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<strong>Chemistry</strong><br />

Josh Hoppe<br />

Block 3


Honors <strong>Chemistry</strong><br />

Class Policies and Grading<br />

The students will receive a Unit Outline at the beginning of each Unit. It will have information<br />

about the assignments that they will do, what it’s grade classification will be, what action<br />

they will need to do to complete the assignment and when it is due.<br />

The students will receive a Weekly Memo of the activities they will be responsible for that<br />

week. It will serve to inform the students of the learning goal for the week. It will also give<br />

the students any special information about that week.<br />

The students will also receive daily lectures and assignments that are designed to teach and<br />

re-enforce information related to the learning goal. This will be time in which new material<br />

will be taught and reviewed and will give the students the opportunity to ask questions<br />

regarding the concepts being taught.<br />

The students will work with a Lab partner and also be in a Lab group, but it will be up to the<br />

individual student to do his or her part of all assignments and the individual student will<br />

ultimately be responsible for all information presented in the class.<br />

The students will be required to follow all District and School Policies and to follow all Lab<br />

Safety Procedures, which they will be given and will sign, while performing labs. Students<br />

should come to class on time and with the supplies needed for that class.<br />

The following grading policy will be used.<br />

Units with Projects<br />

Units without Projects<br />

(2,3,4,5) (1,6)<br />

Work 12% Work 18%<br />

Quizzes 13% Quizzes 20%<br />

Labs 25% Labs 31%<br />

Test 25% Test 31%<br />

Projects 25%<br />

The students will be given a teacher generated Mid Term and a District Final.


Unit 1<br />

Measurement Lab<br />

Separation of Mixtures Lab with Lab Write Up<br />

Unit 2<br />

Flame Test Lab<br />

Nuclear Decay Lab<br />

Element Marketing Project<br />

Unit 3<br />

Golden Penny Lab with Lab Write Up<br />

Molecular Geometry<br />

Research Presentation on a Chemical<br />

Mid Term<br />

Unit 4<br />

Double Displacement Lab<br />

Stoichiometry Lab with Lab Write Up<br />

Mole Educational Demonstration Project<br />

Unit 5<br />

Gas Laws Lab with Lab Write Up<br />

States of Matter Lab<br />

Teach a Gas Law Project<br />

Unit 6<br />

Dilutions Lab<br />

Titration Lab<br />

District Final


Unit 1 (14 days)<br />

Chapter 1 Introduction to <strong>Chemistry</strong><br />

Honors <strong>Chemistry</strong><br />

2013/2014 Syllabus<br />

1.1 The Scope of <strong>Chemistry</strong> 1.3 Thinking Like a Scientist<br />

1.2 <strong>Chemistry</strong> and You 1.4 Problem Solving in <strong>Chemistry</strong><br />

Chapter 2 Matter and Change<br />

2.1 Properties of Matter 2.3 Elements and Compounds<br />

2.2 Mixtures 2.4 Chemical Reactions<br />

Chapter 3 Scientific Measurement<br />

3.1 Using and Expressing Measurements 3.3 Solving Conversion Problems<br />

3.2 Units of Measurement<br />

Unit 2 (15 days)<br />

Chapter 4 Atomic Structure<br />

4.1 Defining the Atom 4.3 Distinguishing Among Atoms<br />

4.2 Structure of the Nuclear Atom<br />

Chapter 5 Electrons in Atoms<br />

5.1 Revising the Atomic Model 5.2 Electron Arrangement in Atoms<br />

5.3 Atomic Emission Spectrum and the Quantum Mechanical Model<br />

Chapter 6 The Periodic Table<br />

6.1 Organizing the Elements 6.3 Periodic Trends<br />

6.2 Classifying Elements<br />

Chapter 25 Nuclear <strong>Chemistry</strong><br />

25.1 Nuclear Radiation 25.3 Fission and Fusion<br />

25.2 Nuclear Transformations 25.4 Radiation in Your Life<br />

Unit 3 (11 days)<br />

Chapter 7 Ionic and Metallic Bonding<br />

7.1 Ions 7.3 Bonding in Metals<br />

7.2 Ionic Bonds and Ionic Compounds<br />

Chapter 8 Covalent Bonding<br />

8.1 Molecular Compounds 8.3 Bonding Theories<br />

8.2 The Nature of Covalent Bonding 8.4 Polar Bonds and Molecules<br />

Chapter 9 Chemical Names and Formulas<br />

9.1 Naming Ions 9.3 Naming and Writing Formulas for Molecular Compounds<br />

9.2 Naming and Writing Formulas for Ionic Compounds 9.4 Names for Acids and Bases<br />

3 days<br />

5 days<br />

6 days<br />

3 days<br />

5 days<br />

3 days<br />

3 days<br />

4 days<br />

4 days<br />

3 days


Unit 4 (15 days)<br />

Chapter 10 Chemical Quantities<br />

10.1 The Mole: A Measurement of Matter 10.3 % Composition & Chem. Formulas<br />

10.2 Mole-Mass and Mole-Volume Relationships<br />

Chapter 11 Chemical Reactions<br />

11.1 Describing Chemical Reactions 11.3 Reactions in Aqueous Solutions<br />

11.2 Types of Chemical Reactions<br />

Chapter 12 Stoichiometry<br />

12.1 The Arithmetic of Equations 12.3 Limiting Reagent and % Yield<br />

12.2 Chemical Calculations<br />

Unit 5 (15 days)<br />

Chapter 13 States of Matter<br />

13.1 The Nature of Gases 13.3 The Nature of Solids<br />

13.2 The Nature of Liquids 13.4 Changes in State<br />

Chapter 14 The Behavior of Gases<br />

14.1 Properties of Gases 14.3 Ideal Gases<br />

14.2 The Gas Laws 14.4 Gases: Mixtures and Movement<br />

Chapter 15 Water and Aqueous Systems<br />

15.1 Water and its Properties 15.3 Heterogeneous Aqueous Systems<br />

15.2 Homogeneous Aqueous Systems<br />

Unit 6 (10 days)<br />

Chapter 16 Solutions<br />

16.1 Properties of Solutions 16.3 Colligative Properties of Solutions<br />

16.2 Concentrations of Solutions 16.4 Calc. Involving Colligative Property<br />

Chapter 17 Thermochemistry<br />

17.1 The Flow of Energy 17.3 Heat in Changes of State<br />

17.2 Measuring and Expressing Enthalpy Change 17.4 Calculating Heats in Reactions<br />

Chapter 18 Reaction Rates and Equilibrium<br />

18.1 Rates of Reactions 18.3 Reversible Reaction & Equilibrium<br />

18.2 The Progress of Chemical Reactions 18.5 Free Energy and Entropy<br />

Chapter 19 Acid and Bases<br />

19.1 Acid-Base Theories 19.4 Neutralization Reactions<br />

19.2 Hydrogen Ions and Acidity 19.5 Salts in Solutions<br />

19.3 Strengths of Acids and Bases<br />

5 days<br />

5 days<br />

5 days<br />

4 days<br />

5 days<br />

3 days<br />

4 days<br />

2 days<br />

2 days<br />

2 days


Lorenzo Walker Technical High School<br />

MUSTANG LABORATORIES<br />

<strong>Chemistry</strong> Safety<br />

Safety in the MUSTANG LABORATORIES - <strong>Chemistry</strong> Laboratory<br />

Working in the chemistry laboratory is an interesting and rewarding experience. During your labs, you will be actively<br />

involved from beginning to end—from setting some change in motion to drawing some conclusion. In the laboratory, you will<br />

be working with equipment and materials that can cause injury if they are not handled properly.<br />

However, the laboratory is a safe place to work if you are careful. Accidents do not just happen; they are caused—by<br />

carelessness, haste, and disregard of safety rules and practices. Safety rules to be followed in the laboratory are listed<br />

below. Before beginning any lab work, read these rules, learn them, and follow them carefully.<br />

General<br />

1. Be prepared to work when you arrive at the lab. Familiarize yourself with the lab procedures before beginning the lab.<br />

2. Perform only those lab activities assigned by your teacher. Never do anything in the laboratory that is not called for in<br />

the laboratory procedure or by your teacher. Never work alone in the lab. Do not engage in any horseplay.<br />

3. Work areas should be kept clean and tidy at all times. Only lab manuals and notebooks should be brought to the work<br />

area. Other books, purses, brief cases, etc. should be left at your desk or placed in a designated storage area.<br />

4. Clothing should be appropriate for working in the lab. Jackets, ties, and other loose garments should be removed. Open<br />

shoes should not be worn.<br />

5. Long hair should be tied back or covered, especially in the vicinity of open flame.<br />

6. Jewelry that might present a safety hazard, such as dangling necklaces, chains, medallions, or bracelets should not be<br />

worn in the lab.<br />

7. Follow all instructions, both written and oral, carefully.<br />

8. Safety goggles and lab aprons should be worn at all times.<br />

9. Set up apparatus as described in the lab manual or by your teacher. Never use makeshift arrangements.<br />

10. Always use the prescribed instrument (tongs, test tube holder, forceps, etc.) for handling apparatus or equipment.<br />

