You also want an ePaper? Increase the reach of your titles
YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.
Table 5.23. Parameters of the sorption isotherm models, coefficient of determination R 2 , mean relative deviation modulus P,<br />
and standard errors of the estimate E s for isotherms of top fibre aged 52 and 36 weeks at 30, 45, 55 and 60 o C.<br />
Top fibre<br />
Model Parameter 52 weeks 36 weeks<br />
30 o C 45 o C 55 o C 60 o C 30 o C 45 o C 55 o C 60 o C<br />
GAB mo 5.60 4.44 3.24 3.44 5.51 4.55 3.24 2.94<br />
b 29.86 11.49 14.64 16.26 13.10 9.561 14.64 22.14<br />
c 0.8238 0.8774 0.9298 0.9309 0.8217 0.8783 0.9298 0.9302<br />
R 2 0.9840 0.9900 0.8979 0.9262 0.9797 0.9397 0.8979 0.9361<br />
P 6.571 5.944 18.51 10.99 6.556 12.00 13.78 15.54<br />
Es 1.508 1.427 6.411 5.219 1.676 3.596 5.706 4.090<br />
Hailwood Horrobin b 0.008 0.007 -0.011 0.008 0.014 0.005 -0.007 -0.017<br />
c 0.164 0.228 0.342 0.284 0.161 0.233 0.345 0.396<br />
d -0.140 -0.207 -0.310 -0.272 -0.143 -0.211 -0.317 -0.356<br />
R 2 0.984 0.991 0.871 0.926 0.980 0.941 0.898 0.936<br />
P 6.658 7.678 16.61 10.74 6.208 13.32 13.25 14.13<br />
Es 1.514 1.362 6.377 5.214 1.736 3.535 5.676 4.012<br />
Henderson b 0.01278 0.03459 0.04999 0.07052 0.01916 0.03405 0.05952 0.05529<br />
c 1.725 1.401 1.272 1.143 1.611 1.396 1.221 1.274<br />
R 2 0.9588 0.9824 0.9514 0.9494 0.9825 0.9739 0.9529 0.9550<br />
P 9.959 8.522 14.50 17.15 7.384 10.27 15.29 14.03<br />
Es 1.642 1.935 6.544 5.719 1.423 3.347 6.083 4.913<br />
Bradley b 4.118 2.520 1.811 1.564 3.716 2.491 1.690 1.766<br />
c 0.8337 0.8553 0.8777 0.8899 0.8317 0.8592 0.8796 0.8688<br />
R 2 0.9843 0.9854 0.8546 0.9068 0.9859 0.9451 0.8773 0.9099<br />
P 9.774 12.23 26.45 28.12 7.306 15.22 28.56 26.16<br />
Es 1.336 1.484 6.028 5.241 1.248 3.030 5.561 4.265<br />
Caurie I b 0.1309 0.1576 0.1721 0.1884 0.1410 0.1562 0.1815 0.1793<br />
mo 0.8293 0.8263 0.8200 0.8084 0.8422 0.8176 0.8279 0.8541<br />
R 2 0.9630 0.9810 0.9714 0.9750 0.9687 0.9692 0.9783 0.9887<br />
P 9.682 8.656 11.10 12.32 10.46 10.89 9.873 6.142<br />
Es 2.180 1.619 5.010 4.215 2.251 2.708 4.455 2.911<br />
Smith b -6.359 -7.402 -8.891 -9.927 -6.269 -7.628 -9.049 -8.239<br />
c 4.879 2.561 0.520 -0.6243 4.265 2.560 -0.0208 0.3250<br />
R 2 0.9799 0.9941 0.8734 0.9262 0.9798 0.9538 0.8974 0.9317<br />
P 8.223 6.175 17.63 16.87 9.233 10.99 17.89 16.51<br />
Es 1.511 0.9422 5.627 4.663 1.493 2.778 5.085 3.715<br />
Oswin b 10.004 8.355 6.957 6.981 9.314 8.384 6.638 6.347<br />
