious to <strong>health</strong>.<br />

Soot, lead particles, asbestos, flash, volcanic<br />

emission, pesticides, H 2 SO 4 mist, metallic dust,<br />

cotton <strong>and</strong> cement dust, etc. when inhaled by<br />

man cause respiratory diseases such as<br />

tuberculosis <strong>and</strong> cancer.<br />

In addition there are many kinds of<br />

biological particulate matter that suspended in<br />

atmosphere. These are bacterial cells, spores,<br />

pollen grains, <strong>and</strong> fungal spores. These cause<br />

allergy, bronchial disorders <strong>and</strong> any other<br />

diseases in man animals & plants.<br />

Hazardous <strong>and</strong> Toxic Substances<br />

Hazardous substances are those that can<br />

cause harm to humans or the environment. The<br />

U.S. <strong>Environmental</strong> protection Agency (EPA)<br />

defines hazardous materials have one or more<br />

of the following characteristics.<br />

1. Ignitability – substances that catch fire<br />

readily (e.g. gasoline <strong>and</strong> alcohol).<br />

2. Corrosivity – substances that corrode<br />

storage tanks <strong>and</strong> equipment (e.g. acid).<br />

3. Reactivity – substances that are<br />

chemically unstable <strong>and</strong> may explode or<br />

create toxic fumes when mixed with<br />

water. (eg. conc. H 2 SO 4 ).<br />

4. Toxicity – substances that are injurious to<br />

<strong>health</strong> when in hailed e.g. chlorine,<br />

ammonia, pesticides <strong>and</strong> formaldehyde.<br />

Toxic substances are poisonous <strong>and</strong> cause<br />

death or serious injury to humans <strong>and</strong> other<br />

organisms. They are: (i) heavy metals, <strong>and</strong><br />

(ii) non-biodegradable synthetic organics.<br />

Heavy Metals<br />

The most dangerous heavy metals are<br />

lead, mercury, arsenic, cadmium, tin,<br />

chromium, zinc <strong>and</strong> copper. These metals are<br />

widely used in industry particularly in metal<br />

working or metal plating shops, <strong>and</strong> in such<br />

products as batteries <strong>and</strong> electronics. They are<br />

also used in pesticides <strong>and</strong> medicines, used in


paints pigments glazes, inks <strong>and</strong> dyes. Thus<br />

heavy metals may enter the environment<br />

wherever any of these products are produced,<br />

used <strong>and</strong> ultimately discarded.<br />

Heavy metals are toxic because, as ions<br />

or in certain compounds, they are soluble in<br />

water <strong>and</strong> may be readily absorbed in to the<br />

body, where they combine with <strong>and</strong> inhibit the<br />

functioning of particular vital enzymes. Even<br />

very small amounts can have physiological or<br />

neurological consequences.<br />

The mental retardation caused by lead<br />

poisoning <strong>and</strong> crippling birth defects caused by<br />

mercury are well known examples.<br />

Non-biodegradable Synthetic Organic<br />

Compounds<br />

Synthetic organic compounds are<br />

plastics, synthetic fibers, synthetic rubber,<br />

modern paint like coatings, solvents, pesticides,<br />

wood preservatives <strong>and</strong> hundreds of other<br />

products.<br />

These products are toxic because they<br />

are absorbed in to the body, there they interact<br />

with the particular enzymes, but their non<br />

biodegradability prevents them from being<br />

broken down or processed further. The result<br />

is that they upset the system. When a person<br />

ingests a high dose, the effect may be an acute<br />

poisoning <strong>and</strong> death.<br />

With a low dose over extended periods,<br />

the effects are insidious <strong>and</strong> can be mutagenic,<br />

carcinogenic, or teratogenic (birth defect).<br />

They may cause liver <strong>and</strong> kidney dysfunction,<br />

sterility <strong>and</strong> numerous other physiological <strong>and</strong><br />

