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2728 <strong>IEEE</strong> TRANSACTIONS ON ELECTRON DEVICES, VOL. 55, NO. 10, OCTOBER 2008<br />

<strong>Thermodynamics</strong> <strong>and</strong> <strong>Transport</strong> <strong>Model</strong> <strong>of</strong> <strong>Charge</strong><br />

Injection in Silicon Irradiated by a<br />

Pulsed Focused Laser<br />

Étienne Boulais, Vincent Binet, Jean-Yves Degorce, Guillaume Wild,<br />

Yvon Savaria, Fellow, <strong>IEEE</strong>, <strong>and</strong> Michel Meunier<br />

Abstract—Focused pulsed visible laser used in laser-trimming<br />

technologies such as the laser diffused-resistor process may inject<br />

charges in the semiconductor, leading to an interaction with highly<br />

sensitive circuits. In order to evaluate the process impact on those<br />

circuits, a study <strong>of</strong> the perturbation on the free-running frequency<br />

<strong>of</strong> a ring oscillator due to a nearby laser pulse has been made. The<br />

behavior <strong>of</strong> this modification as a function <strong>of</strong> the laser-pulse power<br />

exhibits complex features. A thermodynamics <strong>and</strong> electrical model<br />

<strong>of</strong> the charge injection by a focused pulsed laser on silicon has been<br />

developed. First, the laser-induced charge diffusion is calculated<br />

by a finite-element-model coupling Boltzmann semiclassical transport<br />

<strong>and</strong> thermodynamic equations; the last one being necessary,<br />

as relatively high laser power may increase significantly the local<br />

temperature. The result is then fed into an electrical model <strong>of</strong><br />

the ring oscillator as a perturbation injected by a current source.<br />

This model coupled to parasitic-light effects due to geometrical<br />

changes during silicon melting is able to explain the oscillator’s<br />

operation-frequency modification.<br />

Index Terms—<strong>Charge</strong> injection, finite-element model, laser<br />

trimming, substrate effect, temperature effect.<br />

I. INTRODUCTION<br />

CLASSES <strong>of</strong> analog microelectronic circuits require highprecision<br />

resistors to function properly. St<strong>and</strong>ard integrated<br />

fabrication processes’ intrinsic variability can introduce<br />

some uncontrolled changes in parametric values that can<br />

severely limit their accuracy, possibly resulting in a completely<br />

useless circuit. A solution to this problem consists in a postproduction<br />

trimming <strong>of</strong> resistor values to obtain the desired<br />

electrical characteristics. The possibility to configure circuits<br />

by creating or cutting metal links [1] allows designers to add re-<br />

Manuscript received October 5, 2007; revised June 27, 2008. Current version<br />

published September 24, 2008. This work was supported in part by the Natural<br />

Sciences <strong>and</strong> Engineering Council <strong>of</strong> Canada <strong>and</strong> in part by LTRIM. The review<br />

<strong>of</strong> this paper was arranged by Editor C.-Y. Lu.<br />

É. Boulais <strong>and</strong> M. Meunier are with the Laser Processing Laboratory,<br />

Engineering Physics Department, École Polytechnique de Montréal,<br />

Montreal, QC H3C 3A7, Canada (e-mail: etienne.boulais@polymtl.ca; michel.<br />

meunier@polymtl.ca).<br />

V. Binet, G. Wild, <strong>and</strong> Y. Savaria are with the Groupe de Recherche en<br />

Microélectronique, Electrical Engineering Department, École Polytechnique de<br />

Montréal, Montreal, QC H3C 3A7, Canada (e-mail: vincent.binet@polymtl.ca;<br />

guillaume.wild@polymtl.ca; yvon.savaria@polymtl.ca).<br />

J.-Y. Degorce was with the Laser Processing Laboratory, Engineering<br />

Physics Department, École Polytechnique de Montréal, Montreal, QC H3C<br />

3A7, Canada. He is now with the Université de Bordeaux, 33000 Bordeaux,<br />

France (e-mail: Degorce.JeanYes@celia.u-bordeaux1.fr).<br />

Digital Object Identifier 10.1109/TED.2008.2003027<br />

dundancy <strong>and</strong> correct malfunction in large VLSI circuits. Thinfilm<br />

resistors can also be trimmed by laser to improve accuracy<br />

<strong>of</strong> digital-to-analog converters [2], analog-to-digital converters<br />

[3], <strong>and</strong> read-only memories [4]. An alternative simple, costeffective,<br />

<strong>and</strong> rapid laser trimming process was recently proposed<br />

by Meunier et al. [5] <strong>and</strong> consists in the formation <strong>of</strong><br />

diffused resistors that can be used directly in mixed signal <strong>and</strong><br />

high-precision analog circuits [6]. This process uses a pulsed<br />

visible laser focused on a semiconductor structure consisting<br />

<strong>of</strong> two highly doped regions separated by a gap. The laser<br />

induces a local melting <strong>of</strong> the silicon surface, thus stimulating<br />

the diffusion <strong>of</strong> dopants <strong>and</strong> the formation <strong>of</strong> an analog resistive<br />

device, whose resistance can be accurately controlled by an<br />

iterative technique [7].<br />

Electron–hole pairs that might be created by the laser during<br />

these processes <strong>and</strong> injected into the substrate must remain<br />

