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Etude de la combustion de gaz de synthèse issus d'un processus de ...

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Experimental set ups and diagnostics<br />

high pressure auto-ignition of combustible mixtures as it gives direct measure of<br />

ignition <strong>de</strong><strong>la</strong>y (Mittal, 2006). When the interest is the heat transfer to the walls then it is<br />

usually used an inert gas, with equal adiabatic coefficient as the reacting mixture, as a<br />

test gas. In this work instead of an inert gas a stoichiometric syngas-air mixture was<br />

used out of auto-ignition conditions. A set of three experiments were ma<strong>de</strong> for each<br />

syngas composition without <strong>combustion</strong> in or<strong>de</strong>r to verify its repetition. The pressure<br />

traces are shown in figure 3.9 for downdraft syngas composition.<br />

Figure 3.9 shows rapid rise in pressure during the compression stroke followed by<br />

gradual <strong>de</strong>crease in pressure due to heat loss from a constant volume chamber, the<br />

clearance volume, at the end of compression. A very good repetition of signals was<br />

found during compression experiments being the maximum difference between<br />

pressure peaks around 0.3 bar (25 bar on average) from one experiment to another.<br />

tel-00623090, version 1 - 13 Sep 2011<br />

Pressure (bar)<br />

30<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

Shot 1<br />

Shot 2<br />

Shot 3<br />

90 100 110 120 130 140 150 160 170 180<br />

Time (ms)<br />

Figure 3.9 - Pressure versus time for compression of stoichiometric downdraft syngas-air in a<br />

RCM. Initial conditions: P i = 1.0 bar; T i = 293 K, ε=11.<br />

1200<br />

1000<br />

Volume (cm 3 )<br />

800<br />

600<br />

400<br />

200<br />

0<br />

0 5 10 15 20 25 30 35 40 45 50<br />

Time (ms)<br />

Figure 3.10 - Typical volume trace for compression of stoichiometric downdraft syngas -air in an<br />

RCM. Initial conditions: P i = 1.0 bar; T i = 293 K, ε=11.<br />

74

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