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Miscibility Studies of Agar-Agar/Starch blends using Various ... - ijrpc

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IJRPC 2012, 2(4) Jagadish et al ISSN: 22312781<br />

Table 2: Experimental and Theoretical Tg values <strong>of</strong> starch, <strong>Agar</strong>-<strong>Agar</strong> and their <strong>blends</strong><br />

<strong>Agar</strong>-<strong>Agar</strong>/ starch blend Experimental<br />

Theoritical Tg values (ºC)<br />

compositions<br />

Tg values (ºC) Fox equation Wood’s equation<br />

<strong>Agar</strong>-<strong>Agar</strong> 44.50 - -<br />

70/30 46.50 48.50 49.51<br />

50/50 50.10 51.70 53.35<br />

<strong>Starch</strong> 61.20 - -<br />

Reduced viscosity ( red<br />

)<br />

25<br />

20<br />

15<br />

10<br />

5<br />

agar<br />

90/10<br />

80/20<br />

70/30<br />

60/40<br />

50/50<br />

40/60<br />

30/70<br />

20/80<br />

10/90<br />

starch<br />

0<br />

0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.18 0.20 0.22<br />

Concentration (g/dL)<br />

Fig. 1: Huggins’s plot for 0.2% w/v, agar-agar/starch <strong>blends</strong> in water at 30ºC<br />

Reduced viscosity ( red<br />

)<br />

16<br />

14<br />

12<br />

10<br />

8<br />

6<br />

4<br />

agar<br />

90/10<br />

80/20<br />

70/30<br />

60/40<br />

50/50<br />

40/60<br />

30/70<br />

20/80<br />

10/90<br />

starch<br />

2<br />

0<br />

0.00 0.02 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.18 0.20 0.22<br />

Concentration (g/dL)<br />

Fig. 2: Huggins’s plot for 0.2% w/v, agar-agar/starch <strong>blends</strong> in water at 50ºC<br />

1052

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