below an acceptable level for industrial applications, as they<br />

can possibly activate destructive phenomena such as latch up<br />

<strong>and</strong> corrupt accuracy in closed-loop trimming methods that<br />

rely on accurate analog measurements. There is thus a need<br />

to develop a tool that will enable us to accurately calculate<br />

the charge injection in an integrated circuit during a trimming<br />

process. Preceding works on laser interaction with electronic<br />

circuit has been made within the fields <strong>of</strong> fault-injection <strong>and</strong><br />

single-event effects [8], [9]. However, as research in those fields<br />

involves very low power laser beam focused on transistors, laser<br />

trimming is usually processed at much higher power pulses (by<br />

three to four orders <strong>of</strong> magnitude), leading to a local temperature<br />

increase <strong>and</strong> to different charge-injection mechanisms <strong>and</strong><br />

impacts on surrounding circuits. Therefore, models developed<br />

for fault-injection <strong>and</strong> single-event effects cannot be used, since<br />

thermodynamic effects on charge transport induced by laser<br />

heating are ignored. Previous work by Wild et al. [10] has<br />

shown that a ring oscillator can be used to detect very small<br />

laser-induced charge injection into the silicon by monitoring its<br />

frequency change during the tuning process. The purpose <strong>of</strong> this<br />

paper is to model both the charge injection in silicon due to a<br />

focused visible laser beam <strong>and</strong> the effect <strong>of</strong> charge injection<br />

on an operating ring oscillator. A finite-element model using<br />

coupled thermodynamic <strong>and</strong> semiclassical charge-transport<br />

equations is used for the charge-injection calculation, while an<br />

electrical model <strong>of</strong> the ring oscillator, including substrate <strong>and</strong><br />

well extraction, is used to calculate the impact <strong>of</strong> the charge<br />

injection on the circuit.<br />

0018-9383/$25.00 © 2008 <strong>IEEE</strong>


BOULAIS et al.: THERMODYNAMICS AND TRANSPORT MODEL OF CHARGE INJECTION IN SILICON 2729<br />

Fig. 1. (a) Schematic <strong>of</strong> a ring oscillator composed <strong>of</strong> four inverters <strong>and</strong> an AND gate. All inverters are equidistant to the target. (b) Typical result <strong>of</strong> the FVC<br />

output after a 950-mW 100-ns pulsed laser irradiating the center <strong>of</strong> the ring oscillator situated at 30 μm.<br />

II. EXPERIMENTAL SETUP AND RESULTS<br />

As described in [10], the sensitive circuits used to detect<br />

injected charges in the experimental work are CMOS ring<br />

oscillators, manufactured by TSMC in a 0.18-μm technology<br />

that has a low-resistivity p-type substrate. Oscillating at a<br />

stable frequency, the ring oscillator, as previously presented by<br />

Wild [10], is composed <strong>of</strong> four inverters <strong>and</strong> a gating NAND acting<br />

as an inverter during the oscillation operation. A frequencyto-voltage<br />

converter (FVC) is used to drive the chip output at<br />

a voltage that represents the oscillator’s frequency, as shown<br />

in Fig. 1. The on-chip oscillation <strong>of</strong> about 380 MHz is first<br />

divided by eight using a frequency divider (FD), then each<br />

period is converted by the FVC to a dc voltage that drives the<br />

output <strong>of</strong> the chip through an analog buffer. The laser target<br />

is a laser diffused resistor (LDR) implanted in the center <strong>of</strong><br />

the ring oscillator <strong>and</strong> located at various distance d to the<br />

ring oscillator, ranging from 20 to 40 μm. A test setup has<br />

been developed as described in [10] using a frequency-doubled<br />

continuous-wave Nd:YAG laser (532 nm) having an adjustable<br />

diameter <strong>and</strong> power. A pulse is selected from the continuous<br />

beam using an acoustooptic modulator <strong>and</strong> is focalized on<br />

the target. In all experiments, a single pulse is used with a<br />

pulse duration <strong>of</strong> 100 ns. The beam diameter is about 7 μm,<br />

<strong>and</strong> the emitted laser power P L is varying up to 1.5 W. Note<br />

that, throughout the text, the emitted laser power refers to<br />

the average laser power <strong>of</strong> the continuous-wave laser, taking<br />

into consideration losses due to the acoustooptic modulator.<br />

It is difficult to evaluate the optical losses due to the multiple<br />

reflections <strong>and</strong> the absorption in the interdielectric layers;<br />

the exact laser power arriving on the silicon is not known.<br />

A typical FVC variation for P L = 950 mW <strong>and</strong> d = 30 μm<br />

is given in Fig. 1(b). The measured maximum <strong>of</strong> the FVC<br />

output variation [FVCOV max defined in Fig. 1(b)] is shown in<br />

Fig. 2 as a function <strong>of</strong> the laser power P L . Estimations based<br />

on diffused-resistor creation experiments <strong>and</strong> in situ reflectivity<br />

measurements give a value for the melting power threshold <strong>of</strong><br />

around P L,th−m =(1.1 ± 0.1) W. One can distinguish three<br />

main regions in these measured results: 1) In the first region,<br />

for P L < 0.375 W, the FVC output increases with P L ;2)in<br />

the second region (0.375 W 0.7 W), the FVC output increases slightly with scattered<br />

