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SAFETY DATA SHEET - Industrial Health and Safety Consultants, Inc.

SAFETY DATA SHEET - Industrial Health and Safety Consultants, Inc.

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<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

TINUVIN327-ESTANE<br />

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND<br />

THE COMPANY/UNDERTAKING<br />

Product Name: Tinuvin® 327 concentrate in Estane® 58245<br />

Date Prepared: 19.9.2002<br />

Manufacturer:<br />

Telephone:<br />

MEDICAL EMERGENCY<br />

TRANSPORTATION EMERGENCY<br />

INFORMATION<br />

Kimberly-Clark Corporation<br />

1400 Holcomb Bridge Road<br />

Roswell, GA 30076-2199<br />

United States of America<br />

1-800-228-5635 Extension 140<br />

Chemtrec 1-800-424-9300<br />

1-888-346-4652<br />

Product Use: Raw Material<br />

2. COMPOSITION/INFORMATION ON INGREDIENTS<br />

Chemical Name<br />

CAS-No./ EINECS-<br />

No<br />

% EU Classification<br />

(67/548/EEC):<br />

Polyurethane Resin Proprietary 88% Not applicable<br />

2,4-di-tert-butyl-6-(5-<br />

chlorobenzotriazol-2-<br />

yl) phenol<br />

3864-99-1 12% X.ni R48/22, R52/53<br />

See Section 16 for further information on EU Classification.<br />

3. HAZARDS IDENTIFICATION<br />

Emergency Overview: Tan, solid pellets. Slight odor. May cause eye irritation.<br />

Prolonged exposure may cause liver <strong>and</strong> kidney effects based on animal data. Molten<br />

polymer will burn skin on contact. No adverse inhalation effects are known or expected at<br />

ambient temperatures. At elevated temperatures (e.g., melt processing temperature or<br />

combustion temperature) product may emit irritating <strong>and</strong> potentially toxic fumes <strong>and</strong><br />

vapors.<br />

EU Classification (1999/45/EC): Xn - Harmful R48/22<br />

US OSHA Classification (29CFR1910.1200): Target Organ Effects<br />

Canadian WHMIS Classification: Class D-2-B<br />

4. FIRST AID MEASURES<br />

Inhalation: Move to fresh air. Obtain medical attention if irritation persists.<br />

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<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

TINUVIN327-ESTANE<br />

Skin contact: Wash off with soap <strong>and</strong> water. Obtain medical attention if irritation<br />

persists. If contact with molten polymer occurs, cool rapidly under running water. Do not<br />

attempt to remove material adhering to the skin. Obtain immediate medical attention.<br />

Eye contact: Rinse with plenty of water. Obtain medical attention.<br />

Ingestion: Obtain medical attention.<br />

5. FIRE-FIGHTING MEASURES<br />

Flashpoint: 752ºF (400ºC)<br />

Autoignition temperature: >765ºF (407ºC)<br />

Flammable Limits in Air % by Volume:<br />

LEL (Lower): Not applicable<br />

UEL (Upper): Not applicable<br />

Suitable Extinguishing Media: Water, water fog, foam, carbon dioxide, dry chemical.<br />

Special Fire Fighting Procedures: Wear self-contained breathing apparatus <strong>and</strong><br />

protective suit. Water may be used to keep exposed containers cool.<br />

Unusual Fire <strong>and</strong> Explosion Hazards: Product will burn under fire conditions. Large<br />

masses of product held at elevated temperatures for prolonged periods may autoignite.<br />

This product may build up electrostatic charge on pouring or transferring. The spark<br />

produced may ignite flammable gases or vapors. Avoid pouring into combustible or<br />

flammable solvents.<br />

Hazardous Combustion Products: Combustion may produce oxides of carbon,<br />

nitrogen oxides, hydrocarbons, isocyanates, <strong>and</strong> small amounts of hydrogen cyanide.<br />

6. ACCIDENTAL RELEASE MEASURES<br />

Carefully sweep up <strong>and</strong> place in a container for reuse or disposal.<br />

7. HANDLING AND STORAGE<br />

Avoid contact with skin <strong>and</strong> eyes. Wash thoroughly with soap <strong>and</strong> water after h<strong>and</strong>ling.<br />

Avoid sparks, flame <strong>and</strong> excessive heat. Minimize the generation <strong>and</strong> accumulation of dust.<br />

8. EXPOSURE CONTROLS / PERSONAL PROTECTION<br />

Chemical Name<br />

Polyurethane Resin<br />

2,4-di-tert-butyl-6-(5-chlorobenzotriazol-2-yl)<br />

phenol<br />

Exposure limit(s)<br />

None established<br />

2.5 mg/m3(manufacturer recommended)<br />

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<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

TINUVIN327-ESTANE<br />

Ventilation: Local exhaust ventilation recommended at points of emission to reduce<br />

exposure to fumes <strong>and</strong> vapors during processing.<br />

Respiratory Protection: If the exposure limit is exceeded or for symptoms of<br />

overexposure, wear an appropriate NIOSH (or local authority) approved respirator.<br />

Protective Gloves: Impervious gloves recommended as good industrial hygiene practice.<br />

