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The chemistry, mineralogy, and rates of transport of sediments in the ...

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9<br />

Only two clay m<strong>in</strong>erals were found, chlorite <strong>and</strong> illite, <strong>and</strong> <strong>the</strong>se<br />

were, common <strong>in</strong> nearly all samples . Kaol<strong>in</strong>ite <strong>and</strong> members <strong>of</strong> <strong>the</strong> montmorillonite<br />

group . were sought but not found . See Campbell et aZ . (1975)<br />

for specific data for <strong>in</strong>dividual rivers <strong>and</strong> lakes .<br />

Nutrients N, P, <strong>and</strong> C <strong>in</strong> Suspended Sediments<br />

Concentrations <strong>of</strong> C, N, <strong>and</strong> P <strong>in</strong> suspended <strong>sediments</strong> (PC1,, PN : <strong>and</strong> PPS)<br />

<strong>of</strong> river waters are given <strong>in</strong> Table 7a <strong>and</strong> 7b . Variations <strong>in</strong> concentrations<br />

<strong>of</strong> <strong>the</strong>se elements <strong>in</strong> <strong>the</strong> particulate phase were likely due to changes a) <strong>in</strong><br />

concentration <strong>of</strong> suspended <strong>sediments</strong>, <strong>and</strong> b) <strong>in</strong> <strong>the</strong> relative proportions<br />

<strong>of</strong> <strong>in</strong>organic <strong>and</strong> organic material <strong>in</strong> suspended <strong>sediments</strong> . <strong>The</strong> proportion<br />

<strong>of</strong> C, N, <strong>and</strong> P per unit weight <strong>of</strong> suspended <strong>sediments</strong> is greater <strong>in</strong> <strong>the</strong><br />

smaller Group 2 streams, compared to <strong>the</strong> larger rivers <strong>of</strong> Group 1 (Table 7b) .<br />

Per unit volume <strong>of</strong> river water, <strong>in</strong>stantaneous concentrations <strong>of</strong> PP, :, PN,-<br />

<strong>and</strong> PC, : were related to <strong>in</strong>stantaneous discharge (Qi) as <strong>in</strong>dicated <strong>in</strong> Figs . 3<br />

<strong>and</strong> 4 . With <strong>in</strong>creased discharge, <strong>the</strong>re was usually an <strong>in</strong>crease <strong>in</strong> concentrations<br />

<strong>of</strong> PN1, PP, :, <strong>and</strong> PC, :, with <strong>the</strong> exception <strong>of</strong> rivers <strong>in</strong> Group 3 .<br />

Mean annual <strong>rates</strong> <strong>of</strong> <strong>transport</strong> <strong>of</strong> na, P91a, <strong>and</strong> gPQ <strong>in</strong> suspended sediment<br />

are given <strong>in</strong> Table 8, 9, <strong>and</strong> 10 . In general, Group 1 watersheds<br />

<strong>transport</strong>ed greater amounts <strong>of</strong> PC, PN, <strong>and</strong> PP (<strong>in</strong> units <strong>of</strong> moles yr'1 <strong>and</strong><br />

moles k<strong>in</strong>-2 <strong>of</strong> watershed area yr'l) than did Group 2 rivers <strong>and</strong> streams <strong>of</strong><br />

Table 1 . <strong>The</strong> annual mass <strong>of</strong> PCW, PNu,, <strong>and</strong> PPW <strong>transport</strong>ed per unit watershed<br />

was also positively related to annual discharge (QQ) as shown <strong>in</strong> FiRs .5<br />

<strong>and</strong> 6 . With <strong>in</strong>creas<strong>in</strong>g annual discharge, <strong>the</strong> <strong>transport</strong> <strong>of</strong> PCW, PNw, <strong>and</strong> PP ; .. .<br />

from a square kilometer <strong>of</strong> watershed also <strong>in</strong>creased . Small Qa rivers <strong>and</strong><br />

streams (Group 2 <strong>in</strong> Table 1) <strong>in</strong> <strong>the</strong> Mackenzie Valley lowl<strong>and</strong>s yielded less<br />

PCW, PNu., <strong>and</strong> PP,, ., per unit watershed area than did <strong>the</strong> larger Qa rivers <strong>of</strong><br />

Group 1 .<br />

<strong>The</strong> concentrations <strong>of</strong> PC, :, PN1 <strong>and</strong> PP, : (moles m'3 <strong>of</strong> river water)<br />

.<strong>in</strong>creased exponentially per unit <strong>in</strong>crease <strong>in</strong> <strong>the</strong> concentration <strong>of</strong> suspended<br />

<strong>sediments</strong> (Table 11) . <strong>The</strong> slopes <strong>of</strong> <strong>the</strong> regression l<strong>in</strong>es were <strong>of</strong> similar<br />

magnitude for PC, :, PN: <strong>and</strong> PP,: . - :<strong>The</strong> mean annual <strong>rates</strong> <strong>of</strong> <strong>transport</strong> <strong>of</strong><br />

suspended <strong>sediments</strong> (SSW <strong>in</strong> kg k~'2yr'1), PCW, PNW, <strong>and</strong> PPW (<strong>in</strong> moles<br />

km- yr-1) <strong>in</strong>creased exponentially per unit <strong>in</strong>crease <strong>in</strong> annual discharge<br />

(Table 12 <strong>and</strong> Figs . 2, 5 & 6) .<br />

An attempt was made to provide a means <strong>of</strong> "order <strong>of</strong> magnitude" prediction<br />

<strong>of</strong> na, . Ts a, TNQ, <strong>and</strong> TPQ from parameters that can be obta<strong>in</strong>ed from<br />

topographic,, climatic, vegetation <strong>and</strong> geologic maps . <strong>The</strong> results <strong>of</strong> multiple<br />

l<strong>in</strong>ear regression analyses given <strong>in</strong> Table 13 <strong>in</strong>dicate that watershed area,<br />

forest cover, relief, <strong>and</strong> precipitation are useful parameters <strong>in</strong> estimat<strong>in</strong>g<br />

<strong>the</strong> annual mass <strong>of</strong> suspended <strong>sediments</strong> <strong>and</strong> particulate nutrients flow<strong>in</strong>g out<br />

<strong>of</strong> a Mackenzie Valley watershed . -Estimates <strong>of</strong> annual <strong>transport</strong> (metric tons<br />

yr-1) <strong>of</strong> <strong>the</strong> above mentioned elements can be obta<strong>in</strong>ed from <strong>the</strong> follow<strong>in</strong>g<br />

equations :

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