Lynne Wong's PhD thesis

Lynne Wong's PhD thesis Lynne Wong's PhD thesis

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value extracted from Tables 4.17 – 4.21 and corrected for residual moisture content. The H 1 values were extracted from Table 6.3. The results are shown in Table 6.6. Table 6.6. Comparison of the calculated bound water (primary, secondary and tertiary) with the Brix-free water values of the nine cane components of R 570 of two ages. Sample 52 weeks 36 weeks Bound water at moisture content/% Brix-free water/% Bound water at moisture content/% Brix-free water/% Primary Secondary Tertiary Primary Secondary Tertiary Stalk fibre 8 10 22 12.37 6 9 20 14.37 Stalk pith 10 11 20 25.05 - 14 22 22.48 Rind fibre 9 10 21 12.02 7 10 21 13.65 Rind fines 8 10 22 11.47 7 13 30 15.58 Top fibre 10 13 23 16.76 12 14 25 15.82 Dry leaf fibre 10 13 20 16.13 13 14 25 15.70 Dry leaf fines 14 15 26 18.17 8 10 25 17.64 Green leaf fibre - 15 21 13.77 8 10 25 13.63 Green leaf fines 9 10 25 14.79 7 9 20 16.20 It can be seen from Table 6.6 that the Brix-free water values of sugar cane component parts correspond most closely to the secondary bound water, except those of stalk pith with inherent high surface area, which indicate the similarity to the tertiary bound water, or the free water point, reported by some research workers (Kaleemullah and Kailappan, 2007; Arslan and Toğrul, 2005). Kaleemullah and Kailappan (2007) found the primary, secondary and tertiary bound waters of red chillies end at moisture contents of 1.5, 14 and 53.6% db respectively. 261

Binding energy/kJ (kg mol) -1 2 0 0 15 0 10 0 5 0 0 - 5 0 Stalk fibre Stalk pith Rind fibre 9 5 0 15 0 7 5 0 5 5 0 3 5 0 5 0 15 0 0 10 2 0 3 0 4 0 0 10 2 0 3 0 4 0 - 5 0 0 10 2 0 3 0 4 0 - 5 0 Binding energy/kJ (kg mol) -1 15 0 10 0 5 0 0 - 5 0 Rind fines Top fibre Dry leaf fibre 2 5 0 15 0 5 0 0 10 2 0 3 0 4 0 0 10 2 0 3 0 4 0 - 5 0 2 5 0 15 0 5 0 - 5 0 0 10 2 0 3 0 4 0 Binding energy/kJ (kg mol) -1 2 5 0 15 0 5 0 - 5 0 Dry leaf fines Green leaf fibre Green leaf fines 10 0 5 0 0 0 10 2 0 3 0 4 0 0 10 2 0 3 0 4 0 - 5 0 2 0 0 15 0 10 0 5 0 0 0 10 2 0 3 0 4 0 - 5 0 EMC /% db Figure 6.11. Average energy of water binding by sugar cane component parts of cane variety R 570 aged 52 weeks. 262

value extracted from Tables 4.17 – 4.21 and corrected for residual moisture content. The<br />

H 1 values were extracted from Table 6.3. The results are shown in Table 6.6.<br />

Table 6.6. Comparison of the calculated bound water (primary, secondary and tertiary)<br />

with the Brix-free water values of the nine cane components of R 570 of two ages.<br />

Sample 52 weeks 36 weeks<br />

Bound water at moisture content/% Brix-free water/% Bound water at moisture content/% Brix-free water/%<br />

Primary Secondary Tertiary Primary Secondary Tertiary<br />

Stalk fibre 8 10 22 12.37 6 9 20 14.37<br />

Stalk pith 10 11 20 25.05 - 14 22 22.48<br />

Rind fibre 9 10 21 12.02 7 10 21 13.65<br />

Rind fines 8 10 22 11.47 7 13 30 15.58<br />

Top fibre 10 13 23 16.76 12 14 25 15.82<br />

Dry leaf fibre 10 13 20 16.13 13 14 25 15.70<br />

Dry leaf fines 14 15 26 18.17 8 10 25 17.64<br />

Green leaf fibre - 15 21 13.77 8 10 25 13.63<br />

Green leaf fines 9 10 25 14.79 7 9 20 16.20<br />

It can be seen from Table 6.6 that the Brix-free water values of sugar cane component parts<br />

correspond most closely to the secondary bound water, except those of stalk pith with<br />

inherent high surface area, which indicate the similarity to the tertiary bound water, or the<br />

free water point, reported by some research workers (Kaleemullah and Kailappan, 2007;<br />

Arslan and Toğrul, 2005). Kaleemullah and Kailappan (2007) found the primary,<br />

secondary and tertiary bound waters of red chillies end at moisture contents of 1.5, 14 and<br />

53.6% db respectively.<br />

261

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