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COMBI-CRYSTAL-PET® (CC-PET®) - Suurmond

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<strong>COMBI</strong>-<strong>CRYSTAL</strong>-PET ® (<strong>CC</strong>-PET ® )<br />

PET direct crystallization – energy savings in a reliable process<br />

<strong>CC</strong>-PET ® combines pelletizing, drying, and<br />

crystallization in a single process. Therefore,<br />

the crystalline PET pellets can directly be used<br />

for extrusion downstream processing. The<br />

pellets are almost dust-free and can be reliably<br />

processed at high bulk density. As pelletizing<br />

and direct crystallizing are combined into one<br />

single step, a lot of energy is saved. <strong>CC</strong>-PET ®<br />

is applied in the production of virgin polymers<br />

and also in recycling processes.<br />

Your benefits<br />

• Reduced investment costs compared to conventional PET processing<br />

• Lower production costs due to high energy savings; additional heating<br />

often required only upon production start-up<br />

• Spherical, almost dust-free and non-sticky pellets<br />

• High bulk density for downstream processing of the material<br />

• Can highly flexibly be adapted to changing process conditions<br />

• Crystallization temperature and dwell time are infinitely variable


<strong>COMBI</strong>-<strong>CRYSTAL</strong>-PET ® (<strong>CC</strong>-PET ® )<br />

PET direct crystallization – significant energy savings, enhanced process reliability<br />

Processes and machines and systems made by Automatik Plastics Machinery stand for cost-effectiveness, flexibility, and<br />

reliability worldwide. With over six decades of experience and an installed base of currently more than 8,000 pelletizing<br />

systems, the company helps its customers to achieve the maximum level of profitability.<br />

Range of applications<br />

<strong>CC</strong>-PET ® combines pelletizing, drying, and crystallization in a single process. Downstream treatment of the pellets, usually<br />

as solid state polymerisation (SSP), is greatly simplified because the semi-crystalline end product does not stick in subsequent<br />

post-processing operations. <strong>CC</strong>-PET ® can be applied to both virgin polymer production and recycling applications with<br />

production capacities ranging from 750 kg/h up to 15,000 kg/h. The output from one reactor may be optionally diverted to<br />

several pelletizing lines and then recombined to a single crystallizer.<br />

Functioning of the <strong>CC</strong>-PET ® system<br />

The PET melt is discharged from the reactor or<br />

the extruder by a melt pump 01.<br />

The material is then processed by a SPHERO ®<br />

02 underwater pelletizer 03.<br />

The hot process water rapidly transports the<br />

pellets to the dryer 04, where the water is separated<br />

from the plastic pellets.<br />

The crystallizer 05 processes the PET pellets<br />

utilizing the residual heat, as well as additional<br />

heating as required.<br />

After crystallizing, the pellets are suitable for<br />

any kind of post-processing 06.<br />

The process water is tempered, filtered and returned<br />

to the points of use in a closed duct 07.<br />

04<br />

04<br />

01<br />

01<br />

02 03<br />

07<br />

07<br />

05<br />

05<br />

06<br />

<strong>CC</strong>-PET ® integrates the crystallization of PET<br />

directly into the SPHERO ® underwater pelletizing<br />

system. The end product does not stick<br />

in subsequent downstream processing operations.<br />

This results in<br />

• Reduced energy consumption, lower<br />

investment costs, and in<br />

• Increased operating profitability for both<br />

the system operator and his customers.<br />

Furthermore, <strong>CC</strong>-PET ® provides for controlled<br />

nucleation, as well as the supply of additional<br />

heating as required, for a wide range of raw<br />

material types. This ensures constant crystallization<br />

conditions which are not sensitive to<br />

fluctuations in material properties, guaranteeing<br />

highly uniform product quality.<br />

Immediately after conventional processing, PET pellets are amorphous.<br />

Such amorphous pellets become sticky when heated to temperatures<br />

above 70 °C and thus are not suitable for subsequent processing such as:<br />

• Post-condensation in the SSP – the pellets must be processed for<br />

several hours at approx. 210 °C.<br />

• Drying prior to downstream processing – due to its distinctive<br />

hygroscopic properties, PET must be intensively dried with hot air at<br />

160-180 °C for up to 6 hours.<br />

Therefore, the PET pellets must first be crystallized, since only this form<br />

