Films minces à base de Si nanostructuré pour des cellules ...
Films minces à base de Si nanostructuré pour des cellules ... Films minces à base de Si nanostructuré pour des cellules ...
From the two cases shown in this gure, it can be noticed that the angle of incidence inuences the intensity and position of the pump maxima. This indicates that with 45° incidence used in our PL experiments, the pump intensity is lower than that obtained in normal incidence. (b) Inuence of thickness tel-00916300, version 1 - 10 Dec 2013 The inuence of the lm thickness (d) on the pump prole was investigated for three cases: d = 300 nm, 500 nm and 1000 nm (Fig. 5.4). In all the three cases shown in this gure, the angle of incidence was xed at 45°, and the refractive index is as described before (ref. Fig. 5.2). It can be seen from gure 5.4 that only by varying the total thickness there is a change in the position and intensity of the pump prole. This can be related to the reection in the lm denoted as r glob in equation 5.10, which is a function of lm thickness. These results Figure 5.4: Inuence of total lm thickness on clearly indicate that the mean pump the pump prole. intensity varies non-monotonously with thickness (Tab. 5.1). Thickness (d) nm Pump intensity range W/m 2 300 1 x 10 4 - 8 x 10 4 500 2.5 x 10 4 - 1x10 5 1000 2 x 10 4 - 9.5 x10 4 Table 5.1: The pump intensity range for the three thicknesses investigated. (c) Inuence of complex refractive index The inuence of the real part and imaginary part of the complex refractive index on the pump prole were investigated. (c1) Real part (n 2 ): To witness the contribution of n 2 on the pump wave that travels from medium 1 (air) to medium 2 (thin lm), simulations are made by considering three SRSO monolayers with 500 nm thickness and three dierent refractive indices (n 2 = 1.48, 142
tel-00916300, version 1 - 10 Dec 2013 1.6 and 2.1). We assume that, there are no losses in the lm due to absorption and hence set k 2 =0. Figure 5.5 shows the pump prole variation with n 2 , along the depth (x) from lm surface. The result indicates that the intensity of the incident pump and the position of maxima varies with the refractive indices of the material. The mean pump intensity varies monotonously with refractive index in the three cases investigated (Tab. 5.5). The lower index resulting in the highest intensity. The period of the pump prole also varies with n 2 . We can thus suppose the variation of emission intensity with refractive index is not a sole contribution from Si-np density, but also the eect of the incident pump intensity that varies. Figure 5.5: Pump prole versus real part of thin lm refractive index (n 2 ). Real part (n 2 ) of refractive index Pump intensity range W/m 2 1.48 1.4 x 10 4 - 1.5 x 10 5 1.6 1.1 x 10 4 - 9.5x10 4 2.1 2.3 x 10 4 - 7.9 x10 4 Table 5.2: The pump intensity range for the three thicknesses investigated. (c2) Imaginary part (k 2 ): In order to investigate the eect of losses, the extinction coecient k 2 of the thin lm was varied while keeping n 2 xed at 1.6 (Fig. 5.6). Figure 5.6a shows the pump prole for three cases : k 2 = 0, 0.01 and 0.1 and gure 5.6b illustrates the envelope of the pump maxima and minima taking k 2 = 0.1 as a typical example. It can be seen from gure 5.6a that there are no losses when k 2 =0 and the intensity of the pump maxima and minima are constant with depth (x). With increasing values of extinction factor k 2 : (i) the envelopes of the pump maxima and minima decrease with depth (x) and (ii) the dierence between (Envelope) max. and (Envelope) min. decreases. This indicates that with increasing losses, the pump intensity decreases. These factors would inuence the excitation of emitters along the depth of the thin lm, and consequently on the emission intensity. 143
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From the two cases shown in this gure, it can be noticed that the angle of<br />
inci<strong>de</strong>nce inuences the intensity and position of the pump maxima. This indicates<br />
that with 45° inci<strong>de</strong>nce used in our PL experiments, the pump intensity is lower<br />
than that obtained in normal inci<strong>de</strong>nce.<br />
(b) Inuence of thickness<br />
tel-00916300, version 1 - 10 Dec 2013<br />
The inuence of the lm thickness (d) on the pump prole was investigated for three<br />
cases: d = 300 nm, 500 nm and 1000 nm (Fig. 5.4).<br />
In all the three cases shown in<br />
this gure, the angle of inci<strong>de</strong>nce<br />
was xed at 45°, and the refractive<br />
in<strong>de</strong>x is as <strong>de</strong>scribed before (ref.<br />
Fig. 5.2). It can be seen from gure<br />
5.4 that only by varying the total<br />
thickness there is a change in the<br />
position and intensity of the pump<br />
prole. This can be related to the<br />
reection in the lm <strong>de</strong>noted as r glob<br />
in equation 5.10, which is a function<br />
of lm thickness. These results<br />
Figure 5.4: Inuence of total lm thickness on<br />
clearly indicate that the mean pump<br />
the pump prole.<br />
intensity varies non-monotonously<br />
with thickness (Tab. 5.1).<br />
Thickness (d) nm Pump intensity range W/m 2<br />
300 1 x 10 4 - 8 x 10 4<br />
500 2.5 x 10 4 - 1x10 5<br />
1000 2 x 10 4 - 9.5 x10 4<br />
Table 5.1: The pump intensity range for the three thicknesses investigated.<br />
(c) Inuence of complex refractive in<strong>de</strong>x<br />
The inuence of the real part and imaginary part of the complex refractive in<strong>de</strong>x<br />
on the pump prole were investigated.<br />
(c1) Real part (n 2 ):<br />
To witness the contribution of n 2 on the pump wave that travels from medium<br />
1 (air) to medium 2 (thin lm), simulations are ma<strong>de</strong> by consi<strong>de</strong>ring three SRSO<br />
monolayers with 500 nm thickness and three dierent refractive indices (n 2 = 1.48,<br />
142