11. Keep all combustible materials away from open flames.<br />

12. Never touch any substance in the lab unless specifically instructed to do so by your teacher.<br />

13. Never put your face near the mouth of a container that is holding chemicals.<br />

14. Never smell any chemicals unless instructed to do so by your teacher. When testing for odors, use a wafting motion to<br />

direct the odors to your nose.<br />

15. Any activity involving poisonous vapors should be conducted in the fume hood.<br />

16. Dispose of waste materials as instructed by your teacher.<br />

17. Clean up all spills immediately.<br />

18. Clean and wipe dry all work surfaces at the end of class. Wash your hands thoroughly.<br />

19. Know the location of emergency equipment (first aid kit, fire extinguisher, fire shower, fire blanket, etc.) and how to use them.<br />

20. Report all accidents to the teacher immediately.<br />

Handling Chemicals<br />

21. Read and double check labels on reagent bottles before removing any reagent. Take only as much reagent as you need.<br />

22. Do not return unused reagent to stock bottles.<br />

23. When transferring chemical reagents from one container to another, hold the containers out away from your body.<br />

24. When mixing an acid and water, always add the acid to the water.<br />

25. Avoid touching chemicals with your hands. If chemicals do come in contact with your hands, wash them immediately.<br />

26. Notify your teacher if you have any medical problems that might relate to lab work, such as allergies or asthma.<br />

27. If you will be working with chemicals in the lab, avoid wearing contact lenses. Change to glasses, if possible, or notify<br />

the teacher.<br />

Handling Glassware<br />

28. Glass tubing, especially long pieces, should be carried in a vertical position to minimize the likelihood of breakage and<br />

to avoid stabbing anyone.


29. Never handle broken glass with your bare hands. Use a brush and dustpan to clean up broken glass. Dispose of the<br />

glass as directed by your teacher.<br />

30. Always lubricate glassware (tubing, thistle tubes, thermometers, etc.) with water or glycerin before attempting to insert it into a<br />

rubber stopper.<br />

31. Never apply force when inserting or removing glassware from a stopper. Use a twisting motion. If a piece of glassware<br />

becomes "frozen" in a stopper, take it to your teacher.<br />

32. Do not place hot glassware directly on the lab table. Always use an insulating pad of some sort.<br />

33. Allow plenty of time for hot glass to cool before touching it. Hot glass can cause painful burns. (Hot glass looks cool.)<br />

Heating Substances<br />

34. Exercise extreme caution when using a gas burner. Keep your head and clothing away from the flame.<br />

35. Always turn the burner off when it is not in use.<br />

36. Do not bring any substance into contact with a flame unless instructed to do so.<br />

37. Never heat anything without being instructed to do so.<br />

38. Never look into a container that is being heated.<br />

39. When heating a substance in a test tube, make sure that the mouth of the tube is not pointed at yourself or anyone else.<br />

40. Never leave unattended anything that is being heated or is visibly reacting.<br />

First Aid in the MUSTANG LABORATORIES - <strong>Chemistry</strong> Laboratory<br />

Accidents do not often happen in well-equipped chemistry laboratories if students understand safe laboratory procedures<br />

and are careful in following them. When an occasional accident does occur, it is likely to be a minor one.<br />

The instructor will assist in treating injuries such as minor cuts and burns. However, for some types of injuries, you must take<br />

action immediately. The following information will be helpful to you if an accident occurs.<br />

1. Shock. People who are suffering from any severe injury (for example, a bad burn or major loss of blood) may be in a state<br />

of shock. A person in shock is usually pale and faint. The person may be sweating, with cold, moist skin and a weak, rapid<br />

pulse. Shock is a serious medical condition. Do not allow a person in shock to walk anywhere—even to the campus security<br />

office. While emergency help is being summoned, place the victim face up in a horizontal position, with the feet raised about<br />

30 centimeters. Loosen any tightly fitting clothing and keep him or her warm.<br />

2. Chemicals in the Eyes. Getting any kind of a chemical into the eyes is undesirable, but certain chemicals are especially<br />

harmful. They can destroy eyesight in a matter of seconds. Because you will be wearing safety goggles at all times in the lab,<br />

the likelihood of this kind of accident is remote. However, if it does happen, flush your eyes with water immediately. Do NOT<br />

attempt to go to the campus office before flushing your eyes. It is important that flushing with water be continued for a<br />

prolonged time—about 15 minutes.<br />

3. Clothing or Hair on Fire. A person whose clothing or hair catches on fire will often run around hysterically in an<br />

unsuccessful effort to get away from the fire. This only provides the fire with more oxygen and makes it burn faster. For<br />

clothing fires, throw yourself to the ground and roll around to extinguish the flames. For hair fires, use a fire blanket to<br />

smother the flames. Notify campus security immediately.<br />

4. Bleeding from a Cut. Most cuts that occur in the chemistry laboratory are minor. For minor cuts, apply pressure to the<br />

wound with a sterile gauze. Notify campus security of all injuries in the lab. If the victim is bleeding badly, raise the bleeding<br />

part, if possible, and apply pressure to the wound with a piece of sterile gauze. While first aid is being given, someone else<br />

should notify the campus security officer.<br />

5. Chemicals in the Mouth. Many chemicals are poisonous to varying degrees. Any chemical taken into the mouth should be<br />

spat out and the mouth rinsed thoroughly with water. Note the name of the chemical and notify the campus office<br />

immediately. If the victim swallows a chemical, note the name of the chemical and notify campus security immediately.<br />

If necessary, the campus security officer or administrator will contact the Poison Control Center, a hospital emergency room,<br />

or a physician for instructions.<br />

6. Acid or Base Spilled on the Skin.<br />

Flush the skin with water for about 15 minutes. Take the victim to the campus office to report the injury.<br />

7. Breathing Smoke or Chemical Fumes.<br />

All experiments that give off smoke or noxious gases should be conducted in a well-ventilated fume hood. This will make an<br />

accident of this kind unlikely. If smoke or chemical fumes are present in the laboratory, all persons—even those who do not<br />

feel ill—should leave the laboratory immediately. Make certain that all doors to the laboratory are closed after the last<br />

person has left. Since smoke rises, stay low while evacuating a smoke-filled room. Notify campus security immediately.


MUSTANG LABORATORIES<br />

COMMITMENT TO SAFETY IN THE LABORATORY<br />

As a student enrolled in <strong>Chemistry</strong> at Lorenzo Walker Technical High School, I agree to use<br />

good laboratory safety practices at all times. I also agree that I will:<br />

1. Conduct myself in a professional manner, respecting both my personal safety and the safety of others in the laboratory.<br />

2. Wear proper and approved safety glasses or goggles in the laboratory at all times.<br />

3. Wear sensible clothing and tie back long hair in the laboratory. Understand that open-toed shoes pose a hazard during<br />

laboratory classes and that contact lenses are an added safety risk.<br />

4. Keep my lab area free of clutter during an experiment.<br />

5. Never bring food or drink into the laboratory, nor apply makeup within the laboratory.<br />

6. Be aware of the location of safety equipment such as the fire extinguisher, eye wash station, fire blanket, first aid kit.<br />

Know the location of the nearest telephone and exits.<br />

7. Read the assigned lab prior to coming to the laboratory.<br />

8. Carefully read all labels on all chemical containers before using their contents, remove a small amount of reagent<br />

properly if needed, do not pour back the unused chemicals into the original container.<br />

9. Dispose of chemicals as directed by the instructor only. At no time will I pour anything down the sink without prior<br />

instruction.<br />

10. Never inhale fumes emitted during an experiment. Use the fume hood when instructed to do so.<br />

11. Report any accident immediately to the instructor, including chemical spills.<br />

12. Dispose of broken glass and sharps only in the designated containers.<br />

13. Clean my work area and all glassware before leaving the laboratory.<br />

14. Wash my hands before leaving the laboratory.<br />

NAME ____________________________<br />

Josh Hoppe<br />

PARENT NAME _______________________________________<br />

Linda Hoppe<br />

BLOCK ____________________________<br />

3 PARENT NUMBER _____________________________________<br />

(239) 537-2550<br />

SIGNATURE _________________________________________________<br />

8/20/13<br />

DATE ____________________________________


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C<br />

THE UNIVERSITY OF THE STATE OF NEW YORK• THE STATE EDUCATION DEPARTMENT• ALBANY, NY 12234<br />

Reference Tables for Physical Setting/CHEMISTRY<br />

Table A<br />

Standard Temperature and Pressure<br />

2011 Edition<br />

Table D<br />

Selected Units<br />

Name Value Unit<br />

Standard Pressure 101.3 kPa kilopascal<br />

1 atm atmosphere<br />

Standard Temperature 273 K kelvin<br />

0°C degree Celsius<br />

Table B<br />

Physical Constants for Water<br />

Heat of Fusion<br />

Heat of Vaporization<br />

Specific Heat Capacity of H 2<br />

O()<br />

Table C<br />

Selected Prefixes<br />

Factor Prefix Symbol<br />

10 3 kilo- k<br />

10 –1 deci- d<br />

10 –2 centi- c<br />

10 –3 milli- m<br />

10 –6 micro- μ<br />

10 –9 nano- n<br />

10 –12 pico- p<br />

334 J/g<br />

2260 J/g<br />

4.18 J/g•K<br />

Symbol Name Quantity<br />

m meter length<br />

g gram mass<br />

Pa pascal pressure<br />

K kelvin temperature<br />

mol<br />

J<br />

mole<br />

joule<br />

s second time<br />

min minute time<br />

h hour time<br />

d day time<br />

y year time<br />

amount of<br />

substance<br />

L liter volume<br />

energy, work,<br />

quantity of heat<br />

ppm parts per million concentration<br />

M<br />

molarity<br />

solution<br />

concentration<br />

u atomic mass unit atomic mass<br />

Reference Tables for Physical Setting/<strong>Chemistry</strong> – 2011 Edition 1