results. An increase in charge injection with increasing power<br />

was expected. The presence <strong>of</strong> region II was not expected.<br />

To explain these results, the effects <strong>of</strong> heating on the charge<br />

transport must considered.<br />

III. CONSTANT-TEMPERATURE ELECTRONIC<br />

TRANSPORT MODEL<br />

Many models describing the interaction between a laser pulse<br />

<strong>and</strong> a semiconductor developed over the past four decades focus<br />

on emulating the impact <strong>of</strong> single-event effects by ionizing<br />

radiation on static memories [9], [11], [12]. In these existing<br />

models, relatively low laser powers are assumed, as any heating<br />

phenomena are excluded from the calculation. However, the<br />

laser used for creating LDRs is different in terms <strong>of</strong> power<br />

level <strong>and</strong> pulse duration, since significant heating <strong>and</strong> melting<br />

<strong>of</strong> silicon is required. As a first approximation, the substrate’s<br />

temperature was assumed to remain constant throughout the<br />

process. It will be shown that this assumption is not accurate.<br />

It is important to note that the laser is not directly focused<br />

on the active area <strong>of</strong> a transistor under test, but rather on the<br />

LDR region, which introduces additional specificity into the


2730 <strong>IEEE</strong> TRANSACTIONS ON ELECTRON DEVICES, VOL. 55, NO. 10, OCTOBER 2008<br />

model. Electron–hole pairs are thus not directly generated on<br />

the transistor drain but can rather reach the circuit under test,<br />

which is a ring oscillator, through a drift <strong>and</strong> diffusion process<br />

that will be described by a finite-element model based on<br />

Boltzmann semiclassical transport equations. An electric model<br />

must also be used to characterize the effects <strong>of</strong> the injected<br />

charges on the circuit under test.<br />

A. Electrical <strong>Model</strong><br />

In order to get an accurate model <strong>of</strong> the victim circuit, the<br />

complete circuit has to be extracted from a detailed layout.<br />

As the coupling between the laser-pulse impact <strong>and</strong> the victim<br />

circuit takes place through the substrate, the model must also<br />

include a thorough substrate extraction. As significant currents<br />

flow into the substrate, the potentials around active devices are<br />

significantly perturbed, which modulates the electrical parameters<br />

<strong>of</strong> the victim circuit through body effects. To include<br />

substrate coupling in the model, commercial s<strong>of</strong>twares like<br />

SubstrateStorm, Substrate Coupling Analysis (SCA), or Assura<br />

RCX (Cadence S<strong>of</strong>tware) could be used to extract substrate<br />

parasitic components <strong>and</strong>, thus, build a resistive <strong>and</strong> capacitive<br />

substrate model. However, existing literature [13] on substrate<br />

modeling <strong>and</strong> parasitic extraction is mostly focused on noise<br />

coupling injected by a large number <strong>of</strong> switching gates. In [14],<br />

such models based only on capacitive coupling have shown<br />

inaccuracy when potentials vary over a wide range. These<br />

models become particularly inaccurate when the potentials shift<br />

by more than 400 mV <strong>and</strong> some normally inactive devices get<br />

activated. Mixed-mode simulations have shown that such large<br />

variations effectively occur in our case. In order to correctly<br />

model the charge-injection phenomena, a custom model <strong>of</strong><br />

the substrate has been developed by enriching capacitive- <strong>and</strong><br />

resistive-only substrate models given by the Cadence SCA<br />

tool. This custom substrate model includes vertical bipolar<br />

transistors <strong>and</strong> diodes to represent well–substrate junctions.<br />

They are added as discrete elements whose models are based on<br />

those provided by TSMC, <strong>and</strong> their size parameters are adjusted<br />

according to the physical layout <strong>of</strong> the circuit.<br />

<strong>Charge</strong> injection is then modeled by sources injecting currents<br />

through different junctions present in the ring-oscillator<br />

test circuit. As shown in Fig. 3, different perturbation sites have<br />

been identified to model the charge–circuit interaction in each<br />

<strong>of</strong> the inverters comprised in the circuit. Current source (A)<br />

simulates most <strong>of</strong> the charges collected by the n-well–substrate<br />

junction, whereas sources (B) <strong>and</strong> (C) connected between the<br />

source/drain nodes <strong>of</strong> the transistor <strong>and</strong> the bulk node represent<br />

charges collected by the NMOS. The last two sources (D)<br />

<strong>and</strong> (E) model injection into PMOSs’ drains <strong>and</strong> sources.<br />

All these sources correspond to possible physical-interaction<br />

mechanisms between charges present in the substrate <strong>and</strong> the<br />

circuit. Performing a series <strong>of</strong> circuit simulations, it was found<br />

that sources B, C, D, <strong>and</strong> E have relatively minor effects<br />

on the oscillator behavior <strong>and</strong> can be neglected. This can be<br />

understood because the surface <strong>of</strong> the well associated to source<br />

