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A N T I M O N Y : ITS HISTORY, CHEMISTRY, MINERALOGY ...

A N T I M O N Y : ITS HISTORY, CHEMISTRY, MINERALOGY ...

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THE ANTIMONY PREPARATIONS AND THEIR USES. 151<br />

(e) Other Alloys of Less Importance.—An alloy for making the<br />

nails to be used in ships consists of : tin 50 per cent., lead 33 per cent.,<br />

and antimony 17 per cent.; or 3 parts tin, 2 parts lead, and 1 part<br />

antimony. It is specially resistant against the continued action of<br />

water and atmosphere.<br />

Metallic mirrors, buttons, etc., have been made from the following<br />

alloys:—<br />

Antimony, silver, copper, zinc.<br />

„ tin, zinc, steel.<br />

,, copper, iron, lead.<br />

,, copper, tin, zinc.<br />

,, copper, tin, lead.<br />

Alloys of Antimony and Hydrogen.—Antimony hydride is rather a<br />

chemical compound than an alloy, and is generally in the form of a<br />

gas. As a solid alloy it can be obtained by sending a current through<br />

a dilute sulphuric acid bath, the metal antimony being then negative.<br />

The hydrogen thus disengaged unites with the antimony to form<br />

brown flakes. If bichloride of mercury is introduced into the bath,<br />

an alloy consisting of hydrogen, antimony, and mercury is obtained,<br />

which becomes very unstable as soon as the galvanic current is<br />

stopped. The phenomenon of dissociation is accompanied by a<br />

development of heat and electricity, thus producing a reversing<br />

secondary current. Although the study of this curious and delicate<br />

reaction is still not far advanced, yet the results already obtained<br />

promise well for its future use in thp manufacture of secondary poles<br />

and ticcumulators.<br />

Antimony Amalgam.—Mercury dissolves antimony in different<br />

proportions, and forms white alloys, the fluidity of which decreases<br />

proportionately as the percentage of antimony increases. When in<br />

a solid state they are so fragile that they break up under the slightest<br />

shock. They are of theoretical interest only.<br />

Alloys of Antimony and the Alkalies.—Potash and soda are reduced<br />

with great facility by carbon in the presence of antimony, forming<br />

alloys which may contain the alkaline metals up to 25 per cent.<br />

This alloy is ordinarily prepared by heating to red heat for two or<br />

three hours a mixture of 6 parts of tartar emetic and 1 part of nitre,<br />

or equal parts of antimony and roasted cream of tartar. The metallic<br />

button thus obtained is very compact, greenish gray in colour, brittle,<br />

and lamellar in structure. It possesses some of the properties of<br />

potassium; when exposed to humid air it inflames rapidly; in water, it<br />

sets the hydrogen free, leaving behind a residue of antimony, while<br />

the potash remains in solution. In contact with mercury, the anti-

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