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provides the accessibility of cation exchange complex to moving soil solution and<br />

large mobile soil solution proportion than in chestnut soil. The over-compacted<br />

chestnut soil has a pore structure in which pore surfaces can rapidly become Casaturated.<br />

1.0<br />

a<br />

b<br />

C rel<br />

0.5<br />

0.0<br />

0 1 2 3<br />

V rel<br />

0 1 2 3<br />

Fig. 7. Chloride (, ), calcium (, ) and sodium (, •) breakthrough curves<br />

observed in slow-flow (hollow symbols) and fast-flow (filled symbols) experiments with<br />

two southern chernozem soil cores.<br />

In summary, the physical heterogeneity governed transport of in ions in this work.<br />

This heterogeneity may cause fast transport of adsorbing pollutants in soil profiles,<br />

groundwater pollution, and creates a challenge incorporating the physical<br />

heterogeneity in models of pollutant transport in soils and sediments.<br />

ACKNOWLEDGEMENT This work was partially supported by the Nato Science Programme,<br />

Cooperative Science & Technology Sub-Programme, Collaborative Linkage Grant # 979233.<br />

REFERENCES<br />

1.<br />

2.<br />

Barnett M.O., P.M.Jardine, S.C.Brooks, and H.M.Selim. 2000. Adsorption and transport of<br />

Uranium(VI) in subsurface media. Soil Science Society of America Journal, 64: 908-917.<br />

Danckwerts P.Y. 1953. Continuous flow systems. Distribution of residence times. Chem.<br />

Eng. Sci., 2: 47-55.<br />

92

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