Table E<br />

Selected Polyatomic Ions<br />

Formula Name Formula Name<br />

H 3<br />

O +<br />

hydronium<br />

CrO 4<br />

2–<br />

chromate<br />

Hg 2<br />

2+<br />

mercury(I)<br />

Cr 2<br />

O 7<br />

2–<br />

dichromate<br />

NH 4<br />

+<br />

C 2<br />

H 3<br />

O<br />

–<br />

2 –}<br />

CH 3<br />

COO<br />

CN –<br />

CO 3<br />

2–<br />

HCO<br />

–<br />

3<br />

C 2<br />

O<br />

2–<br />

4<br />

ClO –<br />

ammonium<br />

acetate<br />

cyanide<br />

carbonate<br />

hydrogen<br />

carbonate<br />

oxalate<br />

hypochlorite<br />

MnO 4<br />

–<br />

NO<br />

–<br />

2<br />

NO<br />

–<br />

3<br />

O<br />

2–<br />

2<br />

OH –<br />

PO 4<br />

3–<br />

SCN –<br />

SO 3<br />

2–<br />

permanganate<br />

nitrite<br />

nitrate<br />

peroxide<br />

hydroxide<br />

phosphate<br />

thiocyanate<br />

sulfite<br />

ClO 2<br />

–<br />

chlorite<br />

SO 4<br />

2–<br />

sulfate<br />

ClO 3<br />

–<br />

chlorate<br />

HSO 4<br />

–<br />

hydrogen sulfate<br />

ClO 4<br />

–<br />

perchlorate<br />

S 2<br />

O 3<br />

2–<br />

thiosulfate<br />

Table F<br />

Solubility Guidelines for Aqueous Solutions<br />

Ions That Form<br />

Soluble Compounds<br />

Group 1 ions<br />

(Li + , Na + , etc.)<br />

ammonium (NH + 4<br />

)<br />

nitrate (NO – 3<br />

)<br />

acetate (C 2<br />

H 3<br />

O – 2<br />

or<br />

CH 3<br />

COO – )<br />

hydrogen carbonate<br />

(HCO – 3<br />

)<br />

chlorate (ClO – 3<br />

)<br />

halides (Cl – , Br – , I – )<br />

Exceptions<br />

when combined with<br />

Ag + , Pb 2+ , or Hg 2<br />

2+<br />

sulfates (SO 4 2– ) when combined with Ag + ,<br />

Ca 2+ , Sr 2+ , Ba 2+ , or Pb 2+<br />

Ions That Form<br />

Insoluble Compounds* Exceptions<br />

carbonate (CO 2– 3<br />

) when combined with Group 1<br />

ions or ammonium (NH + 4<br />

)<br />

chromate (CrO 2– 4<br />

) when combined with Group 1<br />

ions, Ca 2+ , Mg 2+ , or<br />

ammonium (NH + 4<br />

)<br />

phosphate (PO 3– 4<br />

) when combined with Group 1<br />

ions or ammonium (NH + 4<br />

)<br />

sulfide (S 2– ) when combined with Group 1<br />

ions or ammonium (NH + 4<br />

)<br />

hydroxide (OH – ) when combined with Group 1<br />

ions, Ca 2+ , Ba 2+ , Sr 2+ , or<br />

ammonium (NH + 4<br />

)<br />

*compounds having very low solubility in H 2 O<br />

Reference Tables for Physical Setting/<strong>Chemistry</strong> – 2011 Edition 2


150.<br />

140.<br />

Table G<br />

Solubility Curves at Standard Pressure<br />

KI<br />

NaNO 3<br />

130.<br />

120.<br />

KNO 3<br />

110.<br />

100.<br />

Solubility (g solute/100. g H 2<br />

O)<br />

90.<br />

80.<br />

70.<br />

60.<br />

HCl<br />

NH 4<br />

Cl<br />

KCl<br />

50.<br />

40.<br />

30.<br />

NaCl<br />

KClO 3<br />

NH 3<br />

20.<br />

10.<br />

SO 2<br />

0<br />

0 10. 20. 30. 40. 50. 60. 70. 80. 90. 100.<br />

Temperature (°C)<br />

Reference Tables for Physical Setting/<strong>Chemistry</strong> – 2011 Edition 3


Table H<br />

Vapor Pressure of Four Liquids<br />

200.<br />

propanone<br />

ethanol<br />

150.<br />

water<br />

Vapor Pressure (kPa)<br />

100.<br />

101.3 kPa<br />

ethanoic<br />

acid<br />

50.<br />

0<br />

0 25 50. 75 100. 125<br />

Reference Tables for Physical Setting/<strong>Chemistry</strong> – 2011 Edition 4


Table I<br />

Heats of Reaction at 101.3 kPa and 298 K<br />

Reaction<br />

ΔH (kJ)*<br />

CH 4<br />

(g) + 2O 2<br />

(g) CO 2<br />

(g) + 2H 2<br />

O() –890.4<br />

C 3<br />

H 8<br />

(g) + 5O 2<br />

(g) 3CO 2<br />

(g) + 4H 2<br />

O() –2219.2<br />

2C 8<br />

H 18<br />

() + 25O 2<br />

(g) 16CO 2<br />

(g) + 18H 2<br />

O() –10943<br />

2CH 3<br />

OH() + 3O 2<br />

(g) 2CO 2<br />

(g) + 4H 2<br />

O() –1452<br />

C 2<br />

H 5<br />

OH() + 3O 2<br />

(g) 2CO 2<br />

(g) + 3H 2<br />

O() –1367<br />

C 6<br />

H 12<br />

O 6<br />

(s) + 6O 2<br />

(g) 6CO 2<br />

(g) + 6H 2<br />

O() –2804<br />

2CO(g) + O 2<br />

(g) 2CO 2<br />

(g) –566.0<br />

C(s) + O 2<br />

(g) CO 2<br />

(g) –393.5<br />

4Al(s) + 3O 2<br />

(g) 2Al 2<br />

O 3<br />

(s) –3351<br />

N 2<br />

(g) + O 2<br />

(g) 2NO(g) +182.6<br />

N 2<br />

(g) + 2O 2<br />

(g) 2NO 2<br />

(g) +66.4<br />

2H 2<br />

(g) + O 2<br />

(g) 2H 2<br />

O(g) –483.6<br />

2H 2<br />

(g) + O 2<br />

(g) 2H 2<br />

O() –571.6<br />

N 2<br />

(g) + 3H 2<br />

(g) 2NH 3<br />

(g) –91.8<br />

2C(s) + 3H 2<br />

(g) C 2<br />

H 6<br />

(g) –84.0<br />

2C(s) + 2H 2<br />

(g) C 2<br />

H 4<br />

(g) +52.4<br />

2C(s) + H 2<br />

(g) C 2<br />

H 2<br />

(g) +227.4<br />

H 2<br />

(g) + I 2<br />

(g) 2HI(g) +53.0<br />

KNO 3<br />

(s) H 2 O K + (aq) + NO 3 – (aq) +34.89<br />

NaOH(s) H 2 O Na + (aq) + OH – (aq) –44.51<br />

NH 4<br />

Cl(s) H 2 O NH 4 + (aq) + Cl – (aq) +14.78<br />

NH 4<br />

NO 3<br />

(s) H 2 O NH 4 + (aq) + NO 3 – (aq) +25.69<br />

NaCl(s) H 2 O Na + (aq) + Cl – (aq) +3.88<br />

LiBr(s) H 2 O Li + (aq) + Br – (aq) –48.83<br />

H + (aq) + OH – (aq) H 2<br />

O() –55.8<br />

*The ΔH values are based on molar quantities represented in the equations.<br />

A minus sign indicates an exothermic reaction.<br />

Most<br />

Active<br />

Least<br />

Active<br />

Table J<br />

Activity Series**<br />

Metals Nonmetals Most<br />

Active<br />

Li<br />

F 2<br />

Rb Cl 2<br />

K Br 2<br />

Cs<br />

I 2<br />

Ba<br />

Sr<br />

Ca<br />

Na<br />

Mg<br />

Al<br />

Ti<br />

Mn<br />

Zn<br />

Cr<br />

Fe<br />

Co<br />

Ni<br />

Sn<br />

Pb<br />

H 2<br />

Cu<br />

Ag<br />

Au<br />

**Activity Series is based on the hydrogen<br />

standard. H 2 is not a metal.<br />

Least<br />

Active<br />

Reference Tables for Physical Setting/<strong>Chemistry</strong> – 2011 Edition 5


