Safety Data Sheet - Buchem Chemie + Technik Gmbh und Co. KG

SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Trennmittel / Release Agent C5 AEROSOL
Revision date: Print date: Version: 01
03.2012 29.03.12
1. SUBSTANCE, PREPARATION AND COMPANY IDENTIFICATION
Product information
TRADE NAME : Trennmittel C5 silikonfrei
Branch of industry : Plastics processing
Main use : Manufacture of moulded plastic parts
Application : Care, release and lubricating spray
COMPANY : buchem: chemie + technik GmbH & Co.KG
Albert-Einstein-Str.8, 42929 Wermelskirchen, Germany
Telephone : +49 2196 7277-0
Fax : +49 2196 5843
E-mail : buchem@buchem.de
Contact address : Henning Rehse
Telephone: +49 2196 3933
Fax: +49 2196 974878
Emergency telephone : +49 171 3401418
2. POSSIBLE HAZARDS:
Hazard designation:
F+ Extremely flammable
Special hazard information for man R12 Extremely flammable
and the environment: R52/53 Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment
R67 Vapours may cause drowsiness and dizziness
3. COMPOSITION/CONSTITUENT DATA:
Chemical : Pressurized gas container with a preparation containing
characterisation special boiling point petrol and triglyceride mixture of
higher fatty acids
Constituent substances CAS No. EINECS No. Symbol(s): R-phrases Concentration
Triglyceride mixture of
higher fatty acids
Pressurized gas mixture of
propane and n-butane
Aliphatic hydrocarbons
74-98-6
106-97-8
64742-49-0
200-827-9
203-448-7
265-151-9
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F+
Xn*, N
12
R 38, 51/53,
65*, 67
*Not applicable to aerosol packaging (RL 67/548/EEC, Appendix 6, Number 9.4.)
45 - 65%
25%

SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Trennmittel / Release Agent C5 AEROSOL
Revision date: Print date: Version: 01
03.2012 29.03.12
4. FIRST AID MEASURES:
General instructions : If symptoms persist seek medical attention.
Eye contact : Flush the eyes for several minutes under running water
or sterile eye-rinse fluid with the eyelids held open. If
symptoms persist, seek medical advice.
Skin contact : Wash off immediately with soap and water and rinse
thoroughly.
If skin irritation persists, seek medical attention.
Inhalation : Move to area with plenty of fresh air and seek medical
attention. In the case of unconsciousness, maintain and
transport person lying on their side.
Ingestion : Do not induce vomiting; seek medical attention
immediately.
5. MEASURES IN THE CASE OF FIRE
Suitable extinguishing media : CO2, powder fire extinguisher or water jet. In the case of
lager fires use water hose jet or alcohol-resistant foam to
fight the fire.
Special hazards present with the If heated or in the case of fire, production of poisonous gases
substance, its products of combustion is possible (CO)
or the gases produced. :
Special protective equipment Wear breathing apparatus with self-contained air supply
to be used when fire-fighting. : Wear whole-body protective suit
Unsuitable extinguishing medium High pressure water jet
for reasons of safety. :
Additional data: : If no direct fire effects or intense heat has yet occurred
move the stored material to a location free of hazards
or protect against overheating (e.g. by spraying with water.
With the bursting of overheated pressurized gas containers,
these are ejected with great force – risk of injury, risk of
explosive vapours.
6. MEASURES IN THE CASE OF ACCIDENTAL RELEASE
Safety measures for Provide sufficient ventilation
personal protection : Remove sources of ignition
Wear protective gloves
Separate out leaking containers.
Environmental protection measures : Prevent entry into drains, ditches and cellars.
In the case of entry into bodies of water or drains, inform
the relevant authorities.
Cleaning/absorbing procedures : Remove with absorbent material for fluids (sand,
diatomaceous earth, acid binder, universal binder, sawdust).
Dispose of contaminated material as special waste.
