Etude de la combustion de gaz de synthèse issus d'un processus de ...
Etude de la combustion de gaz de synthèse issus d'un processus de ... Etude de la combustion de gaz de synthèse issus d'un processus de ...
Chapter 2 fundamental processes such as ignition, NO, and soot formation, and flame quenching. Moreover, some turbulent flame models prescribe the turbulent burning velocity as a function of laminar burning velocity. Thus, detailed information describing the dependence of the laminar burning velocity, flame thickness, ignition temperature, heat release rate and flame quenching on various system parameters can be a valuable diagnostic and design aid. tel-00623090, version 1 - 13 Sep 2011 There is a significant discrepancy in measuring burning velocities, which gives an indication of the difficulties and uncertainties associated with experimental determination of flame properties. In the light of the earlier experimental studies of Markstein, (1964), the asymptotic analysis of Klimov, (1963), and the computations of laminar flame structure with detailed chemical kinetics by several researchers, all of which show the importance of the flame stretch rate (Dixon-Lewis, 1991). There can be little doubt that this is often neglected key variable (Law, 1989). It follows that any experimental or computed value of laminar burning velocity should be associated with a value of the flame stretch rate. Ideally, the stretch-free value of the burning velocity should be quoted and the influence of stretch rate upon this value should be indicated by the value of the appropriated Markstein length. For these reasons this chapter begins with the definition of stretch rate and the corresponding Karlovitz and Markstein numbers. Following, the theory evolved with the burning velocity determination are described with emphasis for the constant volume and constant pressure methods due to be extensively used. This part of the chapter ends with the flammability limits description as is another important parameter of premixed laminar flames. 2.5.1 Flame stretch A flame surface propagating in a uniform flow field is submitted to strain and curvature effects leading to changes in the frontal area. Karlovitz et al., (1953) and Markstein, (1964) initiated the study of stretched premixed flames and demonstrated the importance of the aerodynamic stretching and the preferential diffusion on the flame response in terms of flame front instability. The flame stretch factor (κ) is defined as the relative rate of change of flame surface area (A) (Williams, 1985): 41
Bibliographic revision 1 d( δ A) 1 dA κ = = (2.2) δ A dt A dt The effect of stretch on the flame is to reduce the thickness of the flame front and hence the flame speed and influence the flame structure through its coupled effect with mass and heat diffusion. The concept of flame stretch can be applied to laminar flame speed; flame stabilization; flammability limits; and modeling of turbulent flames. Let’s first derive the basic relationship between the stretch rate and the strain rate, dilatation of the fluid element, and curvature of the flame surface. The three perpendicular coordinates on a curved flame surface are shown in Fig. 2.7, which has two unit vectors (ν and η ) tangent to the flame surface and an outward normal unit vector n , at the spatial point r( νη , , n) as a function of the three independent coordinates. tel-00623090, version 1 - 13 Sep 2011 Figure 2.7 - Curved laminar flame front with three perpendicular curvilinear coordinates. The elemental arc ( ds ) ν are given by: in the directionν and the elemental arc ( ) ⎛δr ⎞ ⎛δr ⎞ ds = d ds = dη ν ⎜ η ⎜ ⎟ δν ⎟ ⎝ ⎠ ⎝δη ⎠ ( ) ν , ( ) n η ν ds η in the direction η (2.3) The elemental flame surface can be calculated by: ⎛δr δr ⎞ dA t ⎜ ⎟ n d d ⎝δν δη ⎠ () = × ⋅ ( ν )( η ) (2.4) In the orthogonal curvilinear coordinates system, the two unit vectors e , e can be given by: δr δν δr δη e = , e and e e n ν = × = δr δν η δr δη ν η (2.5) ν η Thus: 42
- Page 1 and 2: THÈSE Pour l’obtention du Grade
- Page 3 and 4: Acknowledgements Acknowledgements T
- Page 5 and 6: Résumé __________________________
- Page 7 and 8: Nomenclature Nomenclature Roman tel