Table K<br />

Common Acids<br />

Table N<br />

Selected Radioisotopes<br />

HCl(aq)<br />

Formula<br />

HNO 2<br />

(aq)<br />

HNO 3<br />

(aq)<br />

H 2<br />

SO 3<br />

(aq)<br />

H 2<br />

SO 4<br />

(aq)<br />

H 3<br />

PO 4<br />

(aq)<br />

H 2<br />

CO 3<br />

(aq)<br />

or<br />

CO 2<br />

(aq)<br />

CH 3<br />

COOH(aq)<br />

or<br />

HC 2<br />

H 3<br />

O 2<br />

(aq)<br />

Name<br />

hydrochloric acid<br />

nitrous acid<br />

nitric acid<br />

sulfurous acid<br />

sulfuric acid<br />

phosphoric acid<br />

carbonic acid<br />

ethanoic acid<br />

(acetic acid)<br />

Nuclide Half-Life Decay<br />

Mode<br />

Nuclide<br />

Name<br />

198 Au 2.695 d β – gold-198<br />

14 C 5715 y β – carbon-14<br />

37 Ca 182 ms β + calcium-37<br />

60 Co 5.271 y β – cobalt-60<br />

137 Cs 30.2 y β – cesium-137<br />

53 Fe 8.51 min β + iron-53<br />

220 Fr 27.4 s α francium-220<br />

3 H 12.31 y β – hydrogen-3<br />

131 I 8.021 d β – iodine-131<br />

37 K 1.23 s β + potassium-37<br />

42 K 12.36 h β – potassium-42<br />

Table L<br />

Common Bases<br />

85 Kr 10.73 y β – krypton-85<br />

16 N 7.13 s β – nitrogen-16<br />

Formula<br />

NaOH(aq)<br />

KOH(aq)<br />

Ca(OH) 2<br />

(aq)<br />

NH 3<br />

(aq)<br />

Name<br />

sodium hydroxide<br />

potassium hydroxide<br />

calcium hydroxide<br />

aqueous ammonia<br />

19 Ne 17.22 s β + neon-19<br />

32 P 14.28 d β – phosphorus-32<br />

239 Pu 2.410 × 10 4 y α plutonium-239<br />

226 Ra 1599 y α radium-226<br />

222 Rn 3.823 d α radon-222<br />

90 Sr 29.1 y β – strontium-90<br />

Table M<br />

Common Acid–Base Indicators<br />

Approximate<br />

Indicator pH Range Color<br />

for Color Change<br />

Change<br />

methyl orange 3.1–4.4 red to yellow<br />

bromthymol blue 6.0–7.6 yellow to blue<br />

phenolphthalein 8–9 colorless to pink<br />

litmus 4.5–8.3 red to blue<br />

bromcresol green 3.8–5.4 yellow to blue<br />

thymol blue 8.0–9.6 yellow to blue<br />

99 Tc 2.13 × 10 5 y β – technetium-99<br />

232 Th 1.40 × 10 10 y α thorium-232<br />

233 U 1.592 × 10 5 y α uranium-233<br />

235 U 7.04 × 10 8 y α uranium-235<br />

238 U 4.47 × 10 9 y α uranium-238<br />

Source: CRC Handbook of <strong>Chemistry</strong> and Physics, 91 st ed., 2010–2011,<br />

CRC Press<br />

Source: The Merck Index, 14 th ed., 2006, Merck Publishing Group<br />

Reference Tables for Physical Setting/<strong>Chemistry</strong> – 2011 Edition 6


Table O<br />

Symbols Used in Nuclear <strong>Chemistry</strong><br />

Name Notation Symbol<br />

alpha particle<br />

4<br />

2<br />

He or 4 2 α α<br />

beta particle<br />

0<br />

–1<br />

e or 0<br />

–1 β β–<br />

gamma radiation<br />

0<br />

0<br />

γ γ<br />

neutron<br />

1<br />

0<br />

n n<br />

proton<br />

1<br />

1<br />

H or 1 1 p p<br />

positron<br />

0<br />

+1<br />

e or 0<br />

+1 β β+<br />

Name General Examples<br />

Formula Name Structural Formula<br />

alkanes C n<br />

H 2n+2<br />

ethane<br />

alkenes C n<br />

H 2n<br />

ethene<br />

alkynes C n<br />

H 2n–2<br />

ethyne<br />

Table P<br />

Organic Prefixes<br />

Prefix<br />

meth- 1<br />

eth- 2<br />

prop- 3<br />

but- 4<br />

pent- 5<br />

hex- 6<br />

hept- 7<br />

oct- 8<br />

Number of<br />

Carbon Atoms<br />

non- 9<br />

dec- 10<br />

Table Q<br />

Homologous Series of Hydrocarbons<br />

Note: n = number of carbon atoms<br />

Reference Tables for Physical Setting/<strong>Chemistry</strong> – 2011 Edition 7<br />

H<br />

H<br />

H<br />

H<br />

H<br />

C<br />

H<br />

C<br />

H<br />

C<br />

H<br />

C<br />

H<br />

H<br />

H<br />

C C H


Table R<br />

Organic Functional Groups<br />

Class of<br />

Compound<br />

Functional<br />

Group<br />

General<br />

Formula<br />

Example<br />

halide<br />

(halocarbon)<br />

F (fluoro-)<br />

Cl (chloro-)<br />

Br (bromo-)<br />

I (iodo-)<br />

R X<br />

(X represents<br />

any halogen)<br />

CH 3<br />

CHClCH 3<br />

2-chloropropane<br />

alcohol<br />

OH<br />

R<br />

OH<br />

CH 3<br />

CH 2<br />

CH 2<br />

OH<br />

1-propanol<br />

ether<br />

O<br />

R O R′<br />

CH 3<br />

OCH 2<br />

CH 3<br />

methyl ethyl ether<br />

aldehyde<br />

O<br />

C H<br />

R<br />

O<br />

C H<br />

O<br />

CH 3<br />

CH 2<br />

C H<br />

propanal<br />

ketone<br />

O<br />

C<br />

O<br />

R C R′<br />

O<br />

CH 3<br />

CCH 2<br />

CH 2<br />

CH 3<br />

2-pentanone<br />

organic acid<br />

O<br />

C OH<br />

R<br />

O<br />

C OH<br />

O<br />

CH 3<br />

CH 2<br />

C OH<br />

propanoic acid<br />

ester<br />

O<br />

C O<br />

O<br />

R C O R′<br />

O<br />

CH 3<br />

CH 2<br />

COCH 3<br />

methyl propanoate<br />

amine<br />

N<br />

R<br />

R′<br />

N R′′<br />

CH 3<br />

CH 2<br />

CH 2<br />

NH 2<br />

1-propanamine<br />

amide<br />

O<br />

C NH<br />

R<br />

O R′<br />

C NH<br />

O<br />

CH 3<br />

CH 2<br />

C NH 2<br />

propanamide<br />

Note: R represents a bonded atom or group of atoms.<br />

Reference Tables for Physical Setting/<strong>Chemistry</strong> – 2011 Edition 8


