26.10.2012 Views

A N T I M O N Y : ITS HISTORY, CHEMISTRY, MINERALOGY ...

A N T I M O N Y : ITS HISTORY, CHEMISTRY, MINERALOGY ...

A N T I M O N Y : ITS HISTORY, CHEMISTRY, MINERALOGY ...

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

124 THE METALLURGY OF ANTIMONY.<br />

The following analyses refer to material from the mine La Lucette;<br />

the quantities are those yielded per ton:—<br />

Antimony, kilos .<br />

Gold, grammes .<br />

Waste ground by<br />

Crushing<br />

Mill.<br />

10'9<br />

6<br />

Ball<br />

Mill.<br />

9*5<br />

5<br />

Concentrates<br />

from "Waste.<br />

Sample Sample<br />

II.<br />

1141<br />

34<br />

97*5<br />

214<br />

Mixed<br />

Materials.<br />

14*6<br />

1<br />

Tailings.<br />

6-1<br />

traces<br />

(b) The Treatment of the Concentrates.—They are lixiviated in<br />

agitators with a solution of sodium sulphide. The sulphide of<br />

antimony is dissolved as double sulphide of antimony and sodium,<br />

and the gold is left in the residues.<br />

The liquor thus obtained is heated with the sulphurous acid coming<br />

direct from the roasting of pyritic ores or of the sulphide of antimony,<br />

obtained in the same process from a previous treatment. The antimony<br />

sulphide thus precipitated has a red colour. The gold residue can bo<br />

treated in a reverberatory furnace in the presence of litharge. The<br />

gold can be extracted by cupellation or by oxidation with nitrate of soda.<br />

The process is profitable with an ore containing:—<br />

Antimony, 4 per cent., or 40 kilos per ton.<br />

Gold, 12 grms. per ton.<br />

The profit is 21 frs. per ton, after subtracting the expenses. One<br />

ton of ore may cost only 6 frs. This result has boon obtained at<br />

Genest (Mayenne); France.<br />

Lyte proposes to roast antimony-bearing lead, silver, and copper<br />

ores in the presence of chlorides, to condense the antimony vapour<br />

in a solution of salt, and to precipitate the metal by iron or zinc.<br />

This process requires complicated condensing apparatus.<br />

The Utah Antimony Company, of Garfield Co., Utah, has been able<br />

to obtain a concentrate containing 65 per cent, antimony from ore<br />

containing only 11 per cent, of that metal. The mill is capable of<br />

producing 10 tons of concentrate per day.<br />

III. EXTRACTION BY ELECTROLYTIC METHODS.*<br />

It has been proposed to treat poor sulphide antimony ores, and the<br />

residue from the liquation of richer ores, with solutions of alkali-<br />

* Electric Smelting and Refining of Dr W. Borchors, translated \)y W. G.<br />

McMillan, pp. 476-487 ; London, C. Griffin & Co., 1904.

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!