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Underwater Mass Spectrometry: Developments and Calibration

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<strong>Calibration</strong> Results<br />

Nitrogen (m/z 28)<br />

Oxygen (m/z 32)<br />

Methane (m/z 15)<br />

<strong>Calibration</strong> Normalized at 200atm 1atm Response (78% N2, vs Pressure 21% O2, 1% (atm) CH4) 2/18/05<br />

2/18/05<br />

Instrument<br />

Normalized<br />

Response<br />

Response<br />

(A)<br />

Instrument Response (A)<br />

1.00E-07 1.20 1.0000E-07<br />

9.00E-08 9.0000E-08<br />

1.00<br />

8.00E-08 8.0000E-08<br />

7.00E-08 7.0000E-08<br />

0.80<br />

6.00E-08 6.0000E-08<br />

5.00E-08 0.60 5.0000E-08<br />

4.00E-08<br />

4.0000E-08<br />

0.40<br />

3.0000E-08<br />

3.00E-08<br />

Oxygen<br />

y = 1.742E-10x + 2.143E-08<br />

R 2 = 9.999E-01<br />

Oxygen<br />

y = 7.056E-11x + 1.690E-08<br />

R 2 = 9.994E-01<br />

Nitrogen<br />

y = 1.821E-10x + 5.175E-09<br />

R 2 = 9.999E-01<br />

2.0000E-08<br />

R 2 = 9.939E-01<br />

2.00E-08 0.20<br />

1.0000E-08<br />

1.00E-08<br />

y = 1.593E-10x + 1.573E-10<br />

Methane<br />

y R= 2 6.512E-11x = 9.995E-01+ 7.765E-11<br />

0.00 0.0000E+00<br />

Methane<br />

R 2 = 9.962E-01<br />

0.00E+00<br />

0 100 200 300 400 500 600<br />

0 0 100 50 200 100 300 150 400 200 500 250 600<br />

Concentration (umole/kg)<br />

Hydrostatic Concentration Pressure (umole/kg) (atm)<br />

Methane<br />

Nitrogen<br />

Nitrogen<br />

Oxygen y = 7.176E-11x + 3.614E-09

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