0<br />

6.941<br />

+1<br />

Li<br />

3<br />

2-1<br />

Na<br />

39.0983<br />

K +1<br />

19<br />

2-8-8-1<br />

Rb<br />

Cs<br />

(223)<br />

Fr<br />

87<br />

-18-32-18-8-1<br />

+1<br />

Ra<br />

88<br />

-18-32-18-8-2<br />

39<br />

138.9055<br />

La<br />

57<br />

2-8-18-18-9-2<br />

+2 (227)<br />

Ac<br />

89<br />

-18-32-18-9-2<br />

47.867<br />

Ti<br />

22<br />

2-8-10-2<br />

91.224<br />

Zr<br />

40<br />

2-8-18-10-2<br />

+3 178.49<br />

Hf<br />

72<br />

*18-32-10-2<br />

+3 (261)<br />

Rf<br />

104<br />

+2<br />

+3<br />

+4<br />

+4<br />

+4<br />

50.9415<br />

V<br />

23<br />

2-8-11-2<br />

+2<br />

+3<br />

+4<br />

+5<br />

51.996<br />

Cr<br />

24<br />

2-8-13-1<br />

95.94<br />

Mo<br />

42<br />

2-8-18-13-1<br />

183.84<br />

W<br />

74<br />

-18-32-12-2<br />

+2<br />

+3<br />

+6<br />

+6<br />

+6<br />

54.9380<br />

Mn<br />

25<br />

2-8-13-2<br />

+2<br />

+3<br />

+4<br />

+7<br />

55.845<br />

Fe<br />

26<br />

2-8-14-2<br />

+2<br />

+3 58.9332<br />

Co<br />

27<br />

2-8-15-2<br />

+2<br />

+3<br />

58.693<br />

Ni<br />

28<br />

2-8-16-2<br />

+2<br />

+3 63.546 Cu<br />

2-8-18-1<br />

107.868<br />

Ag<br />

47<br />

2-8-18-18-1<br />

79<br />

+1<br />

+2<br />

+1<br />

65.409<br />

Zn<br />

30<br />

2-8-18-2<br />

+3 12.011<br />

B<br />

5<br />

2-3<br />

26.98154<br />

Al<br />

13<br />

2-8-3<br />

+2 69.723<br />

Ga<br />

31<br />

2-8-18-3<br />

+3<br />

+3<br />

–4<br />

+2<br />

+4<br />

C<br />

6<br />

2-4<br />

28.0855<br />

Si<br />

14<br />

2-8-4<br />

72.64<br />

Ge<br />

32<br />

2-8-18-4<br />

Pb<br />

–4<br />

+2<br />

+4<br />

+2<br />

+4<br />

74.9216<br />

As<br />

33<br />

2-8-18-5<br />

Sb<br />

–3<br />

+3<br />

15.9994<br />

O<br />

F<br />

8<br />

2-6<br />

–2 18.9984<br />

78.96<br />

Se<br />

34<br />

2-8-18-6<br />

127.60<br />

Te<br />

52<br />

2-8-18-18-6<br />

(209)<br />

Po<br />

84<br />

-18-32-18-6<br />

–2<br />

+4<br />

+6<br />

–2<br />

+4<br />

+6<br />

+2<br />

+4<br />

2-7<br />

79.904<br />

Br<br />

35<br />

2-8-18-7<br />

126.904<br />

l<br />

53<br />

2-8-18-18-7<br />

(210)<br />

At<br />

85<br />

-18-32-18-7<br />

4.00260 0<br />

He<br />

2<br />

2<br />

–1 20.180<br />

Ne<br />

10<br />

2-8<br />

0<br />

22.98977<br />

11<br />

2-8-1<br />

1<br />

1.00794 +1<br />

–1<br />

H<br />

1<br />

1<br />

1<br />

85.4678<br />

37<br />

2-8-18-8-1<br />

30.97376<br />

P<br />

15<br />

2-8-5<br />

–3<br />

+3<br />

+5<br />

32.065<br />

S<br />

16<br />

2-8-6<br />

–2<br />

+4<br />

+6<br />

–1<br />

+1<br />

+5<br />

–1<br />

+1<br />

+5<br />

+7<br />

39.948<br />

Ar<br />

18<br />

2-8-8<br />

83.798<br />

Kr<br />

36<br />

2-8-18-8<br />

131.29<br />

Xe<br />

54<br />

2-8-18-18-8<br />

(222)<br />

Rn<br />

86<br />

-18-32-18-8<br />

0<br />

+2<br />

0<br />

+2<br />

+4<br />

+6<br />

0<br />

132.905<br />

55<br />

2-8-18-18-8-1<br />

Symbol<br />

Relative atomic masses are based<br />

Group on 12 C = 12 (exact)<br />

Group<br />

2<br />

13 14 15 16 17 18<br />

Atomic Number<br />

Note: Numbers in parentheses<br />

10.81<br />

are mass numbers of the most<br />

Electron Configuration<br />

stable or common isotope.<br />

+1<br />

+1<br />

+1<br />

9.01218 +2<br />

Be<br />

4<br />

2-2<br />

24.305<br />

Mg<br />

12<br />

2-8-2<br />

40.08<br />

Ca<br />

20<br />

2-8-8-2<br />

87.62<br />

Sr<br />

38<br />

2-8-18-8-2<br />

137.33<br />

Ba<br />

56<br />

2-8-18-18-8-2<br />

(226)<br />

+2<br />

+2<br />

+2<br />

+2<br />

3<br />

44.9559<br />

Sc<br />

21<br />

2-8-9-2<br />

88.9059<br />

Y<br />

2-8-18-9-2<br />

+3<br />

+3<br />

4<br />

KEY<br />

+4<br />

92.9064<br />

Nb +3<br />

+5<br />

41<br />

2-8-18-12-1<br />

180.948<br />

Ta<br />

73<br />

-18-32-11-2<br />

(262)<br />

105<br />

5<br />

Periodic Table of the Elements<br />

Atomic Mass<br />

Db<br />

+5<br />

6<br />

(266)<br />

Sg<br />

106<br />

12.011 2-4<br />

–4<br />

6<br />

C<br />

+2<br />

+4<br />

(98)<br />

Tc<br />

43<br />

2-8-18-13-2<br />

186.207<br />

Re<br />

75<br />

-18-32-13-2<br />

(272)<br />

Bh<br />

107<br />

7<br />

Group<br />

+4<br />

+6<br />

+7<br />

+4<br />

+6<br />

+7<br />

8<br />

101.07<br />

Ru<br />

44<br />

2-8-18-15-1<br />

190.23<br />

Os<br />

76<br />

-18-32-14-2<br />

(277)<br />

Hs<br />

108<br />

+3<br />

+3<br />

+4<br />

Selected Oxidation States<br />

9<br />

102.906<br />

Rh<br />

45<br />

2-8-18-16-1<br />

192.217<br />

Ir<br />

77<br />

-18-32-15-2<br />

(276)<br />

Mt<br />

109<br />

+3<br />

+3<br />

+4<br />

106.42<br />

Pd<br />

46<br />

2-8-18-18<br />

195.08<br />

Pt<br />

78<br />

-18-32-17-1<br />

+2<br />

+4<br />

+2<br />

+4<br />

196.967<br />

Au<br />

-18-32-18-1<br />

(281)<br />

Ds (280) Rg<br />

110<br />

10<br />

29<br />

111<br />

11 12<br />

+1<br />

+3<br />

112.41<br />

Cd<br />

48<br />

2-8-18-18-2<br />

200.59<br />

Hg<br />

80<br />

-18-32-18-2<br />

(285)<br />

Cn<br />

112<br />

+2 114.818<br />

In<br />

+1<br />

+2<br />

49<br />

2-8-18-18-3<br />

204.383<br />

Tl<br />

81<br />

-18-32-18-3<br />

(284)<br />

Uut<br />

113**<br />

+3<br />

+1<br />

+3<br />

118.71<br />

Sn<br />

50<br />

2-8-18-18-4<br />

207.2<br />

82<br />

-18-32-18-4<br />

(289)<br />

Uuq<br />

114<br />

+2<br />

+4<br />

+2<br />

+4<br />

14.0067 –3<br />

–2<br />

N<br />

–1<br />

7<br />

2-5<br />

121.760<br />

51<br />

2-8-18-18-5<br />

208.980<br />

Bi<br />

83<br />

-18-32-18-5<br />

(288)<br />

Uup<br />

115<br />

+1<br />

+2<br />

+3<br />

+4<br />

+5<br />

+5<br />

–3<br />

+3<br />

+5<br />

+3<br />

+5<br />

(292)<br />

Uuh<br />

116<br />

35.453<br />

Cl<br />

17<br />

2-8-7<br />

( ? )<br />

Uus<br />

117<br />

–1<br />

+1<br />

+5<br />

+7<br />

18<br />

(294)<br />

Uuo<br />

118<br />

140.116<br />

Ce<br />

58<br />

232.038<br />

Th<br />

90<br />

+3<br />

+4<br />

140.908<br />

Pr +3<br />

59<br />

144.24<br />

Nd<br />

60<br />

+4 231.036<br />

Pa +4 238.029 +5<br />

U +3<br />

+4<br />

+5<br />

+6<br />

91<br />

92<br />

+3<br />

(145)<br />

Pm<br />

61<br />

+3<br />

150.36<br />

Sm<br />

62<br />

+2<br />

+3<br />

151.964<br />

Eu<br />

63<br />

+2<br />

+3<br />

157.25<br />

Gd<br />

64<br />

+3<br />

158.925<br />

(237)Np (244) Pu (243) Am (247) Cm +3 (247) Bk +3<br />

+3<br />

+4<br />

+5<br />

+6<br />

93 94<br />

+3<br />

+4<br />

+5<br />

+6<br />

65<br />

+3<br />

+4<br />

+5<br />

+6<br />

95 96 97<br />

Tb<br />

+3<br />

+4<br />

162.500<br />

Dy<br />

66<br />

(251)<br />

+3<br />

164.930<br />

Ho<br />

67<br />

+3<br />

167.259<br />

Er<br />

68<br />

Cf +3 (252) Es (257) Fm<br />

100<br />

98 99<br />

+3<br />

+3<br />

+3<br />

168.934<br />

Tm +3<br />

69<br />

(258)<br />

Md<br />

101<br />

+2<br />

+3<br />

173.04<br />

Yb<br />

70<br />

(259)<br />

No<br />

102<br />

+2<br />

+3<br />

+2<br />

+3<br />

174.9668<br />

Lu<br />

71<br />

(262)<br />

Lr<br />

103<br />

+3<br />

+3<br />

*denotes the presence of (2-8-) for elements 72 and above<br />

**The systematic names and symbols for elements of atomic numbers 113 and above<br />

will be used until the approval of trivial names by IUPAC.<br />

Source: CRC Handbook of <strong>Chemistry</strong> and Physics, 91 st ed., 2010–2011, CRC Press<br />

