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Chapter 2<br />

with different characteristics were used, namely Herguido et al., (1992); Javier et al.,<br />

(1997); Kim et al., (2001) and Ro<strong>la</strong>ndo et al., (2002).<br />

It is expected that the rise of temperature leads to an increase in the rate of the several<br />

reactions that took p<strong>la</strong>ce during gasification process, which, globally, produce hydrogen<br />

and carbon monoxi<strong>de</strong> and eliminates hydrocarbons. At higher gasification<br />

temperatures lower solids and tar emissions are observed, which means that the<br />

produced gas may require a lower cost on gas cleaning processes.<br />

2.3.3.2. Pressure<br />

Gasifiers can be operated at elevated pressures, the advantage being for those end<br />

use applications where the gas is required to be compressed afterwards, as in a gas<br />

turbine.<br />

tel-00623090, version 1 - 13 Sep 2011<br />

Pressurized gasifiers have the following significant features:<br />

- Feeding is more complex and very costly, and has a high inert gas requirement<br />

for purging.<br />

- Capital costs of pressure equipment are much higher than for atmospheric<br />

equipment, although equipment sizes are much smaller.<br />

- Pressurized gasification systems can cost up to four times as much as<br />

atmospheric systems at power outputs up to 20 MW e . This disadvantage is<br />

countered by the higher efficiency, and this effect becomes significant at 30-50<br />

MW e , above which pressure systems are believed likely to be more economic<br />

than atmospheric systems.<br />

- Gas is supplied to the turbine at a<strong>de</strong>quate pressure, removing the need for gas<br />

compression and also permitting re<strong>la</strong>tively high tar contents in the gas; such tar<br />

needs to be completely burned in the turbine combustor.<br />

- Hot gas cleanup with mechanical filters (such as sintered metal or ceramic<br />

candles) is usually used, which reduces thermal and pressure energy losses<br />

and in principle in simpler and of lower cost than are scrubbing systems.<br />

- Overall system efficiency is higher owing to retention of sensible heat and<br />

chemical energy of tars in the product gas and the avoidance of a fuel gas<br />

compression stage ahead of the turbine. The only significant energy losses are<br />

to the environment and in provision of inert gas to the pressure fee<strong>de</strong>rs, and<br />

these can be as low as 5-8%, giving energy conversion efficiency for the<br />

gasifier itself of 92-95%. A corresponding atmospheric gasifier with water<br />

37

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