A is much larger (by a factor over ten) than the surface <strong>of</strong> the<br />

physical structures associated to the other sources. Using the<br />

detailed circuit models, including all available circuit, layout,<br />

substrate, <strong>and</strong> parasitic-device information, the complete ringoscillator<br />

model is then built <strong>and</strong> connected to the rest <strong>of</strong> the<br />

chip model, including the FVC, package, <strong>and</strong> bonding wires. In<br />

the first approximation, it was assumed that the FVC <strong>and</strong> other<br />

secondary circuits that are much further away from the laserpulse<br />

impact point remain unaffected by laser-induced charges.<br />

B. Constant-Temperature Semiconductor <strong>Transport</strong> <strong>Model</strong><br />

In a first approximation, by neglecting temperature rise <strong>of</strong> the<br />

substrate, it is possible to model the charge-injection process in<br />

silicon by simply coupling a Beer–Lambert equation for light<br />

absorption with Poisson <strong>and</strong> Boltzmann equations describing<br />

the charge drift <strong>and</strong> diffusion processes. Dopants are assumed to<br />

be completely ionized within the considered temperature range.<br />

Continuity equation relating the electrons concentration n <strong>and</strong><br />

the current density J n is thus given by<br />

∂n<br />

∂t = 1 −→ ∇·−→<br />

Jn + G n − r n . (1)<br />

e<br />

A similar equation for holes has been used. Recombination<br />

term r n in (1) includes Shockley–Read–Hall (SRH) <strong>and</strong><br />

Auger recombination. Appropriate coefficients for silicon can<br />

be found in [15]. A dynamic SRH recombination process can<br />

be used [16], but simulations showed that results were very<br />

close to those obtained by using a st<strong>and</strong>ard equilibrium SRH<br />

expression. Optical generation term G optical is calculated by<br />

assuming that every absorbed photon <strong>of</strong> energy hν causes an<br />

interb<strong>and</strong> transition, thus creating a hole–electron pair<br />

α(T )I<br />

G optical = (2)<br />

hν<br />

where α is the temperature-dependent bulk-absorption coefficient<br />

<strong>and</strong> I in joules per square centimeter is the laser intensity<br />

arriving on the silicon. Intrab<strong>and</strong> absorption is ignored,<br />

since simulations showed that, for laser powers used here, the<br />

maximum carrier density is not enough to stimulate such contribution.<br />

Current density is calculated through the Boltzmann<br />

kinetic equation [17]<br />

( )<br />

−→ −→ F J n = neμ n E + nμn T ∇<br />

T<br />

G n 5/2<br />

+ nμ n k B<br />

G n ∇T (3)<br />

3/2<br />

where μ n is the electron mobility, −→ E is the electric vector field,<br />

F is the quasi-Fermi level, <strong>and</strong> G m is defined as<br />

with<br />

G m =<br />

∫ ∞<br />

0<br />

τx m e x−η dx<br />

(1 + e x−η ) 2 (4)<br />

η = F n − ε gap<br />

. (5)<br />

k B T<br />

Note that all these parameters are position ( −→ r )-dependent.<br />

Similar equations for p can be obtained where the laser term in<br />

(3) changes sign, <strong>and</strong> η p = −F p /k B T .


BOULAIS et al.: THERMODYNAMICS AND TRANSPORT MODEL OF CHARGE INJECTION IN SILICON 2731<br />

Fig. 3.<br />

Custom electrical model <strong>of</strong> an inverter <strong>of</strong> the ring oscillator.<br />

The exact position-dependent mobility parameters for both<br />

holes <strong>and</strong> electron are difficult to determine, since integrated<br />

circuits are not only composed <strong>of</strong> pure <strong>and</strong> crystalline silicon<br />

but also <strong>of</strong> polycrystalline silicon which has suffered many<br />

stresses in some regions, including high-power laser impacts<br />

<strong>and</strong> phase changes. Furthermore, the real doping-concentration<br />

pr<strong>of</strong>ile remains unknown, since those parameters are not provided<br />

by the foundry. Position-dependent dislocations, defects,<br />

<strong>and</strong> dopants would all decrease the carrier mobility, resulting<br />

in a modified position <strong>and</strong> temperature-dependent mobility<br />

given by<br />

with<br />

μ M n,p(x, y, T )=φ(x, y, T )μ C n,p(x, y, T ) (6)<br />

φ(x, y, T ) ∈ [0, 1] (7)<br />

where the superscript M <strong>and</strong> C st<strong>and</strong>s, respectively, for “modified”<br />

<strong>and</strong> “crystalline,” as the subscripts n <strong>and</strong> p, respectively,<br />

st<strong>and</strong>s for electrons <strong>and</strong> holes. Carrier mobility in crystalline<br />

silicon can be found in st<strong>and</strong>ard texts [18]. Now, since the<br />

exact expression for ϕ(x, y, t) is very difficult to obtain, both<br />

theoretically <strong>and</strong> experimentally, we propose to use in a first<br />

approximation an equivalent mobility given by<br />

with<br />

μ eq<br />

n,p(x, y, T )=φμ C n,p(x, y, T ) (8)<br />

φ ∈ [0, 1] (9)<br />

where μ eq<br />

n,p is the equivalent mobility <strong>of</strong> electrons <strong>and</strong> holes <strong>and</strong><br />

φ is an empirical parameter adjusted to fit experimental value.<br />

Similarly, the carrier recombination time is also expected to<br />

be different from the one for crystalline silicon, <strong>and</strong> a uniform<br />

equivalent recombination has been assumed<br />

τ eq<br />

n,p(x, y, t) =τ. (10)<br />

While the introduction <strong>of</strong> equivalent recombination times,<br />

absorption coefficient, <strong>and</strong> mobilities are required to fit experimental<br />

data, their influence over the general behavior <strong>of</strong><br />

Fig. 4. FVC variation as a function <strong>of</strong> laser power, (circles) experiments, <strong>and</strong><br />