Additional information : not available
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SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Trennmittel / Release Agent C5 AEROSOL
Revision date: Print date: Version: 01
03.2012 29.03.12
7. HANDLING AND STORAGE:
Handling:
Information for safe Keep containers tightly sealed.
handling : Ensure good ventilation/extraction at the workplace.
Prevent aerosol formation or carry out checks.
Use equipment items resistant to solvents.
Information for fire and Container is under pressure
explosion prevention : Protect from the sun’s rays and temperatures above 50°C.
Even after use, do not use force to open containers
and do not incinerate.
Do not spray on to flames or glowing objects.
Keep away from ignition sources. Do not smoke.
Storage:
Requirements of storage rooms Well-ventilated rooms free of frost, heat and moisture.
and containers : Observe storage regulations according to TRG 300
(Technical rules for compressed gases)
Information for mixed storage : Mixed storage of pressurized gas containers together with
flammable liquids, see No. 6.11 Par. 6 TRbF 110 (German)
Technical rules for flammable liquids.
Pressurized gas containers which contain hazardous
substances, see §24 GefStoffV (German) Hazardous Goods
Ordinance.
Additional data on
storage conditions :
Storage class : TRG 300 (Technical rules for compressed gases)
8. EXPOSURE LIMITS AND PERSONAL PROTECTIVE EQUIPMENT
Additional information for the design No further data available
of technical installations : See Point 7
Constituent substances with monitoring limit values for the workplace:
Pressurized gas mixture of propane/n-butane: MAK: 1,000 ppm
Aliphatic hydrocarbons: MAK: 350 ppm
Personal protective equipment
Breathing protection : ---
Hand protection : ---
Eye protection : ---
Skin and body protection : ---
Hygiene measures : Ensure sufficient ventilation is provided.
Prevent contact with skin and eyes.
Do not eat or smoke.
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SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Trennmittel / Release Agent C5 AEROSOL
Revision date: Print date: Version: 01
03.2012 29.03.12
9. PHYSICAL AND CHEMICAL PROPERTIES:
Physical appearance
Colour : Colourless/clear
Form : Aerosol/liquid
Odour : Product-specific
Additional data
Change of state : Quantities of the pressurizing gas which are sprayed
out immediately become gaseous. The sprayed
solvent evaporates rapidly.
Boiling point/boiling range : n/a*
Melting point/melting range : n/a*
Flash point (propellant gas) : n/a*
Ignition temperature : Spray mist is extremely flammable*
Upper explosion limit : n/a*
Lower explosion limit : n/a*
Vapour pressure : n/a*
Density at 20°C : 0.628 g/cm 3
Solubility : n/a
Water solubility at 20°C : Insoluble
pH value at 20°C : n/a
Dynamic viscosity : n/a
Final preparation of the pressurized gas container is only complete after addition of the pressurizing gas.
* These data cannot be measured in the case of the hermetically-sealed containers listed below.
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SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Trennmittel / Release Agent C5 AEROSOL
Revision date: Print date: Version: 01
03.2012 29.03.12
10. STABILITY AND REACTIVITY:
Conditions which should be avoided : Heat effects
Airborne or impact sparks.
Increased pressure leads to a risk of bursting
Container is under pressure. Protect from the sun’s
rays and temperatures above 50°C.
Even after use, do not use force to open containers
and do not incinerate.
Prevent build-up of electrostatic charge.
No decomposition occurs when used according
to instructions
Dangerous reactions : Forms explosive gas mixtures with air.
Reacts with strong oxidizing agents.
Dangerous decomposition products : Carbon monoxide and carbon dioxide,
flammable gases and vapours.
11. TOXICOLOGICAL DATA:
Acute toxicity
Relevant LD/LC50 classification values:
Constituent: Type: Value Species
Press. gas mix. of propane/butane: Inhalation 4h >20mg/l Rat
Aliphatic hydrocarbons Oral >2,000mg/kg Rat
Skin irritation : Non-irritating
Eye irritation : Weakly irritating
Sensitisation : No known sensitisation effect
Additional toxicological Direct inhalation of spray mist/vapours in
information : high concentrations has an anaesthetic action.
