Etude de la combustion de gaz de synthèse issus d'un processus de ...

Etude de la combustion de gaz de synthèse issus d'un processus de ... Etude de la combustion de gaz de synthèse issus d'un processus de ...

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Chapter 2 γb−1 Tu γu −γb ( γ 1) ( 1 ) u − Ti γu − γb−1 Tu γu −γ ⎡ b ( γ −1) ( γ −1 ) p− p ⎡ i + x = ⎣ p − p + ⎣ e i u Ti u ⎤ ⎦ ⎤ ⎦ (2.79) As a final step, the above result is written fully in terms of pressure using Eq. (2.62). For later use, the result is given in a more concise form: p − pf i ( p) x = p − pf( p) e i (2.80) Where ⎛γb −1⎞ ⎛γu −γ ⎞⎛ b p ⎞ f( p) = ⎜ ⎟+ ⎜ ⎟⎜ ⎟ ⎝γu −1⎠ ⎝ γu −1 ⎠⎝ pi ⎠ ( γ −1/ ) γ u u (2.81) tel-00623090, version 1 - 13 Sep 2011 Differentiation is straightforward, yielding Where '( )[ − i ( )] [ − ] 2 dx 1 − pf i '( p) pif p p pf p = + dp p − p f ( p) p pf( p) e i e i ⎛γu − γ ⎞⎛ b p ⎞ pf i '( p) = ⎜ ⎟⎜ ⎟ ⎝ γ u ⎠⎝pi ⎠ −1/ γu (2.82) (2.83) The above methodology was extended to multiple zones by Luijten et al., (2009) without considerable improvement in the results. The linear approximation, introduced by Lewis and Von Elbe, is still the most widespread analytical relation to interpret burning velocity data. Differences in laminar burning velocities between the varieties of x(p) were quantified by Luijten et al., (2009) for the example case of stoichiometric methane–air combustion, demonstrating that deviations between burning velocities from bomb data and other methods can at least partly be ascribed to the limited accuracy of the linear approximation. For the example case, differences up to 8% were found. 2.5.2.4 Constant pressure method Laminar burning velocity and Markstein length can be deduced from schlieren photographs as described by Bradley et al., (1998). For a spherically expending flame, 57

Bibliographic revision the stretched flame velocity, S n , reflecting the flame propagation speed, is derived from the flame radius versus time data as: S n dr u = (2.84) dt where r u is the radius of the flame in schlieren photographs and t is the time. S n can be directly obtained from the flame photo. For expanding spherical flame with instantaneous surface area A= 4πr u 2 , the flame stretch rate is solely due to the change in curvature with time. From Eq. (2.2) and (2.29) the stretch rate can be simplified as tel-00623090, version 1 - 13 Sep 2011 1 dA 2 dru 2 α = = = Sn (2.85) Adt r dt r u Where r u is the instantaneous radius of the flame. Asymptotic analyses of Matalon and Matkowsky, (1982) and detailed modelling of Warnatz and Peters, (1984) show a linear relationship between stretch rate and burning velocity in the low-stretch regime. Thus, it is assumed that, 0 n n b u S − S = L κ (2.86) 0 where Sn is the unstretched flame speed, and L b is the Markstein length of burned gases. From Eqs. (2.84) and (2.85), the stretched flame speed, S n , and flame stretch rate, κ, can be calculated. The unstretched flame speed is obtained as the intercept value at κ = 0, in the plot of S n against κ, and the burned gas Markstein length is the slope of S n –κ curve. Markstein length can reflect the stability of flame (Liao et al., 2004). Positive values of L b indicate that the flame speed decreases with the increase of flame stretch rate. In this case, if any kind of perturbation or small structure appears on the flame front (stretch increasing), this structure tends to be suppressed during flame propagation, and this makes the flame stability. In contrast to this, a negative value of L b means that the flame speed increases with the increase of flame stretch rate. In this case, if any kinds of protuberances appear at the flame front, the flame speed in the flame protruding position will be increased, and this increases the instability of the flame. 58

Chapter 2<br />

γb−1<br />

Tu γu −γb<br />

( γ 1) ( 1 )<br />

u − Ti γu<br />

−<br />

γb−1<br />

Tu γu −γ<br />

⎡<br />

b<br />

( γ −1) ( γ −1<br />

)<br />

p− p ⎡<br />

i<br />

+<br />

x =<br />

⎣<br />

p − p +<br />

⎣<br />

e i u Ti u<br />

⎤<br />

⎦<br />

⎤<br />

⎦<br />

(2.79)<br />

As a final step, the above result is written fully in terms of pressure using Eq. (2.62).<br />

For <strong>la</strong>ter use, the result is given in a more concise form:<br />

p − pf<br />

i<br />

( p)<br />

x =<br />

p − pf( p)<br />

e<br />

i<br />

(2.80)<br />

Where<br />

⎛γb −1⎞ ⎛γu −γ<br />

⎞⎛<br />

b p ⎞<br />

f( p)<br />

= ⎜ ⎟+<br />

⎜ ⎟⎜ ⎟<br />

⎝γu −1⎠ ⎝ γu −1<br />

⎠⎝ pi<br />

⎠<br />

( γ −1/<br />

) γ<br />

u<br />

u<br />

(2.81)<br />

tel-00623090, version 1 - 13 Sep 2011<br />

Differentiation is straightforward, yielding<br />

Where<br />

'( )[ −<br />

i<br />

( )]<br />

[ − ] 2<br />

dx 1 − pf<br />

i<br />

'( p)<br />

pif p p pf p<br />

= +<br />

dp p − p f ( p) p pf( p)<br />

e i e i<br />

⎛γu<br />

− γ ⎞⎛<br />

b<br />

p ⎞<br />

pf<br />

i<br />

'( p)<br />

= ⎜ ⎟⎜ ⎟<br />

⎝ γ<br />

u ⎠⎝pi<br />

⎠<br />

−1/<br />

γu<br />

(2.82)<br />

(2.83)<br />

The above methodology was exten<strong>de</strong>d to multiple zones by Luijten et al., (2009)<br />

without consi<strong>de</strong>rable improvement in the results.<br />

The linear approximation, introduced by Lewis and Von Elbe, is still the most<br />

wi<strong>de</strong>spread analytical re<strong>la</strong>tion to interpret burning velocity data. Differences in <strong>la</strong>minar<br />

burning velocities between the varieties of x(p) were quantified by Luijten et al., (2009)<br />

for the example case of stoichiometric methane–air <strong>combustion</strong>, <strong>de</strong>monstrating that<br />

<strong>de</strong>viations between burning velocities from bomb data and other methods can at least<br />

partly be ascribed to the limited accuracy of the linear approximation. For the example<br />

case, differences up to 8% were found.<br />

2.5.2.4 Constant pressure method<br />

Laminar burning velocity and Markstein length can be <strong>de</strong>duced from schlieren<br />

photographs as <strong>de</strong>scribed by Bradley et al., (1998). For a spherically expending f<strong>la</strong>me,<br />

57

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