9<br />

Period<br />

1<br />

2<br />

3<br />

4<br />

5<br />

6<br />

7<br />

Reference Tables for Physical Setting/<strong>Chemistry</strong> – 2011 Edition 9


Table S<br />

Properties of Selected Elements<br />

First<br />

Atomic Symbol Name Ionization<br />

Electro- Melting Boiling* Density** Atomic<br />

Number Energy negativity Point Point (g/cm 3 ) Radius<br />

(kJ/mol) (K) (K) (pm)<br />

1 H hydrogen 1312 2.2 14 20. 0.000082 32<br />

2 He helium 2372 — — 4 0.000164 37<br />

3 Li lithium 520. 1.0 454 1615 0.534 130.<br />

4 Be beryllium 900. 1.6 1560. 2744 1.85 99<br />

5 B boron 801 2.0 2348 4273 2.34 84<br />

6 C carbon 1086 2.6 — — .— 75<br />

7 N nitrogen 1402 3.0 63 77 0.001145 71<br />

8 O oxygen 1314 3.4 54 90. 0.001308 64<br />

9 F fluorine 1681 4.0 53 85 0.001553 60.<br />

10 Ne neon 2081 — 24 27 0.000825 62<br />

11 Na sodium 496 0.9 371 1156 0.97 160.<br />

12 Mg magnesium 738 1.3 923 1363 1.74 140.<br />

13 Al aluminum 578 1.6 933 2792 2.70 124<br />

14 Si silicon 787 1.9 1687 3538 2.3296 114<br />

15 P phosphorus (white) 1012 2.2 317 554 1.823 109<br />

16 S sulfur (monoclinic) 1000. 2.6 388 718 2.00 104<br />

17 Cl chlorine 1251 3.2 172 239 0.002898 100.<br />

18 Ar argon 1521 — 84 87 0.001633 101<br />

19 K potassium 419 0.8 337 1032 0.89 200.<br />

20 Ca calcium 590. 1.0 1115 1757 1.54 174<br />

21 Sc scandium 633 1.4 1814 3109 2.99 159<br />

22 Ti titanium 659 1.5 1941 3560. 4.506 148<br />

23 V vanadium 651 1.6 2183 3680. 6.0 144<br />

24 Cr chromium 653 1.7 2180. 2944 7.15 130.<br />

25 Mn manganese 717 1.6 1519 2334 7.3 129<br />

26 Fe iron 762 1.8 1811 3134 7.87 124<br />

27 Co cobalt 760. 1.9 1768 3200. 8.86 118<br />

28 Ni nickel 737 1.9 1728 3186 8.90 117<br />

29 Cu copper 745 1.9 1358 2835 8.96 122<br />

30 Zn zinc 906 1.7 693 1180. 7.134 120.<br />

31 Ga gallium 579 1.8 303 2477 5.91 123<br />

32 Ge germanium 762 2.0 1211 3106 5.3234 120.<br />

33 As arsenic (gray) 944 2.2 1090. — 5.75 120.<br />

34 Se selenium (gray) 941 2.6 494 958 4.809 118<br />

35 Br bromine 1140. 3.0 266 332 3.1028 117<br />

36 Kr krypton 1351 — 116 120. 0.003425 116<br />

37 Rb rubidium 403 0.8 312 961 1.53 215<br />

38 Sr strontium 549 1.0 1050. 1655 2.64 190.<br />

39 Y yttrium 600. 1.2 1795 3618 4.47 176<br />

40 Zr zirconium 640. 1.3 2128 4682 6.52 164<br />

Reference Tables for Physical Setting/<strong>Chemistry</strong> – 2011 Edition 10


First<br />

Atomic Symbol Name Ionization<br />

Electro- Melting Boiling* Density** Atomic<br />

Number Energy negativity Point Point (g/cm 3 ) Radius<br />

(kJ/mol) (K) (K) (pm)<br />

41 Nb niobium 652 1.6 2750. 5017 8.57 156<br />

42 Mo molybdenum 684 2.2 2896 4912 10.2 146<br />

43 Tc technetium 702 2.1 2430. 4538 11 138<br />

44 Ru ruthenium 710. 2.2 2606 4423 12.1 136<br />

45 Rh rhodium 720. 2.3 2237 3968 12.4 134<br />

46 Pd palladium 804 2.2 1828 3236 12.0 130.<br />

47 Ag silver 731 1.9 1235 2435 10.5 136<br />

48 Cd cadmium 868 1.7 594 1040. 8.69 140.<br />

49 In indium 558 1.8 430. 2345 7.31 142<br />

50 Sn tin (white) 709 2.0 505 2875 7.287 140.<br />

51 Sb antimony (gray) 831 2.1 904 1860. 6.68 140.<br />

52 Te tellurium 869 2.1 723 1261 6.232 137<br />

53 I iodine 1008 2.7 387 457 4.933 136<br />

54 Xe xenon 1170. 2.6 161 165 0.005366 136<br />

55 Cs cesium 376 0.8 302 944 1.873 238<br />

56 Ba barium 503 0.9 1000. 2170. 3.62 206<br />

57 La lanthanum 538 1.1 1193 3737 6.15 194<br />

Elements 58–71 have been omitted.<br />

72 Hf hafnium 659 1.3 2506 4876 13.3 164<br />

73 Ta tantalum 728 1.5 3290. 5731 16.4 158<br />

74 W tungsten 759 1.7 3695 5828 19.3 150.<br />

75 Re rhenium 756 1.9 3458 5869 20.8 141<br />

76 Os osmium 814 2.2 3306 5285 22.587 136<br />

77 Ir iridium 865 2.2 2719 4701 22.562 132<br />

78 Pt platinum 864 2.2 2041 4098 21.5 130.<br />

79 Au gold 890. 2.4 1337 3129 19.3 130.<br />

80 Hg mercury 1007 1.9 234 630. 13.5336 132<br />

81 Tl thallium 589 1.8 577 1746 11.8 144<br />

82 Pb lead 716 1.8 600. 2022 11.3 145<br />

83 Bi bismuth 703 1.9 544 1837 9.79 150.<br />

84 Po polonium 812 2.0 527 1235 9.20 142<br />

85 At astatine — 2.2 575 — — 148<br />

86 Rn radon 1037 — 202 211 0.009074 146<br />

87 Fr francium 393 0.7 300. — — 242<br />

88 Ra radium 509 0.9 969 — 5 211<br />

89 Ac actinium 499 1.1 1323 3471 10. 201<br />

Elements 90 and above have been omitted.<br />

*boiling point at standard pressure<br />

**density of solids and liquids at room temperature and density of gases at 298 K and 101.3 kPa<br />

— no data available<br />

Source: CRC Handbook for <strong>Chemistry</strong> and Physics, 91 st ed., 2010–2011, CRC Press<br />

Reference Tables for Physical Setting/<strong>Chemistry</strong> – 2011 Edition 11


Table T<br />

Important Formulas and Equations<br />

d = density<br />

m<br />

Density d = m = mass<br />

V<br />

V = volume<br />

Mole Calculations number of moles =<br />

given mass<br />

gram-formula mass<br />

measured value – accepted value<br />

Percent Error % error = × 100<br />

accepted value<br />

mass of part<br />

Percent Composition % composition by mass = × 100<br />

mass of whole<br />

mass of solute<br />

parts per million = × 1000000<br />

mass of solution<br />

Concentration<br />

molarity =<br />

moles of solute<br />

liter of solution<br />

Combined Gas Law<br />

P<br />

P = pressure<br />

1<br />

V 1<br />

P<br />

= 2<br />

V 2<br />

V = volume<br />

T 1<br />

T 2 T = temperature<br />

M A<br />

= molarity of H + M B<br />

= molarity of OH –<br />

Titration M A<br />

V A<br />

= M B<br />

V B<br />

V A<br />

= volume of acid V B<br />

= volume of base<br />

q = mCΔT q = heat H f<br />

= heat of fusion<br />

Heat q = mH f<br />

m = mass H v<br />

= heat of vaporization<br />

q = mH v<br />

C=specific heat capacity<br />

ΔT = change in temperature<br />

Temperature<br />

K = °C + 273<br />

K = kelvin<br />

°C = degree Celsius<br />

DET 609 ADU<br />

Reference Tables for Physical Setting/<strong>Chemistry</strong> – 2011 Edition 12


Common Lab Equipment Uses


SCIENTIFIC NOTATION RULES<br />

How to Write Numbers in Scientific Notation<br />

Scientific notation is a standard way of writing very large and very small numbers so that they're<br />

easier to both compare and use in computations. To write in scientific notation, follow the form<br />

N X 10 ᴬ<br />

where N is a number between 1 and 10, but not 10 itself, and A is an integer (positive or negative<br />

number).<br />

RULE #1: Standard Scientific Notation is a number from 1 to 9 followed by a decimal and the<br />

remaining significant figures and an exponent of 10 to hold place value.<br />

Example:<br />

5.43 x 10 2 = 5.43 x 100 = 543<br />

8.65 x 10 – 3 = 8.65 x .001 = 0.00865<br />

****54.3 x 10 1 is not Standard Scientific Notation!!!<br />

RULE #2: When the decimal is moved to the Left the exponent gets Larger, but the value of the<br />

number stays the same. Each place the decimal moves Changes the exponent by one (1). If you<br />

move the decimal to the Right it makes the exponent smaller by one (1) for each place it is moved.<br />

Example:<br />

6000. x 10 0 = 600.0 x 10 1 = 60.00 x 10 2 = 6.000 x 10 3 = 6000<br />

(Note: 10 0 = 1)<br />

All the previous numbers are equal, but only 6.000 x 10 3 is in proper Scientific Notation.


