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A N T I M O N Y : ITS HISTORY, CHEMISTRY, MINERALOGY ...

A N T I M O N Y : ITS HISTORY, CHEMISTRY, MINERALOGY ...

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70 THE METALLURGY OF ANTIMONY.<br />

perature is too low the residue will contain too large a proportion<br />

of antimony, part of which at least should go to the liquated<br />

product as crude antimony. It has already been mentioned that<br />

the best size of the pieces of ore is that of walnuts; for, if the<br />

size is in any way smaller, the liquation process is less complete, and<br />

hence the residues are too rich in the sulphide ; furthermore, fine ores<br />

lie so close together as to render the escape of the fused sulphide<br />

difficult.<br />

(a) Intermittent Working.<br />

As a rule, closed furnaces use more fuel and cost more for labour<br />

than open ones (reverberatory), which, on the other hand, lose more<br />

antimony through volatilisation and oxidation than closed ones.<br />

This loss can, however, be eliminated by the use of the condensation<br />

apparatus of Herrenschmidt, to be mentioned later.<br />

The smelting is done in pots, which are either heated directly by<br />

the burning fuel or by the flame coming from a fireplace. In the<br />

liquation in pots, the working is carried on intermittently, while<br />

continuous working is permitted in that of tubes or reverberatory<br />

furnaces, thus economising the consumption of fuel.<br />

a. Intermittent Liquation in Pots in Open Fire.—Pots, being in<br />

direct contact with the fuel, are used at Wolfsberg in the Harz, at<br />

Magurka. Eosenau, and Gross-Gbllnitz in Hungary, at Milleschau in<br />

Bohemia, and at Malbosc<br />

in France. The only merit<br />

of this method is its simplicity,<br />

and for this reason<br />

it can be carried on without<br />

much difficulty at the<br />

mines. If the ores are<br />

rich and fuel (wood or<br />

coal) is cheap at" the mine,<br />

this method can be used<br />

with advantage.<br />

FIG. 3. The pots are made of<br />

fire-clay, and are able to<br />

hold from 11 to 36 lbs. There are in the bottom of each pot four or<br />

five holes, each varying from 0-4 to 0-6 inch in diameter, through which<br />

the molten sulphide escapes. Below these pots rest receivers, made<br />

of burnt clay, for the collection of the liquefied crude antimony.<br />

These receivers are embedded in sand, ashes, or breeze, thus ensuring<br />

the slow cooling of their contents. The pots are arranged in several

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