(crosses) simulation.<br />

injected current as a function <strong>of</strong> incident laser power remains<br />

limited. Finite-element simulations were performed on a<br />

1.8-V reversed-biased p-n junction located at d = 30 μm from<br />

a pulsed focused laser. The calculated current was then inserted<br />

as a current source perturbing the electrical model to obtain the<br />

simulated variation <strong>of</strong> the FVC output voltage. Mobility factor<br />

<strong>and</strong> recombination time were then adjusted to fit experimental<br />

results. Simulations show that φ = 0.17 <strong>and</strong> τ = 200 ns reproduces<br />

the experimental results with the best accuracy. Fig. 4<br />

shows both the best-fit simulated <strong>and</strong> measured results <strong>of</strong> the<br />

FVC output variation as a function <strong>of</strong> P L . Results in Fig. 4<br />

show that, while the model predictions agree quite well with<br />

simulation results within the first region (P L < 0.375 W), it<br />

does not follow the behavior observed in the second region<br />

(0.375 W


2732 <strong>IEEE</strong> TRANSACTIONS ON ELECTRON DEVICES, VOL. 55, NO. 10, OCTOBER 2008<br />

IV. COUPLED THERMODYNAMICS AND<br />

TRANSPORT MODEL<br />

A. Coupled Thermodynamic <strong>and</strong> <strong>Transport</strong> <strong>Model</strong><br />

Without Fusion<br />

In this improved model based on coupled thermodynamic<br />

<strong>and</strong> transport equations, the carrier spatial distribution is simulated<br />

in a two-step process. Temperature is first calculated<br />

using a model essentially based on the one introduced by<br />

Degorce et al. [19], involving the resolution <strong>of</strong> coupled<br />

Beer–Lambert <strong>and</strong> heat equations, where the phase transformation<br />

is accounted for by using an enthalpic model. Siliconoxide<br />

effect on temperature distribution is neglected to reduce<br />

the model’s complexity. The carrier distribution is then determined<br />

through the resolution <strong>of</strong> the coupled Boltzmann <strong>and</strong><br />

Poisson equations. The temperature calculated in the first step<br />

is used into these equations without any explicit feedback.<br />

However, carrier-distribution effects on temperature are taken<br />

into account by using an empirical relation <strong>of</strong> the temperaturedependent<br />

absorption coefficient α(T ). This approximation reduces<br />

greatly the model’s complexity. The calculated maximum<br />

temperature gradient <strong>of</strong> 3.5 × 10 7 K/cm remains small enough<br />

to justify the use <strong>of</strong> Boltzmann equation for any laser power<br />

considered in this paper. As expected, temperature gradient has<br />

a considerable effect on the charge transport in the material<br />

which can be easily understood by looking at the Boltzmann<br />

equation. Developing (3), for the electrons, one can write<br />

Fig. 5. Schematic <strong>of</strong> the time evolution <strong>of</strong> the distribution <strong>of</strong> electronic current<br />

in the material. At the beginning <strong>of</strong> the pulse (A), electrons induced in the<br />

material diffuse from the laser impact point to the circuit. The laser heats<br />

the substrate, <strong>and</strong> when temperature gradient gets high enough over a certain<br />

area (B), this area experiences an inversion <strong>of</strong> its electronic current. After the<br />

end <strong>of</strong> the pulse (C), the temperature gradient gets lower, <strong>and</strong> the inverse current<br />

area disappear.<br />

( )<br />

−→ G5/2<br />

J n = −enμ n ∇V + nμ n ∇F − k B nμ n − η ∗ ∇T<br />

G 3/2<br />

(11)<br />

where the first terms represent the drift <strong>and</strong> temperatureconstant<br />

diffusion current <strong>and</strong> the last one corresponds to<br />

a current generated when a temperature gradient is present<br />

within the material. A similar equation can be obtained for<br />

holes. Calculations show that the coefficient multiplying the<br />

temperature gradient (11) is always positive. In our application,<br />

in addition to injecting carriers, the laser acts as a heat source<br />

generating a thermal gradient having the same sign as the<br />

carrier concentration <strong>and</strong> the quasi-Fermi level. Therefore, the<br />

temperature gradient always opposes the effect <strong>of</strong> the carrierconcentration<br />

gradient, here represented by the quasi-Fermi<br />

level gradient, on the diffusion current. Strong temperature<br />

gradient could limit <strong>and</strong> even stop the diffusion <strong>of</strong> carriers from<br />

the laser impact point to the junction. Fig. 5 shows a schematic<br />

time pr<strong>of</strong>ile <strong>of</strong> the electronic current present in the material.<br />

As shown in Fig. 5, when a strong temperature gradient is<br />

present in the material, an inversion <strong>of</strong> the electronic current is<br />

experienced over a small area <strong>of</strong> the substrate. Carriers are then<br />

confined in this small region limited by this diffusion barrier<br />

where they can recombine. Only carriers created at the very<br />

beginning <strong>of</strong> the laser pulse, which is before the formation <strong>of</strong><br />

a strong temperature gradient, or created outside the diffusion<br />

barrier will eventually get to the junction. Fig. 6 shows a<br />

simulation result showing that this inversion <strong>of</strong> the electronic<br />

current indeed occurs for a 0.5-W laser pulse in a region located<br />

about 400 nm from the laser impact point. Fig. 7 now shows<br />

Fig. 6. Electronic current as a function <strong>of</strong> distance from laser impact point at<br />

the end <strong>of</strong> a 0.5-W pulse as calculated with (solid line) coupled thermodynamic<br />