RULE #3: To add/subtract in scientific notation, the exponents must first be the same.<br />

Example:<br />

(3.0 x 10 2 ) + (6.4 x 10 3 ); since 6.4 x 10 3 is equal to 64. x 10 2 . Now add.<br />

(3.0 x 10 2 )<br />

+ (64. x 10 2 )<br />

67.0 x 10 2 = 6.70 x 10 3 = 6.7 x 10 3<br />

67.0 x 10 2 is mathematically correct, but a number in standard scientific notation can only<br />

have one number to the left of the decimal, so the decimal is moved to the left one place and<br />

one is added to the exponent.<br />

Following the rules for significant figures, the answer becomes 6.7 x 10 3 .<br />

RULE #4: To multiply, find the product of the numbers, then add the exponents.<br />

Example:<br />

(2.4 x 10 2 ) (5.5 x 10 –4 ) = ? [2.4 x 5.5 = 13.2]; [2 + -4 = -2], so<br />

(2.4 x 10 2 ) (5.5 x 10 –4 ) = 13.2 x 10 –2 = 1.3 x 10 – 1<br />

RULE #5: To divide, find the quotient of the number and subtract the exponents.<br />

Example:<br />

(3.3 x 10 – 6 ) / (9.1 x 10 – 8 ) = ? [3.3 / 9.1 = .36]; [-6 – (-8) = 2], so<br />

(3.3 x 10 – 6 ) / (9.1 x 10 – 8 ) = .36 x 10 2 = 3.6 x 10 1


1. 7,485 6. 1.683<br />

2. 884.2 7. 3.622<br />

3. 0.00002887 8. 0.00001735<br />

4. 0.05893 9. 0.9736<br />

5. 0.006162 10. 0.08558<br />

11. 6.633 X 10−⁴ 16. 1.937 X 10⁴<br />

12. 4.445 X 10−⁴ 17. 3.457 X 10⁴<br />

13. 2.182 X 10−³ 18. 3.948 X 10−⁵<br />

14. 4.695 X 10² 19. 8.945 X 10⁵<br />

15. 7.274 X 10⁵ 20. 6.783 X 10²


Convert each number from Scientific Notation to real numbers:<br />

1. 7.485 X 10³ 6. 1.683 X 10⁰<br />

2. 8.842 X 10² 7. 3.622 10⁰<br />

3. 2.887 X 10−⁵ 8. 1.735 X 10−⁵<br />

4. 5.893 X 10−² 9. 9.736 X 10−¹<br />

5. 6.162 X 10−³ 10. 8.558 X 10−²<br />

Convert each number from a real number to Scientific Notation:<br />

11. 0.0006633 16. 1,937,000<br />

12. 0.0004445 17. 34,570<br />

13. 0.002182 18. 0.00003948<br />

14. 469.5 19. 894,500<br />

15. 727,400 20. 678.3


Significant Figures Rules<br />

There are three rules on determining how many significant figures are in a<br />

number:<br />

1. Non-zero digits are always significant.<br />

2. Any zeros between two significant digits are significant.<br />

3. A final zero or trailing zeros in the DECIMAL PORTION ONLY are<br />

significant.<br />

Please remember that, in science, all numbers are based upon measurements (except for a very few<br />

that are defined). Since all measurements are uncertain, we must only use those numbers that are<br />

meaningful.<br />

Not all of the digits have meaning (significance) and, therefore, should not be written down. In<br />

science, only the numbers that have significance (derived from measurement) are written.<br />

Rule 1: Non-zero digits are always significant.<br />

If you measure something and the device you use (ruler, thermometer, triple-beam, balance, etc.)<br />

returns a number to you, then you have made a measurement decision and that ACT of measuring<br />

gives significance to that particular numeral (or digit) in the overall value you obtain.<br />

Hence a number like 46.78 would have four significant figures and 3.94 would have three.<br />

Rule 2: Any zeros between two significant digits are significant.<br />

Suppose you had a number like 409. By the first rule, the 4 and the 9 are significant. However, to<br />

make a measurement decision on the 4 (in the hundred's place) and the 9 (in the one's place), you<br />

HAD to have made a decision on the ten's place. The measurement scale for this number would have<br />

hundreds, tens, and ones marked.<br />

Like the following example:<br />

These are sometimes called "captured zeros."<br />

If a number has a decimal at the end (after the one’s place) then all digits (numbers) are significant<br />

and will be counted.<br />

In the following example the zeros are significant digits and highlighted in blue.<br />

960.<br />

70050.


Rule 3: A final zero or trailing zeros in the decimal portion ONLY are<br />

significant.<br />

This rule causes the most confusion among students.<br />

In the following example the zeros are significant digits and highlighted in blue.<br />

0.07030<br />

0.00800<br />

Here are two more examples where the significant zeros are highlighted in blue.<br />

When Zeros are Not Significant Digits<br />

4.7 0 x 10−³<br />

6.5 0 0 x 10⁴<br />

Zero Type # 1 : Space holding zeros in numbers less than one.<br />

In the following example the zeros are NOT significant digits and highlighted in red.<br />

0.09060<br />

0.00400<br />

These zeros serve only as space holders. They are there to put the decimal point in its correct<br />

location.<br />

They DO NOT involve measurement decisions.<br />

Zero Type # 2 : Trailing zeros in a whole number.<br />

In the following example the zeros are NOT significant digits and highlighted in red.<br />

200<br />

25000<br />

For addition and subtraction, look at the decimal portion (i.e., to the right of the decimal point)<br />

of the numbers ONLY. Here is what to do:<br />

1) Count the number of significant figures in the decimal portion of each number in the problem. (The<br />

digits to the left of the decimal place are not used to determine the number of decimal places in the<br />

final answer.)<br />

2) Add or subtract in the normal fashion.<br />

3) Round the answer to the LEAST number of places in the decimal portion of any number in the<br />

problem<br />

The following rule applies for multiplication and division:<br />

The LEAST number of significant figures in any number of the problem determines the number of<br />

significant figures in the answer.<br />

This means you MUST know how to recognize significant figures in order to use this rule.


How Many Significant Digits for Each Number?<br />

1) 2359 = ______<br />

2) 2.445 x 10−⁵= ______<br />

3) 2.93 x 10⁴= ______<br />

4) 1.30 x 10−⁷= ______<br />

5) 2604 = ______<br />

6) 9160 = ______<br />

7) 0.0800 = ______<br />

8) 0.84 = ______<br />

9) 0.0080 = ______<br />

10) 0.00040 = ______<br />

11) 0.0520 = ______<br />

12) 0.060 = ______<br />

13) 6.90 x 10−¹= ______<br />

14) 7.200 x 10⁵= ______<br />

15) 5.566 x 10−²= ______<br />

16) 3.88 x 10⁸= ______<br />

17) 3004 = ______<br />

18) 0.021 = ______<br />

19) 240 = ______<br />

20) 500 = ______


For addition and subtraction, look at the decimal portion (i.e., to the right of the decimal point) of the<br />

numbers ONLY. Here is what to do:<br />

1) Count the number of significant figures in the decimal portion of each number in the problem. (The<br />

digits to the left of the decimal place are not used to determine the number of decimal places in the<br />

final answer.)<br />

2) Add or subtract in the normal fashion.<br />

3) Round the answer to the LEAST number of places in the decimal portion of any number in the<br />

problem.<br />

Solve the Problems and Round Accordingly...<br />

1) 43.287 + 5.79 + 6.284 = _______<br />

2) 87.54 - 3.3 = _______<br />

3) 99.1498 + 6.5397 + 9.7 = _______<br />

4) 5.868 - 5.1 = _______<br />

5) 59.9233 + 86.21 + 99.396 = _______<br />

6) 7.7 + 26.756 = _______<br />

7) 66.8 + 2.3 + 4.8516 = _______<br />

8) 9.7419 + 43.545 = _______<br />

9) 4.8976 + 48.4644 + 1.514 = _______<br />

10) 4.335 + 35.85 = _______<br />

11) 9.448 - 1.7 = _______<br />

12) 75.826 - 8.6555 = _______<br />

13) 57.2 + 23.814 = _______<br />

14) 77.684 - 4.394 = _______<br />

15) 26.4496 + 3.339 = _______<br />

16) 9.6848 + 29.85 = _______<br />

17) 63.11 + 2.5412 + 4.93 = _______<br />

18) 11.2471 + 75.4 = _______<br />

19) 73.745 - 8.755 = _______<br />

20) 6.5238 + 1.7 + 27.79 = _______


The following rule applies for multiplication and division:<br />

The LEAST number of significant figures in any number of the problem determines the number of<br />

significant figures in the answer.<br />

This means you MUST know how to recognize significant figures in order to use this rule.<br />