c 0.281 0.346 0.428 0.446 0.292 0.354 0.441 0.430<br />
R 2 0.970 0.992 0.900 0.941 0.972 0.962 0.921 0.958<br />
P 12.09 8.867 10.72 12.41 12.90 12.08 9.742 6.382<br />
Es 1.849 1.092 4.998 4.177 1.748 2.532 4.452 2.895<br />
Halsey b 2.705 2.262 2.054 1.850 2.563 2.260 1.964 2.053<br />
c 250.1 63.19 35.22 20.54 145.8 65.81 26.01 29.73<br />
R 2 0.9411 0.9534 0.9550 0.9636 0.9366 0.9401 0.9648 0.9785<br />
P 13.44 14.31 15.76 15.39 15.44 14.57 14.61 9.986<br />
Es 2.909 2.472 5.026 4.627 2.977 3.180 4.552 2.949<br />
Caurie II b 1.225 0.8475 0.6543 0.4202 1.067 0.8597 0.5358 0.5839<br />
c 2.079 2.492 2.733 3.056 2.217 2.504 2.851 2.717<br />
R 2 0.9673 0.9545 0.9239 0.9327 0.9826 0.9486 0.9282 0.9221<br />
P 9.744 13.99 16.58 18.88 7.016 13.12 17.26 18.02<br />
Es 2.261 3.535 7.973 7.416 2.247 4.691 7.598 6.538<br />
Modified GAB b 5.639 4.161 3.202 3.347 5.415 4.146 3.068 2.870<br />
c 0.822 0.885 0.930 0.933 0.825 0.890 0.934 0.933<br />
d 786.808 1767.520 200000000 2359.258 468.075 2573.757 300000000 700000000<br />
R 2 0.984 0.991 0.871 0.926 0.980 0.941 0.898 0.935<br />
P 6.709 7.702 14.775 10.720 6.218 13.414 12.203 12.708<br />
Es 1.508 1.340 6.357 5.214 1.673 3.527 5.671 4.035<br />
Kuhn b -0.4199 -0.4952 -0.6169 -0.6673 -0.4168 -0.5218 -0.6240 -0.5621<br />
c 10.05 8.499 7.244 7.188 9.316 8.504 6.884 6.678<br />
R 2 0.8276 0.9017 0.8925 0.9091 0.8392 0.9045 0.9058 0.9418<br />
P 30.79 32.89 35.09 39.23 33.18 34.38 34.82 29.20<br />
Es 4.427 3.854 5.185 5.177 4.215 3.997 4.872 3.429<br />
Iglesias - Chirife b 0.420 0.496 0.618 0.668 0.417 0.522 0.625 0.563<br />
c 10.233 8.719 7.517 7.484 9.501 8.735 7.160 6.927<br />
R 2 0.826 0.901 0.892 0.908 0.838 0.904 0.905 0.941<br />
P 30.89 33.09 35.35 39.49 33.32 34.58 35.09 29.41<br />
Es 4.444 3.873 5.198 5.194 4.232 4.016 4.887 3.446<br />
Mizrahi b -10.23 -8.719 -7.517 -7.484 -9.501 -8.735 -7.160 -6.927<br />
c -9.813 -8.224 -6.900 -6.816 -9.084 -8.213 -6.536 -6.364<br />
R 2 0.826 0.901 0.892 0.908 0.838 0.904 0.905 0.941<br />
P 30.85 33.09 35.35 39.49 33.32 34.58 35.10 29.41<br />
Es 4.445 3.873 5.198 5.194 4.232 4.016 4.887 3.446<br />
Modified BET mo 2.695 2.799 3.106 3.298 2.601 2.894 3.096 2.841<br />
b 40000000 50000000 30000000 20000000 20000000 100000000 30000000 60000000<br />
R 2 0.516 0.786 0.857 0.895 0.578 0.797 0.882 0.909<br />
P 41.15 32.25 28.72 20.94 39.30 32.10 25.12 25.91<br />
Es 7.415 5.688 5.973 5.569 6.830 5.833 5.457 4.292<br />
Note: m o, b, c and d are constants.<br />
216
Change language