<strong>and</strong> transport model <strong>and</strong> (dashed-dot line) constant-temperature semiconductor<br />

constant model.<br />

a comparison <strong>of</strong> the simulated FVC output voltage using this<br />

new model to the experimental results. Comparison <strong>of</strong> Fig. 7<br />

to Fig. 4 shows that introducing temperature effects into the<br />

semiconductor transport model permits one to almost reproduce<br />

the experimental behavior in the second region which could<br />

thus be attributed for a large part to the presence <strong>of</strong> strong<br />

temperature gradient within the substrate. It is <strong>of</strong> interest that<br />

the electrical model used to simulate FVC output is no longer<br />

valid beyond 0.7 W. At that point, the electric model predicts<br />

that current perturbation required to reproduce experimental<br />

values shortcuts the n-well junction. The linear-circuit model<br />

used here is then no longer a good approximation to the phenomena<br />

taking place. It is thus difficult to correlate simulated<br />

<strong>and</strong> experimental behaviors for incident powers beyond 0.7 W.


BOULAIS et al.: THERMODYNAMICS AND TRANSPORT MODEL OF CHARGE INJECTION IN SILICON 2733<br />

Fig. 7. FVC variations as a function <strong>of</strong> laser power, (circles) experiments, <strong>and</strong><br />

(triangles) simulation.<br />

The physical model presented so far predicts a saturation <strong>of</strong> the<br />

current entering the junction as a function <strong>of</strong> the laser power in<br />

the third region. In fact, at those powers, the temperature rise<br />

in silicon is strong enough to induce melting <strong>of</strong> the substrate.<br />

Although melting <strong>of</strong> the surface is included in the model,<br />

its direct effect on electronic transport has been neglected.<br />

The next section introduces a model that considers those<br />

effects.<br />

B. Coupled Thermodynamic <strong>and</strong> <strong>Transport</strong> <strong>Model</strong><br />

With Fusion<br />

Basically, the equations <strong>of</strong> coupled thermodynamic <strong>and</strong><br />

transport model presented in the previous section remains<br />

essentially the same, except that one must include the effect<br />

<strong>of</strong> the melted silicon, which has become metallic. Inverse<br />

bremsstrahlung then becomes the main light-absorption<br />

mechanism, <strong>and</strong> direct electron–hole pair creation can be<br />

neglected. However, when fusion temperature is reached,<br />

semiconductor–metal phase transformation induces confined<br />

electrons in covalent bonds to reach conduction b<strong>and</strong>s thus significantly<br />

increasing equilibrium electronic concentration [20].<br />

The density <strong>of</strong> states <strong>of</strong> silicon is greatly modified when melted,<br />

<strong>and</strong> the Fermi level position decreases by approximately 0.6 eV<br />

according to experimental studies [21]. The solid–liquid interface<br />

is assumed to be at equilibrium so that thermionic<br />

charge injection can be neglected. Electron mobility is also<br />

modified [22]. Therefore, at relatively high laser power, the<br />

process will result in a metal–semiconductor heterostructure<br />

whose interface moves with the melted front. Because <strong>of</strong> the<br />

Fermi level drop in the melted silicon, carriers in liquid silicon<br />

are trapped inside a 0.6-eV well. Therefore, even if the carrier<br />

density within the melted silicon is very high, those carriers<br />

are probably not able to diffuse, <strong>and</strong> they probably stay trapped<br />

inside the melted region. Melting <strong>of</strong> the substrate is thus believed<br />

to have a negligible impact on the current perturbation<br />

affecting the sensitive circuit. From simulation results <strong>and</strong> using<br />

Fermi statistics, one can estimate the number <strong>of</strong> carriers in the<br />

melted region that is able to pass over the potential barrier to be<br />

approximately 10 19 times lower than the photoinduced charges<br />

injected in the solid semiconductor outside the melted region.<br />

As the laser power increases, reflected light from the impact<br />

point could be scattered to relatively large distances<br />

through multiple reflections in the interdielectrics <strong>and</strong> reach<br />

the p-n junction, thus creating additional electron–hole pair<br />

in the silicon. A simple calculation can be made to approximate<br />

the magnitude <strong>of</strong> this scattered light. Neglecting backscattering<br />

from dielectric/dielectric interface since their refraction<br />

indexes are expected to be very similar, the proportion <strong>of</strong> light<br />

backscattered from the irradiated surface, to the interface top<br />

layer/air, <strong>and</strong> back to the surface is about 10% <strong>of</strong> the incident<br />

light at the laser impact point. However, since the target is not<br />

experimentally located exactly at the laser waist, it is expected<br />

that the incoming lightwave will not be perfectly plane at the<br />

surface, yielding to a reflected light over a large area. Moreover,<br />

when melted, the silicon surface experiences different transformations<br />

that increase this light scattering. First, liquid silicon’s<br />

reflection coefficient is about 1.5 times larger than the one <strong>of</strong><br />

