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MATERIAL SAFETY DATA SHEET (MSDS) - Jablotron

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Lithium Ion Batteries<br />

Page 1/5<br />

<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong> (<strong>MSDS</strong>)<br />

SECTION I – PRODUCT AND MANUFACTURER INFORMATION<br />

Product Name:<br />

Chemical Systems:<br />

Sizes:<br />

Designed for Recharge:<br />

Lithium Ion Battery<br />

Lithium Ion<br />

All Cylindrical and Prismatic Type<br />

Yes<br />

Well Link Industrial Limited<br />

Rm. 1116-17 Tower A, Regent Centre<br />

63 Wo Yi Hop Rd., Kwai Chung, NT., Hong Kong<br />

Telephone Number for Information: 852-24818893<br />

Date Prepared: January, 2011<br />

SECTION II – HAZARDS IDENTIFICATION<br />

- Ingestion<br />

- Inhalation<br />

- Skin Contact<br />

- Eye Contact<br />

SECTION III – INFORMATION ON INGREDIENTS<br />

WARNING: The battery should not be opened or burned. Exposure to the ingredients contained within or their<br />

combustion products could be harmful.<br />

<strong>MATERIAL</strong> OR INGREDIENTS<br />

Content.<br />

TLV<br />

(ACGIH Threshold Limit Values)<br />

Lithium Cobaltate (CAS# 12190-79-3) 30% None Established<br />

Graphite (CAS# 7782-42-5) 16% 2.5mg/m 3 (as dust)<br />

Organic Solvent 13% None Established<br />

Lithium Salt 1% None Established<br />

Weight of Lithium per cell : 0 gram<br />

There is no metallic lithium in lithium ion battery and are all applicable to the UN Recommendations/Special<br />

Provision 188 and Special Provision A45 of the ICAO and IATA and thus can be transported as ‘Non-Dangerous<br />

Goods’.<br />

PROFESSIONAL BATTERY MANUFACTURER: NiMH rechargeable battery . NiCd rechargeable battery . Li-Ion rechargeable battery . Lithium polymer rechargeable battery .<br />

SLA rechargeable battery . Alkaline battery . Lithium battery . Zinc chloride battery . Carbon zinc battery


Lithium Ion Batteries<br />

Page 2/5<br />

SECTION IV – FIRST-AID MEASURES<br />

Ingestion:<br />

Swallowing a battery can be harmful. Seek medical attention immediately. Call The National Capital<br />

Poison Control Center (202-625-3333) collect, or your local Poison Control Center (800-222-1222), day or<br />

night, for advice and follow-up.<br />

Inhalation:<br />

Contents of an open battery can cause respiratory irritation.<br />

Provide fresh air and seek medical attention.<br />

Skin Contact:<br />

Contents of an open battery can cause skin irritation and/or chemical burns. Remove contaminated clothing<br />

and wash skin with soap and water. If a chemical burn occurs or if irritation persists, seek medical<br />

attention.<br />

Eye Contact:<br />

Contents of an open battery can cause severe irritation and/or chemical burns. Immediately flush eyes<br />

thoroughly with copious quantities of flowing lukewarm water for a minimum of 15 minutes. Seek<br />

immediate medical attention.<br />

SECTION V – FIRE FIGHTING MEASURES<br />

If fire or explosion occurs when batteries are on charge, shut off power to charger.<br />

In case of fire where lithium ion batteries are present, flood the area with water. If any batteries are burining,<br />

water may not extinguish them, but will cool the adjacent batteries and control the spread of fire. CO 2 , dry<br />

chemical and foam extinguishers are preferred for small fires, but also may not extinguish burning lithium<br />

ion batteries. Burning batteries will burn themselves out. Virtually all fires involving lithium ion batteries can<br />

be controlled with water. When water is used, however, hydrogen gas may be evolved which can form an<br />

explosive mixture with air. LITH-X (powdered graphite) or copper powder fire extinguishers, sand dry<br />

ground dolomite or soda ash may also be used. These materials act as apply smothering agents.<br />

Fire fighters should wear self-contained breathing apparatus. Burning lithium ion batteries can produce toxic<br />

fumes including HF, oxides of carbon, aluminum, lithium, copper and cobalt.<br />

SECTION VI - SPILL OR LEAK PROCEDURES<br />

Procedures to Contain and Clean Up Leaks or Spills:<br />

The preferred response is to leave the area and allow the batteries to cool and the vapors to dissipate. Avoid<br />

skin and eye contact or inhalation of vapors. Remove spilled liquid with absorbent and incinerate.<br />

Reporting Procedure:<br />

Report all spills in accordance with Federal, State and Local reporting requirements.<br />

PROFESSIONAL BATTERY MANUFACTURER: NiMH rechargeable battery . NiCd rechargeable battery . Li-Ion rechargeable battery . Lithium polymer rechargeable battery .<br />

SLA rechargeable battery . Alkaline battery . Lithium battery . Zinc chloride battery . Carbon zinc battery


Lithium Ion Batteries<br />

Page 3/5<br />

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE<br />

Storage:<br />

Store in a cool, dry, and well-ventilated area. Elevated temperature can result in shortened battery life.<br />

Storing unpackaged cells together could result in cell shorting and heat build-up.<br />

Mechanical Containment:<br />

Do not obstruct safety release vents on batteries. Encapsulation (potting) of batteries will not allow cell<br />

venting and can cause high-pressure rupture.<br />

Handling:<br />

Accidental short circuit for a few seconds will not seriously affect the battery. However, this battery is<br />

capable of delivering very high short circuit currents. Prolonged short circuits will cause high cell<br />

temperatures that can cause skin burns. Sources of short circuits include jumbled batteries in bulk containers,<br />

metal jewelry, and metal covered tables or metal belts used for assembly of batteries into devices.<br />

