Safety Data Sheet - Buchem Chemie + Technik Gmbh und Co. KG

SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Reiniger SE Aerosol
Revision date: Print date: Version: 01
11.2011 09.05.12
1. SUBSTANCE, PREPARATION AND COMPANY IDENTIFICATION
Product information
TRADE NAME : Reiniger SE
Branch of industry : Tool manufacture
Main use : Manufacture of tools
Application : Cleaner
COMPANY : buchem: chemie + technik GmbH & Co.KG
Albert-Einstein-Str.8, 42929 Wermelskirchen, Germany
Telephone : +49 2196 7277-0
Fax : +49 2196 5843
E-mail : buchem@buchem.de
Contact address : Henning Rehse
Telephone: +49 2196 3933
Fax: +49 2196 974878
Emergency telephone : +49 171 3401418
2. HAZARDS IDENTIFICATION:
2.1 Classification of the substance or mixture:
Classification (67/548/EWG, 1999/45/EC)
Extremely Flammable R 12 Extremely Flammable
Irritant R 41 Risk of serious injury to the eyes
R 67 Vapours may cause drowsiness and dizziness
2.2. Label Elements
Labelling according to EC Directives (1999/45/EC)
Hazard pictograms
Xi Irritant
F+ Extremely flammable
R-phrases R 12 Extremely Flammable
R 41 Risk of serious injury to the eyes
R 67 Vapours may cause drowsiness and dizziness
S-phrases S 2 Keep out of the reach of children
S 16 Keep away from sources of ignition - No smoking
S 23 Do not breathe spray
Special labelling of certain mixtures: Pressurized container.
Protect from sunlight and do not expose to temperatures
exceeding 50°C.
1/10

SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Reiniger SE Aerosol
Revision date: Print date: Version: 01
2.3 Other hazards
none
11.2011 09.05.12
3. COMPOSITION/CONSTITUENT DATA:
Chemical :
characterisation
Constituent substances CAS No. Einecs
No.
n-Butan compressed
Propan gas mixture
γ -Butyrolacton
2-Aminoethanol
γ-Aminobutyrolactam
2-Propanol
106-97-8
74-98-6
96-48-0
141-43-5
616-45-5
67-63-0
* Not applicable for aerosol dispensers
4. FIRST AID MEASURES:
203-448-7
200-827-9
202-509-5
205-483-3
210-483-1
200-661-7
Do not pierce or burn, even after use.
Do not spray on naked flame or any other incandescent
material.
Keep away from sources of ignition - No smoking
Keep out of the reach of children
2/10
Symbol(s):
(67/548/EEC)
F+
F+
Xn*, Xi
C, Xn*
Xn*, Xi
Xi
R-phrases
(67/548/EEC)
R 12
R 12
R 22*, R 41
R 34, 20/21, 22*
R 22*, 36/38
R 11, 36, 67
General instructions : Consult a doctor if symptoms persist
Concentration
5-15%
5-15%
10-30%
< 1%
< 1%
< 15%
Eye contact : Opened eye for several minutes rinse with running water.
Protect unharmed eye.
Seek medical attention immediately.
Skin contact : Wash with soap and water.
Consult a doctor if skin irritation.
Inhalation : Fresh air, if necessary artificial respiration
Seek medical advice
Ingestion : Seek medical attention immediately

SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Reiniger SE Aerosol
Revision date: Print date: Version: 01
11.2011 09.05.12
5. MEASURES IN THE CASE OF FIRE
Suitable extinguishing media : CO2, powder fire extinguisher or water spray jet. In the case
of larger fires use water spray jet or alcohol-resistant foam
to fight the fire.
Special hazards present with the If heated or in the case of fire, poisonous gases are
substance, its products of combustion possible (CO, NOx)
or the gases produced :
Special protective equipment Wear breathing apparatus with self-contained air supply
to be used when fire-fighting : Wear whole-body protective suit
Unsuitable extinguishing medium High pressure water jet
for reasons of safety :
Additional data : Containers in vicinity of fire should be cooled with water
spray jet. Vapours are heavier than air and spread out
at floor level.
Flammable liquid can float on the water surface.
Heating leads to increased pressure and bursting of the
containers.
6. MEASURES IN THE CASE OF ACCIDENTAL RELEASE
Safety measures for Wear breathing apparatus. Wear protective equipment.
personal protection : Keep unprotected persons away.
Ensure sufficient ventilation.
Remove ignition sources from vicinity.
Prevent contact with the skin and the eyes.
Do not breathe the vapour/aerosol.
Environmental protection measures : Prevent entry into drains, ditches and cellars.
In the case of entry into bodies of water or drains, inform
the relevant authorities.
Cleaning/absorbing procedures : Remove with absorbent material for fluids (sand,
diatomaceous earth, acid binder, universal binder, sawdust).
Dispose of contaminated material as waste in accordance
with Point 13.
Ensure sufficient ventilation.
Additional information : not available
3/10

SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Reiniger SE Aerosol
Revision date: Print date: Version: 01
11.2011 09.05.12
7. HANDLING AND STORAGE:
Handling:
Information for safe handling and
protection against fire and explosion : Pressurized container.
Protect from sunlight and temperatures above 50° C.
Not pierce or burn even after use.
Do not spray on naked flame or any incandescent material.
Keep away from ignition sources - No smoking.
Without adequate ventilation formation of explosive
mixtures possible.
Keep out of reach of children.
Do not breathe spray.
Never doses in the range of spark ignition or heat sources,
place or store.
Risk of serious damage to eyes. In case of contact with eyes,
rinse immediately with plenty of water and seek medical
advice.
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and
containers : Keep container tightly closed.
Keep in a well-ventilated place.
Keep away from heat.
Advice on common storage : No materials to be especially mentioned.
German storage class : 2B Compressed Gas (Aerosol cans)
Other data: : Sore in cool place.
4/10

SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Reiniger SE Aerosol
Revision date: Print date: Version: 01
11.2011 09.05.12
8. EXPOSURE LIMITS AND PERSONAL PROTECTIVE EQUIPMENT
Additional information for the design No further data available
of technical installations : See Point 7
Constituent substances with monitoring limit values for the workplace:
CAS-Nr. Name % Type Data Unit
106-97-8 n-Butan

SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Reiniger SE Aerosol
Revision date: Print date: Version: 01
11.2011 09.05.12
9. PHYSICAL AND CHEMICAL PROPERTIES:
Physical appearance
Colour : Colourless/clear
Form : Aerosol/liquid
Odour : product-specific
Additional data
Change of state : pressure of gas is immediately ejected gas. Sprayed
solvents evaporate quickly.
Boiling point / range : n.a. * (Not applicable)
Flash point : n.a. *
Flammability : spray and evaporative gases are extremely
flammable
Ignition temperature : n.a. *
Auto Ignition : no
Oxidizing properties : the case of overheating
Explosion Danger : overheating rupture / bursting of the container
Formation of explosive mixtures are possible.
Explosion limits : n.a. *
Vapour pressure inside the dispenser : at 50°C maximum 2/3 of maximum pressure
allowed for the dispenser
Density, here: apparent density at 20 ° C : 0.950 g / cm ³
Solubility in water : yes
Solvent content : 30-50%
More details : * The finished preparation in the aerosol dispenser
only upon the addition of the pressurized gas.
* Details are in the hermetically sealed under
pressure not measurable container.
10. STABILITY AND REACTIVITY:
Thermal decomposition
Conditions to avoid : in danger of the heat reservoir
Incompatibility : Strong oxidizers
Dangerous products of
combustion or extreme heat : carbon monoxide (CO) and the possibility of
other unknown
6/10

SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Reiniger SE Aerosol
Revision date: Print date: Version: 01
11.2011 09.05.12
11. TOXICOLOGICAL DATA:
Acute toxicity
Relevant LD/LC50 classification values:
Component Type Data Species
Propan-Butan
Inhalation 4h > 20 mg/l rat
(pressure-gas-mixture)
gamma-Butyrolacton oral 1580 mg/kg rat
2-Propanol oral 4570 mg/kg rat
Primary irritant effect:
on the skin : irritant
on the eye : Strong irritant with the risk of eye damage.
Sensitization : No sensitizing effect known.
Additional toxicological information: Direct inhalation of spray mist or vapours at high
concentrations has narcotic effect
12. ECOLOGICAL DATA
General notes : Water hazard class 1 (Self-assessment): slightly hazardous
for water
Do not get in the ground water, water course or sewage
system.
13. DISPOSAL INFORMATION
Product :
Recommendation :
Empty aerosols acc. to § 3, 11packaging ordinance
EWC-No.: 150104 metal packaging
Filled Aerosols
EAK-No.: 070604 other organic solvents
the filled aerosol dispensers, including those with residual
contents, hazardous waste and dispose of accordingly.
Put only completely empty aerosol dispensers to resource
collection points.
7/10

SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Reiniger SE Aerosol
Revision date: Print date: Version: 01
11.2011 09.05.12
14. TRANSPORT DATA
� Land transport ADR/RID (transfrontier/inland):
� ADR/RID-GGVS/E Class: 2
� Number: 5F
� UN number: 1950
� Description of the good: Pressurized gas containers, 2, 5F, LQ2 (LQ=Limited
quantities)
� Sea transport IMDG/GGV Sea:
� IMDG / GGV Sea class: 2.1
� UN number: 1950
� EmS: 2-13
� MFAG: 620
� Correct technical name: Aerosols
� Remark on the delivery document: Carriage according to 28th Amdt., limited quantities.
� Air transport ICAO-TI and IATA-DGR:
� ICAO / IATA Class: 2.1
� UN/ID number: 1950
� Packaging group: -
� Correct technical name: Aerosols, flammable
� Additional information: UN-tested packaging prescribed
8/10

15. REGULATIONS
SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Reiniger SE Aerosol
Revision date: Print date: Version: 01
11.2011 09.05.12
Designation according to EC guidelines:
Labelling according to the Hazardous Substances Regulation and the EC Directive 1999/45/EC on the
classification, packaging and labelling of dangerous substances and preparations
Aerosol-Richtlinie 75/324/EWG v. 20.Mai 1975
geändert durch: Aerosol-Richtlinie 94/1/EG v. 06.Januar 1994
Code letter and hazard designation of product:
Xn Irritant
F+ Extremely flammable
Risk phrases:
R 12 Extremely flammable
R 41 Risk of serious damage to eyes
R 67 Vapours may cause drowsiness and dizziness
Safety phrases:
S 2 Keep out of reach of children.
S 23 Do not breathe aerosol.
S 26 In case of contact with eyes, rinse immediately with water and seek medical advice.
According to the Annex Aerosol-Richtlinie 2.2 point a:
"Container is under pressure. Protect from sunlight and temperatures above 50 ° C.
Not pierce or burn even after use.
According to the Annex Aerosol-Richtlinie 2.3 point b:
"Do not flame or incandescent spray. Keep away from sources of ignition - No smoking. Keep out of
reach of children."
Additional volunteers:
"Without sufficient ventilation formation of explosive mixtures."
Hazardous components of labelling:
Pressurized container. Protect from sunlight and temperatures above 50 ° C.
Not pierce or burn even after use.
Do not spray on naked flame or any incandescent material.
Keep away from ignition sources - No smoking.
Keep out of reach of children.
Without adequate ventilation formation of explosive mixtures possible.
Risk of serious damage to eyes. In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
Do not breathe spray.
National regulations:
Gefahrstoffverordnung, TRG 300 and Aerosol Richtlinie
9/10

SAFETY DATA SHEET according to Regulation
(EC) No. 1907/2006
Reiniger SE Aerosol
Revision date: Print date: Version: 01
11.2011 09.05.12
16. ADDITIONAL DATA
Full text of R-phrases referred to under sections 2 and 3
R 11 Highly flammable
R 12 Extremely Flammable
R 20/21 Harmful in contact with skin and if swallowed
R 22 Harmful if swallowed
R 34 Causes burns
R 36 Irritating to eyes
R 36/38 Irritating to eyes and skin
R 41 Risk of serious damage to eyes
R 67 Vapours may cause drowsiness and dizziness
This information is based on the present state of our knowledge, they do not constitute an
assurance of product properties and establishes no contract legal rights.
Reasons for change: change in formulation
Department issuing MSDS: Rehse GbR
Contact: Henning Rehse, Tel: 02196/3933, 01713401418
Data compared to the previous version altered
With the release of this MSDS, all previous versions of this product / the substance invalid. Changes
in the relevant chapters from the previous version are indicated on the right side with a red bar.
10/10