solid silicon. In addition, besides reflection coefficient modification,<br />

silicon undergoes purely geometrical modification when<br />

melted. Fig. 8 shows an image from a transmission electron<br />

microscopy <strong>of</strong> a silicon area which has been melted by a laser<br />

irradiation whose parameters are analog to the one used for<br />

trimming processes. Silicon has experienced strong geometrical<br />

modification <strong>and</strong> has reshaped as a rounded pyramid, similar<br />

to a sombrero shape. Other shapes have been reported in<br />

the literature, including bowl, for silicon <strong>and</strong> other material<br />

surfaces [23], [24]. These studies showed that irradiating at<br />

low energy tends to create bowllike structures, while at higher<br />

energy, sombrero structures are mostly observed. As stated<br />

in [23], bowllike structure formation results from temperature<br />

gradient inducing thermocapillarity flow that drives material<br />

from the hot center to the cold periphery. However, at higher<br />

laser power, native oxide layer is removed (at least partially),<br />

thus creating a surfactant-concentration gradient driving material<br />

toward the center. The observed sombrerolike structure is<br />

expected to increase the quantity <strong>of</strong> scattered light reaching the<br />

transistor region. Wave front at the surface is indeed no longer<br />

plane, <strong>and</strong> reflections will occur at angles far from normal, thus<br />

increasing the proportion <strong>of</strong> light reaching regions distant from<br />

the laser impact point. Scattered light creates photo-induced<br />

carriers in regions far from impact point <strong>and</strong> outside the strong<br />

temperature gradient area. Those carriers then diffuse freely<br />

to the circuit area, thus contributing to the total current. Note<br />

that all samples contained those substrate deformation from<br />

the beginning, since measurements have been conducted on a<br />

previously irradiated circuit. Consequently, the laser power at<br />

the edge <strong>of</strong> region 3 in Fig. 2 does not st<strong>and</strong> for the point at<br />

which the deformation appears but rather for the point at which<br />

scattered-light induced carrier effect on the oscillator becomes<br />

dominant over the diffusion process. Within this model, lightscattered<br />

induced carrier generation is modeled as a uniform<br />

<strong>and</strong> constant light background proportional to the incident laser<br />

power. Light-scattered generation have thus to be added to the<br />

optical generation<br />

G = G optical + G scattering . (12)


2734 <strong>IEEE</strong> TRANSACTIONS ON ELECTRON DEVICES, VOL. 55, NO. 10, OCTOBER 2008<br />

Fig. 8. (a) TEM cross-sectional image showing geometrical changes in silicon surface induced by laser melting. (b) Schematic <strong>of</strong> the scattered-light induced<br />

carrier injection backscattered from the irradiated surface to the interface top layer—air—<strong>and</strong> back to the surface.<br />

Numerical simulations has shown that 0.5% scattered-light<br />

intensity reaching regions outside the strong temperature gradient<br />

area can generate a considerable current through the<br />

junction, thereby preventing the total perturbative current to<br />

saturate as the power is increased over 700 mW in region III.<br />

Such a scattering is reasonable considering the initial 10% light<br />

reflected from the reflection on dielectric layers. Considering<br />

the experimental evidence about the existence <strong>of</strong> sample surface<br />

deformations <strong>and</strong> the small intensity <strong>of</strong> parasitic light required<br />

to produce observable effects on current, parasitic-light photoinduced<br />

carriers are thought to play an important role on the<br />

FVC output behavior at higher power.<br />

V. CONCLUSION<br />

Laser-induced diffused-resistor fabrication processes involve<br />

pulsed visible laser interaction on chips containing highly<br />

sensitive circuitry. In order to evaluate the impact <strong>of</strong> the laser<br />

pulses on these circuits, a study <strong>of</strong> the perturbation induced<br />

on the free-running frequency <strong>of</strong> a ring oscillator has been<br />

made. The behavior <strong>of</strong> this modification as a function <strong>of</strong> the<br />

laser-pulse power exhibits a quasi-linear increase for low laser<br />

power, then a saturation <strong>and</strong> finally another increase for high<br />

laser power. An electric model <strong>of</strong> the ring oscillator <strong>and</strong> <strong>of</strong><br />

the FVC circuit has been coupled to a semiconductor model<br />

<strong>of</strong> the charge injection to describe the impact <strong>of</strong> the laser<br />

pulse on the sensitive circuit. A simple model neglecting the<br />

temperature rise <strong>of</strong> the substrate is unable to describe properly<br />

the observed experimental behavior. A model based on thermodynamics<br />

<strong>and</strong> Boltzmann semiclassical transport equations<br />

<strong>of</strong> the charge injection by a focused pulsed laser in silicon has<br />

been developed to include the temperature rise <strong>of</strong> the substrate.<br />

Results show that below silicon melting, the charge injection<br />

increases linearly at low power <strong>and</strong> then saturates due to the<br />

presence <strong>of</strong> strong temperature gradient that confines photoinduced<br />

carriers in a small region around the laser impact point,<br />

thereby preventing them to diffuse to the oscillator. Above<br />

melting, silicon experiences a semiconductor-to-metal phase<br />

transition, injecting a lot <strong>of</strong> free carriers in the liquid silicon.<br />