- Page 9 and 10: Nomenclature Subscripts tel-0062309
- Page 11 and 12: Contents tel-00623090, version 1 -
- Page 13 and 14: Contents 6.4. SYNGAS FUELLED-ENGINE
- Page 15 and 16: Introduction CHAPTER 1 INTRODUCTION
- Page 17 and 18: Introduction proves to have higher
- Page 19 and 20: Introduction Chapter 3 - Experiment
- Page 21 and 22: Bibliographic revision CHAPTER 2 BI
- Page 23 and 24: Bibliographic revision point today
- Page 25 and 26: Bibliographic revision - Boudouard
- Page 27 and 28: Bibliographic revision Table 2.1 -
- Page 29 and 30: Bibliographic revision Biomass Dryi
- Page 31 and 32: Bibliographic revision Circulating
- Page 33 and 34: Bibliographic revision or eliminate
- Page 35 and 36: Bibliographic revision established
- Page 37 and 38: Bibliographic revision Hydrogen Hyd
- Page 39 and 40: Bibliographic revision of low moist
- Page 41 and 42: Bibliographic revision scrubbing an
- Page 43: Bibliographic revision suggests tha
- Page 47 and 48: Bibliographic revision Since n is
- Page 49 and 50: Bibliographic revision 2 ( rsr ) 2
- Page 51 and 52: Bibliographic revision This evoluti
- Page 53 and 54: Bibliographic revision The burning
- Page 55 and 56: Bibliographic revision δVG = − a
- Page 57 and 58: Bibliographic revision 2 1 − −
- Page 59 and 60: Bibliographic revision where the su
- Page 61 and 62: Bibliographic revision the stretche
- Page 63 and 64: Bibliographic revision burning velo
- Page 65 and 66: Experimental set ups and diagnostic
- Page 67 and 68: Experimental set ups and diagnostic
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- Page 71 and 72: Experimental set ups and diagnostic
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- Page 87 and 88: Experimental set ups and diagnostic
- Page 89 and 90: Chapter 4 CHAPTER 4 EXPERIMENTAL AN
- Page 91 and 92: Chapter 4 4.1 Laminar burning veloc
- Page 93 and 94: Chapter 4 4.1.1.1 Flame morphology
Bibliographic revision<br />
1 d( δ A)<br />
1 dA<br />
κ = = (2.2)<br />
δ A dt A dt<br />
The effect of stretch on the f<strong>la</strong>me is to reduce the thickness of the f<strong>la</strong>me front and<br />
hence the f<strong>la</strong>me speed and influence the f<strong>la</strong>me structure through its coupled effect with<br />
mass and heat diffusion. The concept of f<strong>la</strong>me stretch can be applied to <strong>la</strong>minar f<strong>la</strong>me<br />
speed; f<strong>la</strong>me stabilization; f<strong>la</strong>mmability limits; and mo<strong>de</strong>ling of turbulent f<strong>la</strong>mes.<br />
Let’s first <strong>de</strong>rive the basic re<strong>la</strong>tionship between the stretch rate and the strain rate,<br />
di<strong>la</strong>tation of the fluid element, and curvature of the f<strong>la</strong>me surface. The three<br />
perpendicu<strong>la</strong>r coordinates on a curved f<strong>la</strong>me surface are shown in Fig. 2.7, which has<br />
two unit vectors (ν and η ) tangent to the f<strong>la</strong>me surface and an outward normal unit<br />
<br />
vector n , at the spatial point r( νη , , n)<br />
as a function of the three in<strong>de</strong>pen<strong>de</strong>nt coordinates.<br />
tel-00623090, version 1 - 13 Sep 2011<br />
Figure 2.7 - Curved <strong>la</strong>minar f<strong>la</strong>me front with three perpendicu<strong>la</strong>r curvilinear coordinates.<br />
<br />
The elemental arc ( ds ) ν<br />
are given by:<br />
in the directionν and the elemental arc ( )<br />
<br />
<br />
⎛δr<br />
⎞<br />
⎛δr<br />
⎞<br />
ds = d ds = dη<br />
ν ⎜<br />
η ⎜ ⎟<br />
δν ⎟<br />
⎝ ⎠ ⎝δη<br />
⎠<br />
( ) ν , ( )<br />
n <br />
η ν <br />
<br />
ds η<br />
in the direction η<br />
(2.3)<br />
The elemental f<strong>la</strong>me surface can be calcu<strong>la</strong>ted by:<br />
<br />
⎛δr<br />
δr<br />
⎞ <br />
dA t ⎜ ⎟ n d d<br />
⎝δν<br />
δη ⎠<br />
() = × ⋅ ( ν )( η )<br />
(2.4)<br />
<br />
In the orthogonal curvilinear coordinates system, the two unit vectors e , e can be<br />
given by:<br />
δr<br />
<br />
<br />
δν δr<br />
δη <br />
e = , e and e e n<br />
ν = × =<br />
δr<br />
δν η <br />
δr<br />
δη<br />
ν η<br />
(2.5)<br />
ν<br />
η<br />
Thus:<br />
42