174 THE METALLURGY OF 12. Por the Fabrication of Dice-boxes, etc. An alloy of lead and antimony is used. 13. Miscellaneous Uses. (a) If fluoride of antimony is heated with the sulphide, the sulphochloride is formed. It is used in medicine, or as a corrosive and macerating agent for wool. (6) It has been proposed to use beurre tfantimoine in the manufacture of matches without phosphorus. (c) Oxide of antimony is used in the manufacture of artistic abat-jour (lamp-shades) and reflecteur en verre jawne opaque (yellow opaque glass reflector). (d) Antimony salts, particularly combined with fibrocol,* are very good antiseptics for incorporation with lime-wash and with the paste t used in the papiers couches of painters. (e) Thermo-electric couples. BIBLIOGRAPHY Off THE ANTIMONY PREPARATIONS AND THEIR USES. ALLOYS. 1. Baykoff, "Les alliages de cuivre et d'antimoine," Bull, de la Soe. d? Encouragement, 1903, pp. 626-640. • 2. Brannt, W. T., The Metallic Alloys; London, Sampson Low, Marston & Co., 1896 (General). 3. Brenil, Genie civil, Sept. 12, 1903 ("Machines a essayer an frottement; anti-friction "). 4=. Campbell, "Structure of Alloys," /. Am. Chem, JSoc., xxvi. pp. 1306-15 (Tin and antimony). 5. Chabal, JUvue g&Uraledes Chemins defer, 1894 (" Essais pratiques "). 6. Charpy, M. G., " Les alliages blancs dits anti-friction : Contr. k l'^tude des alliages," Soe. d'Biumiragement pour Vlnd. nat, pp. 203-240 ; Paris, Typo. Chamerot et Eenonard, 1901 ; also p. 12 (Sb-Ag). 7. Clamer, Journ. of the Franklin In$t.} clvi. pp. 49-77, 1903 (Anti-friction). &. Dudley, Revue gtvdrple des CJumhis defer, June 1893 (" Essais de Antifriction"). 9. Fay and Ashley, " Alloys of Antimony and Tellurium," Chem. Journ., ixvii, 1902, pp. 95-105. * Proposed by Hy vert in his book Lt Fibrocol. t Ordinary paste is a colloidal substance, giving rise to anticelluloid fermentation due to Bacillus arriylobaeter and Bacillus biUyrieus.
THE ANTIMONY PREPABATIONS AND THEIR USES. 175 10. Fraenkel, '' Untersuchung Zinn- und Antimonhaltigen Legierungen," Mitth. des k. Jc. technologischen Gewerbe-Museum zu Wien, viii., 1898, pp. 334-336. 11. Gallagher, "Alloys of Antimony and Tin," Journ. of Phys. Chem., vol. x. pp. 93-98. 12. Gautier, "Contribution a l'etude des alliages metalliques," Soc. d'Encourag., p. 93 (Fusibilite de Al-Sb et Ag-Sb). 13. Gosselin, Eol., u Contribution a l'etude des alliages me'talliques," p. 114 (Sb-Bi). 14. Gosselin, Eol., " Contrib. a l'etude des allia. met. : Memoire de M. Gautier," pp. Ill et 108 (Zn-Sb et Sn-Sb). 15. Guettier, Le guide, dufondeur (Sb-As). 16. Gulllemin, Commission des mithodes d J essais, 1894 (Anti-friction). 17. Guillet, Le"on, JzJlude industrielle des alliages m6talliqy.es, Paris JET. Dunod, 1906. 18. Herschkowitsch, Zeit. /. phys. Chemie, t. xxvii. p. 123 (Zn-Sb). 19. Heycock and Neville, Transactions of Royal Society and Journal o) the Chemical Society, 1890. 20. Hiorns, Mixed Metals, Macmillan & Co., London, 1901. 21. Homer, J. G-., The Encyclopaedia, of Practical Eng. and Allied Trades, vol. i. p. 151; London, Virtue & Co. 22. Howe, H. ML, Iron, Steel, and other Alloys, N.Y., 1905. 23. Hyvert, G., TechnologiedeVantimoine, Carcassonne, G-. Serviere, 1906. 24. Kamensky, Philosoph. Mag., ivii., 1884, p. 270(Cu-Sb). 25. Knab, Traiti des alliages me'talliques (General). 26. Laurie, Journ. of Chem. Industry, cccii. p. 104 (Sn-Sb and Zn-Sb). 27. Law, E. P., Alloys; London, Charles Griffin & Co., 1908. 28. Lossew, " Legierungen des Mckels mit Antimon," Z. anorg. Chem., pp. 58-71, 1906. 29. " Merkwiirdige Legierung aus Antimon und Aluminium," Prom,, xiv., 1903, • p. 320. 30. Metallographist, 6 vols. only, published at Boston by Sauveur. 31. Mozo, Bull, de la Soc. des Ingdnieurs civils, 1852 (Essais pratiques de anti-friction). 32. Pe'cheux, Comptes rendus, June 20, 1904 ($tude chimiquo, Al-Sb). 33. Pelabon, "Les melanges d'antimoine et de tellure, d'antimoiUe et de selenium," Comp. rend., cxlii. pp. 207-260, 1906. 34. Eeindera, "Alloys of Tin and Antimony," App. III. to 6th Report to the Alloys Research Committee, Proc. Mech. Eng., 1904, pp. 209-214. 35. Revue {La) de chimie industrielle, Paris, 19 e annee, No. 222, Juin 1908, pp. 164-169. 36. Eoberts-Austen, Reports 1 to 6, Alloys Research Committee of the Inst. of Mech. Eng., London, 1891-99. 37. Eoberts-Austen, Introduction to the Study of Metallurgy, Cantor Lectures on Alloys delivered at the Society of Arts, 1834-1901. 38. Eoberts-Austen and Stanfield, La constitution des alliages me'talliques: Report of the Physical Corigress, Paris, 1900, vol. i. ; Gauthier Villars. 39. Salomon, Bull, de la Commission internat de.s Congres des chemins de ftr, 1896 (Essais). 40. Spring, W., Bull, de VAcadimie roy. de Behjujue, 1878.
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A N T I M O N Y : ITS HISTORY, CHEM
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PREFACE. A METALLURGICAL work in En
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TABLE OF CONTENTS. CHAPTER I. THE H
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THE CHEMISTRY OF ANTIMONY. 7 antimo
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THE CHEMISTKY OF ANTIMONY. compound
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Chemical Formulae. K3SbCl6 Na3SbCl6
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THE CHEMISTRY OF ANTIMONY. 19 The o
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THE CHEMISTKY OF ANTIMONY. 21 a cop
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Chemical Composition. (STH4)2Sb4S7
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CHAPTER TIT. THE MINERALOGY OF ANTI
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TI1K ISKOIJOGIOAL OOCURUKNOK OV ANT
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CHAPTER V.* THE METALLUBGY OF ANTIM
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