Etude de la combustion de gaz de synthèse issus d'un processus de ...

Etude de la combustion de gaz de synthèse issus d'un processus de ... Etude de la combustion de gaz de synthèse issus d'un processus de ...

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Chapter 7 (Updtraft) (Downdraft) ⎧ Su 0 =− φ + φ − ⎪ ⎨α = φ − φ + ⎪ ⎪⎩ β =− φ + φ − 2 0.413 1.056 0.355 2 4.881 9.952 6.731 2 1.469 2.786 1.561 2 ⎧ S u 0 =− 0.45φ + 1.152φ −0.354 ⎪ ⎨α = 2 0.988φ − 1.936φ + 2.502 ⎪ 2 ⎪⎩ β =− 1.194φ + 1.967φ −0.931 tel-00623090, version 1 - 13 Sep 2011 ⎧Su 0 = 0.21φ −0.073 ⎪ (Fluidized bed) ⎨α = 1.485φ + 0.639 ⎪ ⎩β =− 1.4φ + 0.882 Conclusion can be drawn that the burning velocity decreases with the increase of pressure. In opposite, an increase in temperature induces an increase of burning velocity. The higher burning velocity value is obtained for downdraft syngas. This result is endorsed to the higher heat value, lower dilution and higher volume percentage of hydrogen in the downdraft syngas. This information about laminar burning velocity of syngas-air flames is then applied on a multi-zone numerical heat transfer simulation code of the wall-flame interaction developed at the Laboratoire de Combustion et Détonique. The adapted code allows simulating the combustion of homogeneous premixed gas mixtures within constant volume spherical chamber in order to predict the quenching distance of typical syngasair flames. Thus, it was possible to establish analytical expressions of quenching distance for typical stoichiometric syngas-air flames. δ q =450 P -0.79 (μm), P>0.3 MPa (Updraft) δ q =300 P -0.89 (μm), P>0.3 MPa (Downdraft) Another major finding is that the code reproduces well the pressure evolution beyond the validity of the burning velocity correlation established in this work for updraft and downdraft syngas compositions. Fluidized bed syngas composition due to cellular flame development, which violates the assumption of spherical flame was removed from this study. Engine-like conditions were experimentally reproduced in a rapid compression machine (RCM) when working on two strokes mode simulating a single cycle of an internal combustion engine. Stationary power applications usually use natural gas as fuel, thus a methane-air mixture is also included in this work as a reference fuel for comparison with the typical syngas compositions under study. A common practice in engine testing for combustion diagnostic is, prior to the usual firing tests, to test the engine in motored 197

Conclusions conditions, therefore single compression tests were also performed in the RCM operating with and without combustion in order to identify different parameters related with its operation, namely the heat transfer to the walls. tel-00623090, version 1 - 13 Sep 2011 Higher pressures are obtained with methane-air mixture followed by downdraft-syngas and lastly by updraft-syngas. These results could be endorsed to the heat of reaction of the fuels and air to fuel ratio under stoichiometric conditions, but also to burning velocities. Updraft and downdraft syngas compositions have similar burning velocities in laminar conditions but the same is not found in turbulent conditions, where the difference in peak pressure is higher by about 25%. As the turbulent burning velocity is proportional to the laminar burning velocity, analysing the correlations for laminar burning velocity of the typical syngas compositions developed on this work show that the effect of pressure is very significant (coefficient β for updraft is 40% higher in relation to downdraft syngas coefficient). The higher pressure used on RCM also makes temperature to increase due to compression but the effect of temperature on burning velocity for typical syngas compositions is irrelevant since the coefficient α is of the order. Another major finding is that syngas typical compositions are characterized by high ignition timings due to their low burning velocities. A simulation code for the power cycle of syngas-fuelled engines has been developed, using a quasi-dimensional model with ‘standard’ modeling assumptions. Model testing has been carried on over detailed experimental data available in literature for hydrogen and methane, two of the main constituents of syngas. The very good agreement found allows validating the developed model and applied it to typical syngas compositions. An attempt to adapt the model to the RCM is made by changing several aspects of the model namely the in-cylinder volume function and burning rate model. The comparison with experimental results obtained in this work in the RCM shows that the adapted code is able to reproduce fairly well the in-cylinder pressure and that the Woschni model works well in its original formulation and represent the heat transfer of the RCM compression stroke. The validated model is then applied to a syngas-fuelled engine in order determine its performance. Conclusions can be drawn that typical syngas compositions besides its lower heat value and burning velocities can be used on SI engines even at elevated rotation speeds. 198