is not sticky. For crystallizing, the pellets must be heated for a limited<br />

period of time to a temperature of approx. 130-180 °C. In order to<br />

avoid agglutination during the crystallizing operation, the pellets must<br />

be kept moving, e.g. by vibration, stirring, or fluidizing. The crystallization<br />

process is exothermic, and this reaction heat in combination with<br />

the residual heat can often meet the entire energy need for process<br />

heating. <strong>CC</strong>-PET ® helps to retain as much internal heat from upstream<br />

processing steps in the pellets as possible, thus reducing energy costs.


<strong>COMBI</strong>-<strong>CRYSTAL</strong>-PET ® (<strong>CC</strong>-PET ® )<br />

<strong>CC</strong>-PET ® system components<br />

In order to implement the <strong>CC</strong>-PET ® process, the following system<br />

components are combined in various configurations immediately<br />

following the melt generation unit:<br />

Pelletizing<br />

The pelletizing operation is performed with SPHERO ® for large-scale<br />

production of virgin PET or for recycling applications.<br />

SPHERO ® underwater pelletizer for virgin polymers and recycling<br />

applications<br />

• Suspension system provides optimal access to all pelletizer components<br />

• Die geometry tailored to material properties and desired pellet weight<br />

• Electric or liquid heating<br />

• Excellent cooling and pellet flow due to optimized cutting chamber<br />

design<br />

Featuring<br />

• Gentle melt handling<br />

• Rheologically optimized product channels<br />

• Electric, liquid, or steam heating<br />

• Energy-optimized process chain<br />

Melt handling<br />

• Melt pump<br />

• Polymer filter<br />

• Start-up valve for SPHERO ® systems<br />

CENTRO pellet dryer – for all USG and SPHERO ® systems<br />

• Energy-optimized pellet drying<br />

• Re-feeding of the separated water to the process loop<br />

• Direct transfer of pellets to the crystallizer<br />

<strong>CC</strong>-PET ® direct crystallization for all pelletizing options<br />

• Vibrating conveyor for simple recycling applications<br />

• ΔQ crystallizer for more sophisticated PET types and for highest<br />

throughput rates in automatic operation<br />

• Fluid bed crystallizer available for specialized applications<br />

<strong>CC</strong>-PET ® ΔQ crystallizer<br />

Options for post-processing of pellets<br />

• Classifier<br />

• Spiral cooling conveyor<br />

• SSP<br />

• Dealdehydization<br />

CENTRO pellet dryer<br />

<strong>CC</strong>-PET ® system controls<br />

• From simple machine controls to complex process visualization options<br />

• Function of individual components (e.g. melt pump, polymer filter,<br />

water circuit) can be integrated into the pelletizer controls<br />

• Data exchange with higher-level control systems possible<br />

Process water treatment<br />

Continuous filtration of return water with manual or automatic filters<br />

and automatic compensation for water loss within the system.<br />

<strong>CC</strong>-PET ® vibrating conveyor


<strong>COMBI</strong>-<strong>CRYSTAL</strong>-PET ® (<strong>CC</strong>-PET ® )<br />

Technical data<br />

PET product properties for the <strong>CC</strong>-PET ® process:<br />

IV: 0.50-0.90 dl/g<br />

DEG < 1.5 %w<br />

Co-monomers:<br />

IPA < 2.5 %w<br />

Others 0 %w<br />

Melt temperature T s<br />

:<br />

T S<br />

= TMP + 30 K (TMP = melting point)<br />

Pellet weight:<br />

15-18 mg<br />

Pellet temperature: After crystallizator: 150 °C-170 °C<br />

Global contacts, see www.maag.com<br />

Contact us at contact@maag.com<br />

A_50_2012/3<br />

The data and illustrations refer to the date of printing. Necessary changes can be made at any time without special notice. Maag Group´s products and processes are protected by IP rights.

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