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Listing of Sessions and Abstracts of Papers - History of Science ...

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E-mail Address: jjames@fas.harvard.edu<br />

Naturalizing the Odd-electron Bond<br />

Chemists <strong>and</strong> historians <strong>of</strong> chemistry alike have cited the use <strong>of</strong> odd-electron bonds as a prominent<br />

weak point in valence bond theory when compared to the rival molecular orbital theory. They have<br />

characterized odd-electron bonds as ad hoc solutions to the problems presented by a h<strong>and</strong>ful <strong>of</strong> chemical<br />

compounds <strong>and</strong> as poorly supported addenda to a theoretical edifice founded on the electron pair bond.<br />

The depth <strong>and</strong> prevalence <strong>of</strong> the unease these criticisms reflect suggest that more may be driving them<br />

than a minor point in a two-sided theory debate. Indeed closer examination <strong>of</strong> both published <strong>and</strong><br />

unpublished sources related to the construction <strong>and</strong> presentation <strong>of</strong> odd-electron bond theory by Linus<br />

Pauling <strong>and</strong> his collaborators at Caltech suggests a very different characterization. Pauling et al developed<br />

accounts <strong>of</strong> odd-electron bonds <strong>and</strong> electron pair bonds not only concurrently but conjointly. Oddelectron<br />

bonds were hardly an afterthought. Later separation <strong>of</strong> odd-electron bonds from electron pair<br />

bonds was a multi-step process, completed to differing degrees by Pauling <strong>and</strong> his detractors, <strong>and</strong> was<br />

conditioned by a network <strong>of</strong> distinct but interconnected disputes that ranged over several sub-fields <strong>of</strong><br />

chemistry <strong>and</strong> predated much <strong>of</strong> valence bond theory. Opposition to the use <strong>of</strong> odd-electron bonds in<br />

valence bond theory originated in this pre-existing network <strong>of</strong> commitments <strong>and</strong> disagreements, <strong>and</strong> fits<br />

poorly with common models that portray theoretical disputes as developing around a single dichotomous<br />

split.<br />

Jamison, Andrew<br />

E-mail Address: <strong>and</strong>y@i4.auc.dk<br />

Hybrid Identities in the Making <strong>of</strong> Western <strong>Science</strong><br />

One <strong>of</strong> the central features <strong>of</strong> the dominant mode <strong>of</strong> scientific knowledge production which emerged<br />

in Europe was the development <strong>of</strong> what might be termed hybrid identities. As opposed to the situation in<br />

other parts <strong>of</strong> the world, there were opportunities in Europe for scholars <strong>and</strong> craftsmen, for artists <strong>and</strong><br />

engineers <strong>and</strong>, perhaps most importantly, for philosophers <strong>and</strong> technicians, to interact <strong>and</strong> forge social<br />

identities that combined characteristics from what had been previously separated spheres <strong>of</strong> human<br />

activity. The construction <strong>of</strong> these hybrid proto-scientific identities played an important part in shaping<br />

new experimental ways <strong>of</strong> life, as well as in instituting the forms <strong>of</strong> organization <strong>and</strong> formulating the<br />

discursive frameworks that have proved so powerful in relation to other, non-Western modes <strong>of</strong> knowledge<br />

production. While much attention in recent years has been focused on the actual practices <strong>and</strong> sites<br />

<strong>of</strong> constructing, or, as Jan Golinksi has put it, ral knowledgeghts have only rarely been connected to<br />

work on the sociological roots <strong>of</strong> science <strong>of</strong> e.g. Edgar Zilsel <strong>and</strong> Christopher Hill. By focusing on the<br />

process <strong>of</strong> hybridization, <strong>and</strong> providing examples <strong>of</strong> several hybrid identities in the 16th <strong>and</strong> 17th centuries<br />

(e.g. Paracelsus, Tycho Brahe, Gerrard Winstanley), I try to link the new croglected broader historical<br />

concerns. The paper is a draft chapter <strong>of</strong> an ongoing ence<br />

Janssen, Michael<br />

E-mail Address: janss011@tc.umn.edu<br />

The role <strong>of</strong> unexplained coincidences in theory construction <strong>and</strong> theory choice<br />

In developing both special <strong>and</strong> general relativity, Einstein was guided not by experimental anomalies<br />

facing existing theories but by certain striking coincidences left unexplained by these theories. Think <strong>of</strong><br />

the magnet-conductor example with which he opened the 1905 paper on special relativity <strong>and</strong> <strong>of</strong> the<br />

equality <strong>of</strong> inertial <strong>and</strong> gravitational mass that formed the starting point for the development <strong>of</strong> general<br />

relativity. For Einstein <strong>and</strong> others, the explanation <strong>of</strong> such coincidences was an important virtue <strong>of</strong> the<br />

new theories. In my talk I want to explore what philosophers <strong>of</strong> science have to <strong>of</strong>fer (inferences to<br />

common causes <strong>and</strong> best explanations spring to mind) for a general account <strong>of</strong> this virtue.

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