Eye Protection: <strong>Safety</strong> glasses or goggles recommended.<br />

9. PHYSICAL AND CHEMICAL PROPERTIES<br />

Appearance <strong>and</strong> Odor<br />

Boiling point/range<br />

Melting point/range<br />

Tan, solid pellets.Slight odor.<br />

Not applicable<br />

Not available<br />

Specific Gravity (water=1) 1.2-1.3<br />

Vapor pressure<br />

Vapor density (air=1)<br />

Solubility<br />

pH<br />

Partition coefficient (n-octanol/water):<br />

Evaporation Rate (Butyl acetate=1)<br />

Volatile Organic Carbon Compounds (VOC)<br />

(g/L)<br />

Percent Volatile by Volume (%) 0<br />

negligible<br />

Not applicable<br />

Insoluble<br />

Not applicable<br />

Not available<br />

Not applicable<br />

None.<br />

10. STABILITY AND REACTIVITY<br />

Stability: Stable<br />

Conditions to Avoid: Keep away from heat <strong>and</strong> sources of ignition.<br />

Materials to avoid: <strong>Inc</strong>ompatible with acids <strong>and</strong> bases. <strong>Inc</strong>ompatible with oxidizing<br />

agents.<br />

Hazardous Decomposition Products: Combustion may produce oxides of carbon,<br />

nitrogen oxides, hydrocarbons, isocyanates, <strong>and</strong> small amounts of hydrogen cyanide. At<br />

elevated temperatures (e.g., melt processing temperature or combustion temperature)<br />

product may emit irritating <strong>and</strong> potentially toxic fumes <strong>and</strong> vapors.<br />

Hazardous Polymerization: Does not occur.<br />

11. TOXICOLOGICAL INFORMATION<br />

Symptoms/Effects of Overexposure:<br />

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<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

TINUVIN327-ESTANE<br />

Inhalation: No adverse inhalation effects are known or expected at ambient temperatures.<br />

Inhalation of processing vapors <strong>and</strong> fumes may cause moderate to severe respiratory<br />

irritation.<br />

Skin contact: Prolonged contact may cause mild irritation in sensitive individuals.<br />

Molten polymer will burn skin on contact.<br />

Eye contact: May cause eye irritation.<br />

Ingestion: Prolonged exposure may cause liver <strong>and</strong> kidney effects based on animal data.<br />

Chronic toxicity: Prolonged exposure may cause liver <strong>and</strong> kidney effects based on<br />

animal data.<br />

Medical Conditions Aggravated by Exposure: None currently known.<br />

Carcinogenicity Data: None of the components of this product is listed as a carcinogen<br />

by IARC, NTP or OSHA.<br />

Reproductive Toxicity: No adverse effects on reproduction are known.<br />

Acute Toxicity Values: No data available<br />

12. ECOLOGICAL INFORMATION<br />

2,4-di-tert-butyl-6-(5-chlorobenzotriazol-2-yl)<br />

phenol<br />

LC50 Fish >100 mg/L.EC50 Daphnia 16<br />

mg/L.Not Biodegradable.<br />

13. DISPOSAL CONSIDERATIONS<br />

Dispose in accordance with all state, local <strong>and</strong> federal regulations.<br />

14. TRANSPORT INFORMATION<br />

US DOT Shipping Description: Not regulated<br />

IATA Shipping Description (Air): Not regulated<br />

IMDG Shipping Description (Vessel): Not regulated<br />

15. REGULATORY INFORMATION<br />

US Regulations<br />

EPA Toxic Substances Control Act (TSCA): All of the components of this product<br />

are listed on the TSCA Inventory or exempted from TSCA.<br />

SARA 302 Listed Chemicals: None.<br />

SARA 311/312 Hazard Categories: Chronic <strong>Health</strong><br />

SARA 313 This Product Contains the Following Chemicals Subject to<br />

Annual Release Reporting Requirements Under the SARA Section 313 (40<br />

CFR 372): None.<br />

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<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

TINUVIN327-ESTANE<br />

California Proposition 65: This product does not contain chemicals listed per the Safe<br />

Drinking Water <strong>and</strong> Toxic Enforcement Act of 1986.<br />

International Regulations<br />

Canadian WHMIS Classification:<br />

Chronic Effects<br />

This product has been classified in accordance with the hazard criteria of the CPR <strong>and</strong> the<br />

MSDS contains all the information required by the CPR.<br />

EU EINECS Status: All of the components of this product are listed on the EINECS<br />

Inventory or exempted from notification.<br />

EU Labeling:<br />

R48/22 - Harmful: danger of serious damage to health by prolonged exposure if swallowed.<br />

S36 - Wear suitable protective clothing.<br />

16. OTHER INFORMATION<br />

HMIS Rating: <strong>Health</strong> 2 Fire 1 Reactivity 0<br />

The information is true <strong>and</strong> correct to the best of our knowledge; however, no warranty,<br />

expressed or implied, is made. Nothing should be interpreted as a recommendation to<br />

infringe on existing patents or violate any regulations. Final determination of the suitability<br />

of the material is the sole responsibility of the user.<br />

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