neurological problems.<br />

The troublesome class of synthetic<br />

organics is the halogenated hydrocarbons. It is<br />

organic compounds in which one or more of<br />

the hydrogen atoms have been replaced by<br />

atoms of chlorine, bromine, fluorine, or iodine.<br />

These four elements are classed as halogens.<br />

Of the halogenated hydrocarbons, the<br />

chlorinated hydrocarbons are the most<br />

common. Organic chlorides are used in<br />

plastics, pesticides, solvents electrical<br />

insulation, flame retardants <strong>and</strong> many other<br />

products.<br />

Bio-accumulation <strong>and</strong> Bio-magnification<br />

Heavy metals <strong>and</strong> non-biodegradable<br />

synthetic organic compounds are accumulated<br />

in the organisms. Because of accumulation in<br />

small amounts received over a long period of<br />

time may reach to toxic levels. This<br />

phenomenon is referred to as bio-accumulation<br />

(Nebel 1998).<br />

Organisms act as filter for heavy metals<br />

<strong>and</strong> synthetic organics. Heavy metals are<br />

removed from solution. Synthetic organics are<br />

highly soluble in lipids (fats <strong>and</strong> fatty<br />

compounds) but sparingly soluble in water. As<br />

they pass through cell membranes, which are<br />

lipid, they come out of water solution <strong>and</strong> enter<br />

in to the lipid of the body. Thus traces of<br />

heavy metals <strong>and</strong> synthetic organics that are<br />

absorbed by the water <strong>and</strong> water soluble wastes<br />

are passed in the urine. Since the body has no<br />

mechanism to excrete the heavy metals <strong>and</strong><br />

synthetic organics, trace levels consumed over<br />

time gradually accumulate in the body <strong>and</strong><br />

produce toxic effects.<br />

Each organism accumulates the<br />

contamination in its food, so it accumulates in<br />

its body. All the contaminants accumulated by<br />

the higher organism through smaller organism<br />

when they consume them as food. This<br />

multiplying effect of bioaccumulation that<br />

occurs through the food chain is called biomagnification.<br />

The pesticide D.DT is an<br />

example of bio-magnification (Nebel 1998).<br />

There is no warning symptoms in the<br />

beginning, until the contaminant concentration<br />

in the body are high enough to cause problems.<br />

Then it is too late to do much about.<br />

There are also several polycentric<br />

aromatic hydrocarbons. (PAHs), which arrive<br />

in the atmosphere from coal production,<br />

vehicle disposal, wood burning, municipal<br />

incineration, petroleum refining <strong>and</strong> coal<br />

furnaces. In general they do not produce<br />

adverse effect in their parent forms. However<br />

if metabolized by enzymes of the body, they<br />

produce intermediates which are capable of<br />

producing cancer.<br />

36


Prevention <strong>and</strong> Control of Air <strong>Pollution</strong>.<br />

We have seen that the main sources of air<br />

pollution are motor vehicles, industries –<br />

particularly their chimney wastes, <strong>and</strong> fossil<br />

fuel (coal) based plants, as thermal power<br />

plants. Steps are to be taken to control<br />

pollution at source (prevention) as well as after<br />

the release of pollutants in the atmosphere.<br />

Vehicular <strong>Pollution</strong><br />

How can we control the air pollution by<br />

motor vehicles?<br />

1. By checking pollutant emission from<br />

vehicular exhaust. This can be achieved by:<br />

(i) using gas additives to improve<br />

combustion.<br />

(ii) more exact timing of fuel feeding.<br />

(iii) using new proportion of gasoline <strong>and</strong><br />

air.<br />

(iv) injecting air to exhaust to convert<br />

exhaust compounds to less toxic<br />

materials.<br />

(v) updating of engine design to improve<br />

combustion.<br />

(vi) The three pollutant, CO, NO x <strong>and</strong><br />

hydrocarbon can eliminate by<br />

updating engine design. Very recently,<br />

L.K. Bharati of Bombay has claimed<br />

to have devised a simple attachment<br />

thermo reactor, to scrub air pollution<br />

by motor vehicle. The reactor is fitted<br />

to exhaust tailpipe <strong>and</strong> it converts<br />

carbon monoxide in to pure oxygen.<br />

2. By using electrostatic precipitators<br />

(ESPs)<br />

To remove the particles from gas stream,<br />

the electrical forces are applied within the<br />

chamber in the precipitator. Suspended<br />

particles become charged or ionized <strong>and</strong> they<br />

are attracted to charged electrodes <strong>and</strong> removed<br />

99% particulate pollutant can remove by this<br />

method. ESPs work very well in power plants,<br />

paper mills, cement factory carbon block plants<br />

etc.<br />

Conclusion<br />

The environment <strong>and</strong> its relation to<br />

humanity is one of the most important<br />

problems of the present time. <strong>Environmental</strong><br />

problems are man made. Hence man naturally<br />

is the solution to most of them. With his<br />

unique technological capabilities he can<br />

increase or decrease human miseries.<br />

Exploitation of nature was considered<br />

inevitable for human survival. Hence man is<br />

obliged to re examine his values, attitudes,<br />

behavior, life styles <strong>and</strong> where necessary to<br />

alter them to ensure his survival. To day we<br />

have both knowledge <strong>and</strong> technology for a<br />

sound ecological management. We know how<br />

to control pollution, how to recycle materials<br />

<strong>and</strong> nutrients <strong>and</strong> harness solar energy. What is<br />

required is only a matter of desire <strong>and</strong> will as<br />

individuals <strong>and</strong> societies to put what is known<br />

in to practice. All powers are given to man to<br />

preserve a quality environment. Our<br />

environmental recession making should reflect<br />

this fundamental purpose of human existence.<br />

References<br />

Enger, D.E.; <strong>and</strong> Smith, B.F. 2000.<br />

<strong>Environmental</strong> Science. A Study of<br />

Interrelationship, 8 th ed. McGraw-Hill,<br />

New York, NY, USA.<br />

Nebel, B.J.; <strong>and</strong> Wright, R.T. 1998.<br />

<strong>Environmental</strong> Science, 6 th ed. Prentice<br />

Hall, Upper Saddle River, NJ, USA.<br />

Sharma, P.D. 1998. Ecology <strong>and</strong> Environment,<br />

7 th ed. Rastogi Publ., Meerut, New Delhi,<br />

India.<br />

Sharma, P.D. 1999. <strong>Environmental</strong> Biology,<br />

2 nd ed. Rastogi Publ., Meerut, New Delhi<br />

India.<br />

.<br />

37

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