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A N T I M O N Y : ITS HISTORY, CHEMISTRY, MINERALOGY ...

A N T I M O N Y : ITS HISTORY, CHEMISTRY, MINERALOGY ...

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128 THE METALLURGY OF ANTIMONY.<br />

sodium sulphide solution and then boiled repeatedly with water;<br />

they are then allowed to pass through o into the filter p, where<br />

they are washed again with hot water. The wash-waters collected<br />

in the holder q are used again for washing other residues. Such a<br />

plant can extract 6 to 8 cwts. of antimony from its ores containing<br />

less than 10 per cent, of the metal in twelve hours.<br />

Figs. 57 and 58 show the arrangement of the electrolytic baths on<br />

a large scale. A are the anodes, K the cathodes, which are hung in<br />

iron baths. The cathodes are of sheet-iron and bolted on to the<br />

rails T, and rest directly upon the rim of the baths, so that the<br />

baths also serve as cathodes. The anodes are plates of lead suspended<br />

FIG. 58.<br />

from iron rails, resting upon the positive leads, which are isolated by<br />

resting on the wooden bars J. The electrolyte is fod through the<br />

three-way cock D under the bath, since it becomes less dense as the<br />

antimony is removed. The outlet is through G by means of the<br />

rubber pipes S into the next bath. In order to effect an oven distribution<br />

of the incoming electrolyte, a plate, V, is riveted upon and along<br />

the bottom of the bath; over this plate is another ono, U, which<br />

is so attached that there is a little space between the two, the two<br />

thus forming a channel.<br />

With concentrated solutions electrolysis may be commenced with<br />

a current of 100 to 150 amperes per square metre (0'064 to 0*1<br />

ampere per square inch), which may gradually be reduced to 40 or 45

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