Etude de la combustion de gaz de synthèse issus d'un processus de ...
Etude de la combustion de gaz de synthèse issus d'un processus de ... Etude de la combustion de gaz de synthèse issus d'un processus de ...
Experimental and numerical laminar syngas combustion Stretch (s -1 ) 200 150 100 50 φ 1.2 1.0 0.8 0.6 0 1 2 3 4 5 6 7 Pressure (bar) Figure 4.32 – Stretch rate versus pressure for updraft syngas-air mixture at 1.0 bar. tel-00623090, version 1 - 13 Sep 2011 Stretch (s -1 ) 200 150 100 50 0 1 2 3 4 5 6 7 Pressure (bar) Figure 4.33 – Stretch rate versus pressure for downdraft syngas-air mixture at 1.0 bar. 200 φ 1.2 1.0 0.8 0.6 Stretch (s -1 ) 150 100 50 0 1.0 0.8 0.6 1 2 3 4 5 6 7 Pressure (bar) φ Figure 4.34 – Stretch rate versus pressure for fluidized bed syngas-air mixture at 1.0 bar. These figures show a very similar behavior of the stretch rate versus pressure for all the syngas–air mixtures and equivalence ratios. Stoichiometric mixtures are highly stretched and stretch decreases with the equivalence ratio. The criterion of establishing 118
Chapter 4 a minimum pressure to explore the burning velocity is doubtful because it corresponds to different stretch rate values, as easily could be seen from figures 4.32-4.34. Therefore, in this work, the criterion is a fixed stretch rate of 50 s -1 . For this level of stretch, the stretched burning velocity is close to the unstretched burning velocity. 4.1.2.3 Laminar burning velocity correlations The simultaneous change in the pressure and temperature of the unburned mixture during a closed vessel explosion makes it necessary to rely on correlations which take these effects into account like the one proposed by Metghalchi and Keck, (1980): α ⎛T ⎞ ⎛ P ⎞ = ⎜ ⎟ ⎜ ⎟ ⎝ ⎠ ⎝ ⎠ Su Su 0 T 0 P 0 β (4.15) tel-00623090, version 1 - 13 Sep 2011 Where, T 0 and P 0 , are the reference temperature and pressure, respectively. The influence of the equivalence ratio is incorporated through the temperature and pressure exponents, α and β, and through the reference burning velocity S u0 as square or linear functions. Following the procedure described in the appendix A, this three unknowns are obtained for the three typical syngas compositions and are shown in the table 4.3. In all syngas cases the temperature coefficient is positive and the pressure coefficient negative. This means that the burning velocity increases with temperature increase and decreases with the increase of pressure. The stretch rate in these correlations is lower than 50 s -1 . This means that these values of the stretched burning velocity are close to the unstretched ones. Notice the different range of validity of the expressions with the equivalence ratio and syngas composition. This is due to the unsuccessful ignition. 119
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Chapter 4<br />
a minimum pressure to explore the burning velocity is doubtful because it corresponds<br />
to different stretch rate values, as easily could be seen from figures 4.32-4.34.<br />
Therefore, in this work, the criterion is a fixed stretch rate of 50 s -1 . For this level of<br />
stretch, the stretched burning velocity is close to the unstretched burning velocity.<br />
4.1.2.3 Laminar burning velocity corre<strong>la</strong>tions<br />
The simultaneous change in the pressure and temperature of the unburned mixture<br />
during a closed vessel explosion makes it necessary to rely on corre<strong>la</strong>tions which take<br />
these effects into account like the one proposed by Metghalchi and Keck, (1980):<br />
α<br />
⎛T<br />
⎞ ⎛ P ⎞<br />
= ⎜ ⎟ ⎜ ⎟<br />
⎝ ⎠ ⎝ ⎠<br />
Su<br />
Su<br />
0<br />
T<br />
0 P<br />
0<br />
β<br />
(4.15)<br />
tel-00623090, version 1 - 13 Sep 2011<br />
Where, T 0 and P 0 , are the reference temperature and pressure, respectively. The<br />
influence of the equivalence ratio is incorporated through the temperature and pressure<br />
exponents, α and β, and through the reference burning velocity S u0 as square or linear<br />
functions.<br />
Following the procedure <strong>de</strong>scribed in the appendix A, this three unknowns are obtained<br />
for the three typical syngas compositions and are shown in the table 4.3.<br />
In all syngas cases the temperature coefficient is positive and the pressure coefficient<br />
negative. This means that the burning velocity increases with temperature increase and<br />
<strong>de</strong>creases with the increase of pressure. The stretch rate in these corre<strong>la</strong>tions is lower<br />
than 50 s -1 . This means that these values of the stretched burning velocity are close to<br />
the unstretched ones. Notice the different range of validity of the expressions with the<br />
equivalence ratio and syngas composition. This is due to the unsuccessful ignition.<br />
119