Conclusions<br />

conditions, therefore single compression tests were also performed in the RCM<br />

operating with and without <strong>combustion</strong> in or<strong>de</strong>r to i<strong>de</strong>ntify different parameters re<strong>la</strong>ted<br />

with its operation, namely the heat transfer to the walls.<br />

tel-00623090, version 1 - 13 Sep 2011<br />

Higher pressures are obtained with methane-air mixture followed by downdraft-syngas<br />

and <strong>la</strong>stly by updraft-syngas. These results could be endorsed to the heat of reaction of<br />

the fuels and air to fuel ratio un<strong>de</strong>r stoichiometric conditions, but also to burning<br />

velocities. Updraft and downdraft syngas compositions have simi<strong>la</strong>r burning velocities<br />

in <strong>la</strong>minar conditions but the same is not found in turbulent conditions, where the<br />

difference in peak pressure is higher by about 25%. As the turbulent burning velocity is<br />

proportional to the <strong>la</strong>minar burning velocity, analysing the corre<strong>la</strong>tions for <strong>la</strong>minar<br />

burning velocity of the typical syngas compositions <strong>de</strong>veloped on this work show that<br />

the effect of pressure is very significant (coefficient β for updraft is 40% higher in<br />

re<strong>la</strong>tion to downdraft syngas coefficient). The higher pressure used on RCM also<br />

makes temperature to increase due to compression but the effect of temperature on<br />

burning velocity for typical syngas compositions is irrelevant since the coefficient α is of<br />

the or<strong>de</strong>r. Another major finding is that syngas typical compositions are characterized<br />

by high ignition timings due to their low burning velocities.<br />

A simu<strong>la</strong>tion co<strong>de</strong> for the power cycle of syngas-fuelled engines has been <strong>de</strong>veloped,<br />

using a quasi-dimensional mo<strong>de</strong>l with ‘standard’ mo<strong>de</strong>ling assumptions. Mo<strong>de</strong>l testing<br />

has been carried on over <strong>de</strong>tailed experimental data avai<strong>la</strong>ble in literature for hydrogen<br />

and methane, two of the main constituents of syngas. The very good agreement found<br />

allows validating the <strong>de</strong>veloped mo<strong>de</strong>l and applied it to typical syngas compositions. An<br />

attempt to adapt the mo<strong>de</strong>l to the RCM is ma<strong>de</strong> by changing several aspects of the<br />

mo<strong>de</strong>l namely the in-cylin<strong>de</strong>r volume function and burning rate mo<strong>de</strong>l. The comparison<br />

with experimental results obtained in this work in the RCM shows that the adapted<br />

co<strong>de</strong> is able to reproduce fairly well the in-cylin<strong>de</strong>r pressure and that the Woschni<br />

mo<strong>de</strong>l works well in its original formu<strong>la</strong>tion and represent the heat transfer of the RCM<br />

compression stroke.<br />

The validated mo<strong>de</strong>l is then applied to a syngas-fuelled engine in or<strong>de</strong>r <strong>de</strong>termine its<br />

performance. Conclusions can be drawn that typical syngas compositions besi<strong>de</strong>s its<br />

lower heat value and burning velocities can be used on SI engines even at elevated<br />

rotation speeds.<br />

198

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