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PDF of contents and abstracts - SEPM

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CARBON STABLE ISOTOPE COMPOSITION OF MODERN CALCAREOUS<br />

SOIL PROFILES IN CALIFORNIA: IMPLICATIONS FOR CO 2<br />

RECONSTRUCTIONS FROM CALCAREOUS PALEOSOLS<br />

NEIL J. TABOR AND TIMOTHY S. MYERS<br />

Roy M. Huffington Department <strong>of</strong> Earth Sciences, Southern Methodist University, Dallas,<br />

Texas 75275-0395, USA<br />

e-mail: ntabor@smu.edu<br />

ERIK GULBRANSON<br />

Department <strong>of</strong> Geosciences, University <strong>of</strong> Wisconsin, Milwaukee, Wisconsin 53201, USA<br />

CRAIG RASMUSSEN<br />

Soil, Water <strong>and</strong> Environmental Science, University <strong>of</strong> Arizona, Tucson, Arizona 85721, USA<br />

AND<br />

NATHAN D. SHELDON<br />

Department <strong>of</strong> Geological Sciences, University <strong>of</strong> Michigan, Ann Arbor,<br />

Michigan 48105-1005, USA<br />

ABSTRACT: Fourteen soil pr<strong>of</strong>iles from California were collected in order to measure the δ 13 C <strong>of</strong><br />

coexisting soil calcite <strong>and</strong> organic matter. Thirteen <strong>of</strong> the pr<strong>of</strong>iles contained a measurable amount <strong>of</strong><br />

calcite ranging from 0.04 to 54.6 wt %. Soil calcite δ 13 CPDB (δ 13 C value vs. the calcite st<strong>and</strong>ard Peedee<br />

Belemnite) values range from -14.4 to 1.3‰, whereas organic matter δ 13 CPDB values range from -24.0 to -<br />

27.7‰.<br />

The hydrology <strong>of</strong> these pr<strong>of</strong>iles is divided into two broad groups: (1) soils characterized by gravitydriven,<br />

piston-type vertical flow through the pr<strong>of</strong>ile <strong>and</strong> (2) soils affected by groundwater within the<br />

pr<strong>of</strong>ile at depths where calcite is present. The difference between soil calcite <strong>and</strong> organic matter δ 13 CPDB<br />

values, ∆ 13 C cc-om , is smaller in pr<strong>of</strong>iles affected by groundwater saturation as well as most Vertisols <strong>and</strong><br />

may be a product <strong>of</strong> waterlogging. The larger ∆ 13 C cc-om values in soils with gravity-driven flow are<br />

consistent with open-system mixing <strong>of</strong> tropospheric CO 2 <strong>and</strong> CO 2 derived from in situ oxidation <strong>of</strong> soil<br />

organic matter with mean soil PCO 2 values potentially in excess <strong>of</strong> ~20,000 ppmV at the time <strong>of</strong> calcite<br />

crystallization. There is a correlation between estimates <strong>of</strong> soil PCO 2 <strong>and</strong> a value termed “E PPT-U ”<br />

(kJm2/yr) among the soil pr<strong>of</strong>iles characterized by gravity-driven flow. E PPT-U is the energy flux through<br />

the soil during periods <strong>of</strong> soil moisture utilization, <strong>and</strong> it is the product <strong>of</strong> water mass <strong>and</strong> temperature in<br />

the pr<strong>of</strong>ile during the growing season. Thus, soils with high water-holding capacity/storage <strong>and</strong>/or<br />

low/high growing season temperature may form soil calcite in the presence <strong>of</strong> high soil PCO 2 , <strong>and</strong> vice<br />

versa. The results <strong>of</strong> this research have important implications for reconstructions <strong>of</strong> paleoclimate from<br />

stable carbon isotopes <strong>of</strong> calcareous paleosol pr<strong>of</strong>iles.

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