However, based on experimental studies, those carriers are<br />

trapped in the liquid phase <strong>and</strong> are not able to diffuse to the<br />

oscillator <strong>and</strong> thus do not affect its oscillation frequency. In<br />

addition to this phase transition, melted liquid silicon when<br />

solidified experiences a geometrical transformation that creates<br />

light-scattered induced carriers that either affect directly the<br />

oscillator or is able to diffuse to it. This phenomenon appears to<br />

be responsible for the increase <strong>of</strong> the FVC response for higher<br />

laser power.<br />

ACKNOWLEDGMENT<br />

The authors would like to thank S. Laforte <strong>and</strong> R. Lachaîne<br />

for TEM imaging <strong>and</strong> valuable discussions. They would also<br />

like to thank A. Lacourse from LTRIM Technologies for stimulating<br />

discussions. Some <strong>of</strong> the tools <strong>and</strong> access to fabrication<br />

technologies were provided by CMC Microsystem.<br />

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“Influence <strong>of</strong> laser pulse duration in single event upset testing,” <strong>IEEE</strong><br />

Trans. Nucl. Sci., vol. 53, no. 4, pp. 1799–1805, Aug. 2006.<br />

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ASICs. Boston, MA: Kluwer, 2003.<br />

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Jean-Yves Degorce received the M.A.Sc. degree in<br />

solid state physics from the University <strong>of</strong> Paris VI,<br />

Paris, France, in 1989 <strong>and</strong> the Ph.D. degree in laser<br />

matter interaction from the École Polytechnique de<br />

Montréal, Montreal, QC, Canada, <strong>and</strong> the Université<br />

de Bordeaux, Bordeaux, France, in 2000.<br />

From 2000 to 2005, he was a Lecturer <strong>and</strong><br />

Associate Researcher in laser processing with the<br />

Laser Processing Laboratory, Engineering Physics<br />

Department, École Polytechnique de Montréal. He<br />

is currently a Pr<strong>of</strong>essor in classe préparatoire aux<br />

gr<strong>and</strong>es écoles with the Université de Bordeaux. His current research interests<br />

include micro- <strong>and</strong> nanothermal modeling.<br />

Guillaume Wild received the Diploma degree in<br />

electrical engineering from the Ecole Superieure<br />

d’Electricite, Gif Sur Yvette, France, in 2002 <strong>and</strong><br />

the M.A.Sc. degree from the École Polytechnique de<br />

Montréal, Montreal, QC, Canada, in 2005, under the<br />

supervision <strong>of</strong> Pr<strong>of</strong>s. Y. Savaria <strong>and</strong> M. Meunier.<br />

He is currently with Siemens, Amberg, Germany.<br />

Étienne Boulais received the B.Ing. degree in engineering<br />

physics from the École Polytechnique de<br />

Montréal, Montreal, QC, Canada, in 2007, where<br />

he has been working toward the Ph.D. degree<br />

in the Laser Processing Laboratory, Engineering<br />

Physics Department, under the supervision <strong>of</strong><br />

Pr<strong>of</strong>.M.Meunier.<br />

His research topic is in the field <strong>of</strong> the simulation<br />

<strong>of</strong> laser–matter interaction.<br />

Yvon Savaria (S’77–M’86–SM’97–F’08) received<br />

the B.Ing. <strong>and</strong> M.A.Sc. degrees in electrical engineering<br />

from the École Polytechnique de Montréal,<br />

Montreal, QC, Canada, in 1980 <strong>and</strong> 1982, respectively,<br />

<strong>and</strong> the Ph.D. degree in electrical engineering<br />

from McGill University, Montreal, in 1985.<br />

Since 1985, he has been with the École Polytechnique<br />

de Montréal, where he is currently a Pr<strong>of</strong>essor<br />

<strong>and</strong> the Director <strong>of</strong> the microelectronics <strong>and</strong><br />

microsystems research group in the Electrical Engineering<br />

Department. He has carried out work in<br />

several areas related to microelectronic circuits <strong>and</strong> microsystems.<br />

Vincent Binet received the Diploma degree in<br />

electrical engineering from the Ecole Superieure<br />

d’Electricite, Gif Sur Yvette, France, <strong>and</strong> the<br />

M.A.Sc. degree in microelectronics from the École<br />

Polytechnique de Montréal, Montreal, QC, Canada,<br />

in 2007, under the supervision <strong>of</strong> Pr<strong>of</strong>s. Y. Savaria<br />

<strong>and</strong> M. Meunier.<br />

He is currently with STMicroelectronics,<br />

Grenoble, France, in the IP advanced team in<br />

audio R&D.<br />

Michel Meunier received the B.Ing. <strong>and</strong> M.A.Sc.<br />

degrees in engineering physics from the École Polytechnique<br />

de Montréal, Montreal, QC, Canada, in<br />

1978 <strong>and</strong> 1980, respectively, <strong>and</strong> the Ph.D. degree<br />

from the Massachusetts Institute <strong>of</strong> Technology,<br />

Cambridge, in 1984.<br />

He is currently the Director <strong>of</strong> the Laser Processing<br />

Laboratory, Engineering Physics Department,<br />

École Polytechnique de Montréal. For close to<br />

30 years, he has been involved in laser processing<br />

<strong>of</strong> various materials <strong>and</strong> he has published over<br />

260 papers in this field.<br />

Dr. Meunier is a Canadian Research Chair in laser micro/nanoengineering <strong>of</strong><br />

materials.

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