If soldering or welding to the battery is required, use of tabbed batteries is recommended.<br />

Do not disassemble or deform battery.<br />

Charging:<br />

This battery is made to be charged many times. Because it gradually loses its charge over a few months, it is<br />

good practice to charge battery before use. Use recommended charger. Improper charging can cause heat<br />

damage or even high pressure rupture. Observe proper charging polarity.<br />

SECTION VIII – PERSONAL PROTECTION<br />

Respiratory Protection (Specify Type)<br />

Ventilation<br />

Protective Gloves<br />

Eye Protection<br />

Other Protective Clothing<br />

Not necessary under normal conditions<br />

Not necessary under normal conditions<br />

Not necessary under normal conditions<br />

Not necessary under normal conditions<br />

Not necessary under normal conditions<br />

SECTION IX - PHYSICAL <strong>DATA</strong><br />

Specific Gravity : (H20=1) LiCoO2 : 4.95<br />

Graphite : 2.09-2.2<br />

Melting Point ( o C)<br />

LiCoO2 : ~1130 o C<br />

Appearance and Odor<br />

LiCoO2 is a black, ordorless powder<br />

Graphite is a black, ordorless powder<br />

Organic solvent is a colorless or light yellow liquid<br />

Lithium Salt is a white, crystalline and odorless<br />

powder<br />

PROFESSIONAL BATTERY MANUFACTURER: NiMH rechargeable battery . NiCd rechargeable battery . Li-Ion rechargeable battery . Lithium polymer rechargeable battery .<br />

SLA rechargeable battery . Alkaline battery . Lithium battery . Zinc chloride battery . Carbon zinc battery


Lithium Ion Batteries<br />

Page 4/5<br />

SECTION X - REACTIVITY <strong>DATA</strong><br />

Stable or Unstable<br />

Conditions to Avoid<br />

Hazardous Decomposition Reactions<br />

Stable<br />

Do not heat, disassemble or overcharge<br />

N/A<br />

Hazardous polymerization will not occur<br />

SECTION XI - HEALTH HAZARD <strong>DATA</strong><br />

Under normal conditions of use, the battery is hermetically sealed. Risk of exposure occurs only if the<br />

battery is mechanically or electrically abused. Organic solvent has slightly toxicity and can irritate skin and<br />

eyes. Lithium salt is irritating to skin, eyes and mucous membranes and should be avoided.<br />

Carcinogenicity :<br />

NTP :<br />

None<br />

IARC Monograph : None<br />

OSHA Regulated : None<br />

SECTION XII – FIRE & EXPLOSION HAZARD <strong>DATA</strong><br />

Flash Point<br />

Flammable Limits in Air (%)<br />

Lower (LEL)<br />

Upper (LEL)<br />

Extinguishing Media<br />

Auto-Ignition<br />

NA unless individual components exposed<br />

NA unless individual components exposed<br />

NA unless individual components exposed<br />

NA unless individual components exposed<br />

Water<br />

NA unless individual components exposed<br />

SECTION XIII – Disposal Method<br />

Disposal in accordance with Federal, State and Local reporting requirements.<br />

SECTION XIV – TRANSPORTATION<br />

KINETIC lithium ion batteries are not subject to requirements of the U.S. Hazardous Materials Regulations<br />

pursuant to 49 CFR 173.185(b), IATA Dangerous Goods Regulations pursuant to Special Provision A45, and<br />

IMDG Code pursuant to Special Provision 188.<br />

Batteries must be packaged and offered for transportation in a manner that prevents the dangerous evolution<br />

of heat and protects against short circuits.<br />

PROFESSIONAL BATTERY MANUFACTURER: NiMH rechargeable battery . NiCd rechargeable battery . Li-Ion rechargeable battery . Lithium polymer rechargeable battery .<br />

SLA rechargeable battery . Alkaline battery . Lithium battery . Zinc chloride battery . Carbon zinc battery


Lithium Ion Batteries<br />

Page 5/5<br />

Effective January 1, 2011, all KINETIC lithium coin cell batteries can be shipped by air in accordance with<br />

International Civil Aviation Organization (ICAO), Section II or International Air Transport Association<br />

(IATA) current 52nd 2011 edition, Section II Packing Instructions (PI) 965 (Batteries)<br />

SECTION XV – REGULATORY INFORMATION<br />

These products are “article(s)” that do not release a covered toxic chemical under the normal conditions of<br />

processing or use. They are not subject to the requirements of the Emergency Planning and Community<br />

Right-To-Know Act. Notification is not required.<br />

SECTION XVI – OTHER INFORMATION<br />

The battery referenced herein is defined as “article” and is NOT subject to the 29 CFR 1910.1200 OSHA Hazard<br />

Communication Standard requirement or to the Canadian WHMIS requirement. Hence, a material safety data<br />

sheet (<strong>MSDS</strong>) is not required. The information and recommendation set forth herein are supplied as a service.<br />

They are made in good faith and believed to be accurate as of the date of preparation. Well Link makes no<br />

warranty, either express or implied, with respect to this information and disclaims all liability from reliance on it.<br />

PROFESSIONAL BATTERY MANUFACTURER: NiMH rechargeable battery . NiCd rechargeable battery . Li-Ion rechargeable battery . Lithium polymer rechargeable battery .<br />

SLA rechargeable battery . Alkaline battery . Lithium battery . Zinc chloride battery . Carbon zinc battery

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