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Functional properties of foods. Database and model prediction

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content, feed rate, screw speed, screw configuration. Other affecting factors may include raw material<br />

formulation, pre-processing treatments, initial particle size <strong>of</strong> milled materials, <strong>and</strong> the milling procedure. A<br />

preliminary statistical investigation shows that we have a strong relationship between WAI or WSI <strong>and</strong> 4<br />

independent variables such as die temperature, feed moisture content <strong>of</strong> food product in wet base %, screw<br />

speed <strong>of</strong> extruder <strong>and</strong> blend level% mainly for starchy <strong>and</strong> proteinaceous extruded food products. It is found<br />

from the <strong>model</strong>ling exercise that using a <strong>model</strong>, which considers power law dependency <strong>of</strong> all independent<br />

variables, provides the best performance in the <strong>model</strong>:<br />

WAI or WSI<br />

<br />

a <br />

<br />

T<br />

T o<br />

where WAI: water absorption index (dimensionless), WSI: water solubility index (%), T: die temperature <strong>of</strong><br />

extruder ( o C), X: feed moisture content <strong>of</strong> food product in wet base %, S: screw speed <strong>of</strong> extruder (rpm), M:<br />

mixture <strong>of</strong> blend %, variables with subscripts: reference steady average values <strong>of</strong> independent variables,<br />

a,b,c,d,e: dimensionless adjustment parameters.<br />

Similarly, concerning the property <strong>of</strong> PDI the intended <strong>model</strong> is:<br />

b<br />

PDI a <br />

T <br />

<br />

<br />

T <br />

o <br />

t<br />

t<br />

where PDI: protein dispersibility index (%), T: is the temperature <strong>of</strong> the product which was exposed during<br />

preparation ( o C), t: is the corresponding residence time (10 3 *s), variables with subscripts: reference steady<br />

average values <strong>of</strong> independent variables, a,b,c: dimensionless adjustment parameters.<br />

The parameter estimation was performed by the Levenberg–Marquardt (LM) algorithm. The LM algorithm is<br />

an iterative technique that locates the minimum <strong>of</strong> a multivariate function that is expressed as the sum <strong>of</strong><br />

squares <strong>of</strong> nonlinear real-valued functions. The s<strong>of</strong>tware package Stargraphics Centurion v. XV (Manugistics<br />

Inc. Rockville, MD, USA) was used for the nonlinear regression analysis.<br />

RESULTS & DISCUSSION<br />

b c<br />

X <br />

<br />

<br />

X<br />

<br />

o <br />

c<br />

<br />

<br />

o <br />

Table 1 presents, in a compact form, the main information concerning the examinee <strong>properties</strong>. The<br />

minimum, maximum, average values <strong>and</strong> the st<strong>and</strong>ard deviation for each <strong>of</strong> six <strong>properties</strong> are presented in the<br />

first four columns. The main food systems <strong>and</strong> the factors which altered the value <strong>of</strong> <strong>properties</strong> are presented<br />

in the fifth <strong>and</strong> sixth columns respectively. Finally, the total number <strong>of</strong> experimental data which was<br />

retrieved is presented in the final column.<br />

Table 1. Data compiled from literature about examinee functional <strong>properties</strong> used in statistical analysis<br />

Property MIN MAX AVG SD a Food System Main Factor N b<br />

WAI 0.3 14.4 4.8 1.9 Corn, Wheat,<br />

Rice Flours<br />

WSI 0.2 94.8 22.4 15.4 Corn, Wheat,<br />

Rice Flours<br />

PDI 1.3 100.0 42.0 42.0 Soybean<br />

Products<br />

NSI 2.5 94.0 40.7 19.4 Soybean<br />

Products<br />

Extrusion parameters,<br />

blends<br />

Extrusion parameters,<br />

blends<br />

pH, Heat, Enzymatic<br />

Hydrolysis<br />

pH, Heat, Enzymatic<br />

Hydrolysis<br />

GI 1.0 100.0 71.0 25.1 Wheat Products Genotype, Fertilization,<br />

Location, Subunits<br />

WG 0.2 60.9 29.6 9.2 Wheat Products Genotype, Fertilization,<br />

Location, Subunits<br />

a St<strong>and</strong>ard Deviation; b Number <strong>of</strong> retrieved data<br />

S<br />

S o<br />

d e<br />

M<br />

<br />

<br />

M<br />

<br />

o <br />

Due to the large number <strong>of</strong> replicates, a fundamental prerequisite for the least squares fitting <strong>of</strong> the <strong>model</strong>s to<br />

the corresponding data sets is equal variance <strong>of</strong> the different observations. The results <strong>of</strong> these tests show that<br />

the variance was almost steady. The results <strong>of</strong> the nonlinear regression analysis <strong>of</strong> fitting the equation 1 to the<br />

experimental points are shown in Table 2. In this table the st<strong>and</strong>ard experimental error <strong>and</strong> the st<strong>and</strong>ard<br />

deviation between experimental <strong>and</strong> calculated values are also presented. In most cases the values <strong>of</strong> the<br />

1268<br />

1083<br />

1067<br />

780<br />

3400<br />

2354<br />

(1)<br />

(2)

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