PDF of contents and abstracts - SEPM
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PDF of contents and abstracts - SEPM
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CO 2 CONCENTRATIONS IN VERTISOLS: SEASONAL VARIABILITY AND<br />
SHRINK–SWELL<br />
DANIEL O. BREECKER AND JUNYEON YOON<br />
Department <strong>of</strong> Geological Sciences, The University <strong>of</strong> Texas at Austin, 1 University Station<br />
C1100, Austin, Texas 78712, USA<br />
e-mail: breecker@jsg.utexas.edu<br />
LAUREN A. MICHEL<br />
Department <strong>of</strong> Geology, Baylor University, One Bear Place #97354, Waco, Texas 76798, USA<br />
TAKELE M. DINKA<br />
Soil <strong>and</strong> Crop Sciences Department, Texas A&M University, 2474 TAMU, College Station,<br />
Texas 77843, USA<br />
STEVEN G. DRIESE, JASON S. MINTZ, AND LEE C. NORDT<br />
Department <strong>of</strong> Geology, Baylor University, One Bear Place #97354, Waco, Texas 76798, USA<br />
KATHERINE D. ROMANAK<br />
Bureau <strong>of</strong> Economic Geology, The University <strong>of</strong> Texas at Austin, Austin, Texas 78712, USA<br />
AND<br />
CRISTINE L.S. MORGAN<br />
Soil <strong>and</strong> Crop Sciences Department, Texas A&M University, 2474 TAMU, College Station,<br />
Texas 77843, USA<br />
ABSTRACT: The paleosol–carbonate CO 2 barometer is widely accepted to be the most reliable method<br />
for reconstructing Earth’s atmospheric CO 2 concentrations in deep time. Currently, the largest source <strong>of</strong><br />
error in atmospheric CO 2 calculated using the paleosol barometer originates from uncertainty in soil CO 2<br />
concentrations during soil carbonate formation. Many <strong>of</strong> the paleosols used for CO 2 reconstruction were<br />
formed in clay-rich alluvium <strong>and</strong> have vertic properties, which may influence soil CO 2 .We hypothesized<br />
that the cracking during drying <strong>of</strong> shrink–swell clays results in rapid CO 2 escape <strong>and</strong> low soil CO 2<br />
concentrations. We tested our hypothesis by monitoring soil cracking <strong>and</strong> the concentration <strong>of</strong> CO 2 in the<br />
pore spaces <strong>of</strong> surface Vertisols (the Houston Black <strong>and</strong> Heiden series fine, smectitic, thermic Udic<br />
Haplusterts). Crack porosity <strong>of</strong> soils was estimated by measuring soil subsidence, <strong>and</strong> CO 2 was measured<br />
in syringe samples collected from soil gas wells. During the period <strong>of</strong> study, pore-space CO 2<br />
concentrations at ~1-m soil depth varied by two orders <strong>of</strong> magnitude, from 10% during water-saturated<br />
conditions to