Etudes et évaluation de processus océaniques par des hiérarchies ...
Etudes et évaluation de processus océaniques par des hiérarchies ... Etudes et évaluation de processus océaniques par des hiérarchies ...
184 10 CHAPTER 3. PHYSICAL PROPERTIES OF SEA WATER named after William Dittmar who, in 1884, analysed the waters collected by the scientific expedition of the British corvette, HMS Challenger (1872–1876). The major constituents of sea salt are shown in table 3.1. Small regional variations of the composition of sea salt are however present in the ocean and will probably to be included in the determination of a futur equation of state with a higher degree of accuracy. tel-00545911, version 1 - 13 Dec 2010 Salt percentage Chloride 54 Sodium 31 Sulfate 8 Magnesium 4 Calcium 1 Potassium 1 others 1 Table 3.1: Major constituents of sea salt 3.2 Temperature and Potential Temperature Temperature is measured in degrees Celsius ( o C) and temperature differences in Kelvin (K), oceanographers are however slow in adapting to the SI unit Kelvin to measure temperature differences. The temperature of the world ocean typically ranges from −2 o C (−1.87 o C freezing point for S = 35 at surface) (freezing temperature of sea water) to 32 o C. About 75% of the world ocean volume has a temperature below 4 o C. Before the opening of the Drake Passage 30 million years ago due to continental drift, the mean temperature of the world ocean was much higher. The temperature difference in the equatorial ocean between surface and bottom waters was about 7K compared to the present value of 26K. The temperature in the Mediterranean Sea is above 12 o C even at the bottom and in the Red Sea it is above 20 o C. If one takes a mass of water at the surface and descends it adiabatically (without exchanging heat with the environment) its in situ (latin for: in position; the temperature you actually measure if you put a thermometer in the position) temperature will increase due to the increase of pressure. Indeed if you take a horizontal tube that is 5km long and filled with water of salinity S = 35psu and temperature T = 0 o C and put the tube to the vertical then the temperature in the tube will monotonically increase with depth reaching T = 0.40 o C at the bottom. To get rid of this temperature increase in measurements oceanographers often use potential temperature θ (measured in o C) that is the temperature of a the water mass when it is lifted adiabatically to the sea surface. It is always preferable to use potential temperature, rather than in situ temperature, as it is a conservative tracer (see section 3.7). Differences between temperature and potential temperature are small in the ocean < 1.5K, but can be important in the deep ocean where temperature differences are small.
185 3.3. θ-S DIAGRAMS 11 3.3 θ-S Diagrams If one mixes the mass m 1 (measured in kg) of sea water of salinity S 1 with the mass m 2 of sea water of salinity S 2 one obtains the mass m 1 + m 2 of sea water of salinity S 3 = m 1S 1 + m 2 S 2 m 1 + m 2 . (3.2) This follows from the definition of the salinity and the mass conservation. If one mixes the mass m 1 of sea water of temperature θ 1 with the mass m 2 kg of sea water of temperature θ 2 one obtains the mass m 1 + m 2 of sea water of temperature (see fig. 3.3) θ 3 = m 1θ 1 + m 2 θ 2 m 1 + m 2 . (3.3) tel-00545911, version 1 - 13 Dec 2010 The above is only strictly true if the heat capacity does not vary with temperature and salinity, which is approximatrely true if we restrict ourselves to oceanic values (errors are typically smaller than 1%), and when the (negligible) heat of mixing is neglected. The analysis of water masses are performed with the help of θ-S diagrams as shown in fig. 3.3 θ ( o C) ✻ θ 1 – θ 3 – θ 2 – S 1 S 3 S 2 ✲ S (psu) θ ( o C) ✻ θ 1 – θ 3 – θ 4 – θ 2 – S 1 S 2 S 4 ✲ S 3 S (psu) Figure 3.1: θ-S–diagram. Left: mixing of two water masses, the mixture of two water masses lies on a line between water masses. Right: mixing of three water masses, the mixture of 3 water masses lies within the triangle formed by the three water masses. The exact location can be obtained by eqs. 3.2 and 3.3. 3.4 Pressure Pressure is measured in Pascal (1 Pa = 1 N m −2 ). When pressure is considered, oceanographers usually mean hydrostatic pressure: p(x,y,z) = p atmos + g ∫ 0 z ρ(z ′ )dz ′ , (3.4)
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- Page 183 and 184: 177 Contents 1 Preface 5 tel-005459
- Page 185 and 186: 179 Chapter 1 Preface tel-00545911,
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- Page 199 and 200: 193 4.2. FRESH WATER FLUX 19 water.
- Page 201 and 202: 195 Chapter 5 Dynamics of the Ocean
- Page 203 and 204: 197 5.2. THE LINEARIZED ONE DIMENSI
- Page 205 and 206: 199 5.4. TWO DIMENSIONAL STATIONARY
- Page 207 and 208: 201 5.6. THE CORIOLIS FORCE 27 Whic
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185<br />
3.3. θ-S DIAGRAMS 11<br />
3.3 θ-S Diagrams<br />
If one mixes the mass m 1 (measured in kg) of sea water of salinity S 1 with the mass m 2 of sea<br />
water of salinity S 2 one obtains the mass m 1 + m 2 of sea water of salinity<br />
S 3 = m 1S 1 + m 2 S 2<br />
m 1 + m 2<br />
. (3.2)<br />
This follows from the <strong>de</strong>finition of the salinity and the mass conservation.<br />
If one mixes the mass m 1 of sea water of temperature θ 1 with the mass m 2 kg of sea water<br />
of temperature θ 2 one obtains the mass m 1 + m 2 of sea water of temperature (see fig. 3.3)<br />
θ 3 = m 1θ 1 + m 2 θ 2<br />
m 1 + m 2<br />
. (3.3)<br />
tel-00545911, version 1 - 13 Dec 2010<br />
The above is only strictly true if the heat capacity does not vary with temperature and salinity,<br />
which is approximatrely true if we restrict ourselves to oceanic values (errors are typically<br />
smaller than 1%), and when the (negligible) heat of mixing is neglected.<br />
The analysis of water masses are performed with the help of θ-S diagrams as shown in fig. 3.3<br />
θ ( o C)<br />
✻<br />
θ 1 –<br />
θ 3 –<br />
θ 2 –<br />
S 1<br />
S 3<br />
S 2<br />
✲<br />
S (psu)<br />
θ ( o C)<br />
✻<br />
θ 1 –<br />
θ 3 –<br />
θ 4 –<br />
θ 2 –<br />
S 1<br />
S 2<br />
S 4<br />
✲<br />
S 3<br />
S (psu)<br />
Figure 3.1: θ-S–diagram. Left: mixing of two water masses, the mixture of two water masses<br />
lies on a line b<strong>et</strong>ween water masses. Right: mixing of three water masses, the mixture of 3<br />
water masses lies within the triangle formed by the three water masses. The exact location can<br />
be obtained by eqs. 3.2 and 3.3.<br />
3.4 Pressure<br />
Pressure is measured in Pascal (1 Pa = 1 N m −2 ). When pressure is consi<strong>de</strong>red, oceanographers<br />
usually mean hydrostatic pressure:<br />
p(x,y,z) = p atmos + g<br />
∫ 0<br />
z<br />
ρ(z ′ )dz ′ , (3.4)