12. ECOLOGICAL DATA
Data on elimination (persistence and degradability)
Biological degradability :
General instructions : Water hazard class 1 (KbwS classification,
German):
low hazard to waters
Do not allow product to enter groundwater, bodies of water, drains or the ground.
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SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Trennmittel / Release Agent C5 AEROSOL
Revision date: Print date: Version: 01
03.2012 29.03.12
13. DISPOSAL INFORMATION
� Product:
� Emptied by spraying = residue-emptied pressurized gas containers according to § 3 Par. 11, of
the Packaging Ordinance (German). EAK No.: 150104 Metal packaging
� Filled pressurized gas containers EAK No.: 070604 Other organic solvents
� Recommendation: Filled pressurized gas containers, including those with
residual contents, are special waste and must be
disposed of accordingly. Deliver only fully-emptied
pressurized gas containers to the material recycling
collection point.
14. TRANSPORT DATA
� Land transport ADR/RID (transfrontier/inland):
� ADR/RID-GGVS/E Class: 2
� Number: 5F
� UN number: 1950
� Description of the good: Pressurized gas containers, 2, 5F, LQ2 (LQ=Limited
quantities)
� Sea transport IMDG/GGV Sea:
� IMDG / GGV Sea class: 2.1
� UN number: 1950
� EmS: 2-13
� MFAG: 620
� Correct technical name: Aerosols
� Remark on the delivery document: Carriage according to 28th Amdt., limited quantities.
� Air transport ICAO-TI and IATA-DGR:
� ICAO / IATA Class: 2.1
� UN/ID number: 1950
� Packaging group: -
� Correct technical name: Aerosols, flammable
� Additional information: UN-tested packaging prescribed
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15. REGULATIONS
SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Trennmittel / Release Agent C5 AEROSOL
Revision date: Print date: Version: 01
03.2012 29.03.12
Regulations :
Labelling according to the Hazardous Substances Ordinance and the EC Directive 1999/45/EC for the
classification, packaging and labelling of hazardous substances and preparations.
Aerosol Directive 75/324/EEC of 20.05.1975
amended by the Aerosol Directive 94/1/EC of 06.01.1994
Identification letter and hazard designation F+ Extremely flammable
of the product :
R-phrases : R 12 Extremely flammable
R 52/53 Harmful to aquatic organisms; can have
harmful long-term effects in bodies
of water.
R 67 Vapours can cause drowsiness
and stupor.
S-phrases :
According to Appendix of the Aerosol Directive, Point 2.2, Letter a:
“Container is under pressure. Protect from the sun’s rays and from temperatures above 50°C.
Even after use, do not use force to open containers and do not incinerate.”
According to Appendix of the Aerosol Directive, Point 2.3, Letter b:
“Do not spray on to flames or glowing objects. Keep away from ignition sources –
do not smoke. Must be kept out of the reach of children.”
Voluntary addition:
“Unless sufficient ventilation is provided, the formation of explosive mixtures is possible.”
Hazard-determining constituents for labelling:
Container is under pressure. Protect from the sun’s rays and from temperatures above 50 °C.
Even after use, do not use force to open containers and do not incinerate. Do not spray on to flames
or hot glowing objects. Keep away from ignition sources – do not smoke. Must be kept out of the
reach of children. Unless sufficient ventilation is provided, the formation of explosive mixtures
is possible. Harmful to aquatic organisms; can have harmful long-term effects in bodies of
water. Vapours can cause drowsiness and stupor.
National regulations: Hazardous Substances Ordinance (German), TRG 300 and Aerosol Directive
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SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Trennmittel / Release Agent C5 AEROSOL
Revision date: Print date: Version: 01
03.2012 29.03.12
16. ADDITIONAL DATA
The data are based on our best knowledge at the time of compilation. However, the data do not provide a
guarantee of product properties and do not establish a legal contractual relationship.
Data sheet issuing authority: Rehse GbR (Partnership under the German Civil Code)
Contact person: Henning Rehse, Tel.: 02196/3933, 01713401418
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