Solve the Problems and Round Accordingly...<br />

1) 0.6 x 65.0 x 602 = __________<br />

2) 720 ÷ 7.7 = __________<br />

3) 929 x 0.3 = __________<br />

4) 300 ÷ 44.31 = __________<br />

5) 608 ÷ 9.8 = __________<br />

6) 0.06 x 0.079 = __________<br />

7) 0.008 x 72.91 x 7000 = __________<br />

8) 73.94 x 67 x 780 = __________<br />

9) 0.62 x 0.097 x 40 = __________<br />

10) 600 x 10 x 5030 = __________<br />

11) 5200 ÷ 4.46 = __________<br />

12) 0.0052 x 0.4 x 107 = __________<br />

13) 0.099 x 8.8 = __________<br />

14) 0.0095 x 5.2 = __________<br />

15) 8000 ÷ 4.62 = __________<br />

16) 0.6 x 0.8 = __________<br />

17) 2.84 x 0.66 = __________<br />

18) 0.5 x 0.09 = __________<br />

19) 8100 ÷ 34.84 = __________<br />

20) 8.24 x 6.9 x 8100 = __________


Question Sig Figs Question Add & Subtract Question Multiple & Divide<br />

1 4 1 55.36 1 20,000<br />

2 4 2 84.2 2 94<br />

3 3 3 115.4 3 300<br />

4 3 4 0.8 4 7<br />

5 4 5 245.53 5 62<br />

6 3 6 34.5 6 0.005<br />

7 3 7 74.0 7 4,000<br />

8 2 8 53.287 8 3,900,000<br />

9 2 9 54.876 9 2<br />

10 2 10 40.19 10 30,000,000<br />

11 3 11 7.7 11 1,200<br />

12 2 12 67.170 12 0.2<br />

13 3 13 81.0 13 0.87<br />

14 4 14 73.290 14 0.049<br />

15 4 15 29.789 15 2,000<br />

16 3 16 39.53 16 0.5<br />

17 4 17 70.58 17 1.9<br />

18 2 18 86.6 18 0.05<br />

19 2 19 64.990 19 230<br />

20 1 20 36.0 20 460,000


To use the Stair-Step method, find the prefix the original measurement starts with. (ex. milligram)<br />

If there is no prefix, then you are starting with a base unit.<br />

Find the step which you wish to make the conversion to. (ex. decigram)<br />

Count the number of steps you moved, and determine in which direction you moved (left or right).<br />

The decimal in your original measurement moves the same number of places as steps you moved and in the<br />

same direction. (ex. milligram to decigram is 2 steps to the left, so 40 milligrams = .40 decigrams)<br />

If the number of steps you move is larger than the number you have, you will have to add zeros to hold the<br />

places. (ex. kilometers to meters is three steps to the right, so 10 kilometers would be equal to 10,000 m)<br />

That’s all there is to it! You need to be able to count to 6, and know your left from your right!<br />

1) Write the equivalent<br />

a) 5 dm =_______m b) 4 mL = ______L c) 8 g = _______mg<br />

d) 9 mg =_______g e) 2 mL = ______L f) 6 kg = _____g<br />

g) 4 cm =_______m h) 12 mg = ______ g i) 6.5 cm 3 = _______L<br />

j) 7.02 mL =_____cm 3 k) .03 hg = _______ dg l) 6035 mm _____cm<br />

m) .32 m = _______cm n) 38.2 g = _____kg


2. One cereal bar has a mass of 37 g. What is the mass of 6 cereal bars? Is that more than or less<br />

than 1 kg? Explain your answer.<br />

3. Wanda needs to move 110 kg of rocks. She can carry l0 hg each trip. How many trips must she<br />

make? Explain your answer.<br />

4. Dr. O is playing in her garden again She needs 1 kg of potting soil for her plants. She has 750 g.<br />

How much more does she need? Explain your answer.<br />

5. Weather satellites orbit Earth at an altitude of 1,400,000 meters. What is this altitude in kilometers?<br />

6. Which unit would you use to measure the capacity? Write milliliter or liter.<br />

a) a bucket __________<br />

b) a thimble __________<br />

c) a water storage tank__________<br />

d) a carton of juice__________<br />

7. Circle the more reasonable measure:<br />

a) length of an ant 5mm or 5cm<br />

b) length of an automobile 5 m or 50 m<br />

c) distance from NY to LA 450 km or 4,500 km<br />

d) height of a dining table 75 mm or 75 cm<br />

8. Will a tablecloth that is 155 cm long cover a table that is 1.6 m long? Explain your answer.<br />

9. A dollar bill is 15.6 cm long. If 200 dollar bills were laid end to end, how many meters long would<br />

the line be?<br />

10. The ceiling in Jan’s living room is 2.5 m high. She has a hanging lamp that hangs down 41 cm.<br />

Her husband is exactly 2 m tall. Will he hit his head on the hanging lamp? Why or why not?


Using SI Units<br />

Match the terms in Column II with the descriptions in Column I. Write the letters of the correct term in<br />

the blank on the left.<br />

Column I Column II<br />

_____ 1. distance between two points<br />

a. time<br />

_____ 2. SI unit of length<br />

_____ 3. tool used to measure length<br />

_____ 4. units obtained by combining other units<br />

_____ 5. amount of space occupied by an object<br />

_____ 6. unit used to express volume<br />

_____ 7. SI unit of mass<br />

_____ 8. amount of matter in an object<br />

_____ 9. mass per unit of volume<br />

_____ 10. temperature scale of most laboratory thermometers<br />

_____ 11. instrument used to measure mass<br />

_____ 12. interval between two events<br />

_____ 13. SI unit of temperature<br />

_____ 14. SI unit of time<br />

_____ 15. instrument used to measure temperature<br />

b. volume<br />

c. mass<br />

d. density<br />

e. meter<br />

f. kilogram<br />

g. derived<br />

h. liter<br />

i. second<br />

j. Kelvin<br />

k. length<br />

1. balance<br />

m. meterstick<br />

n. thermometer<br />

o. Celsius<br />

Circle the two terms in each group that are related. Explain how the terms are related.<br />

16. Celsius degree, mass, Kelvin _____________________________________________________<br />

________________________________________________________________________________<br />

17. balance, second, mass __________________________________________________________<br />

________________________________________________________________________________<br />

18. kilogram, liter, cubic centimeter __________________________________________________<br />

________________________________________________________________________________<br />

19. time, second, distance __________________________________________________________<br />

________________________________________________________________________________<br />

20. decimeter, kilometer, Kelvin _____________________________________________________<br />

________________________________________________________________________________


1. How many meters are in one kilometer? __________<br />

2. What part of a liter is one milliliter? __________<br />

3. How many grams are in two dekagrams? __________<br />

4. If one gram of water has a volume of one milliliter, what would the mass of one liter of water be in<br />

kilograms?__________<br />

5. What part of a meter is a decimeter? __________<br />

In the blank at the left, write the term that correctly completes each statement. Choose from the terms<br />

listed below.<br />

Metric SI standard ten<br />

prefixes ten tenth<br />

6. An exact quantity that people agree to use for comparison is a ______________ .<br />

7. The system of measurement used worldwide in science is _______________ .<br />

8. SI is based on units of _______________ .<br />

9. The system of measurement that was based on units of ten was the _______________ system.<br />

10. In SI, _______________ are used with the names of the base unit to indicate the multiple of ten<br />

that is being used with the base unit.<br />

11. The prefix deci- means _______________ .


Standards of Measurement<br />

Fill in the missing information in the table below.<br />

S.I prefixes and their meanings<br />

Prefix<br />

Meaning<br />

0.001<br />

0.01<br />

deci- 0.1<br />

10<br />

hecto- 100<br />

1000<br />

Circle the larger unit in each pair of units.<br />

1. millimeter, kilometer 4. centimeter, millimeter<br />

2. decimeter, dekameter 5. hectogram, kilogram<br />

3. hectogram, decigram<br />

6. In SI, the base unit of length is the meter. Use this information to arrange the following units of<br />

measurement in the correct order from smallest to largest.<br />

Write the number 1 (smallest) through 7 - (largest) in the spaces provided.<br />

_____ a. kilometer<br />

_____ b. centimeter<br />

_____ c. meter<br />

_____ e. hectometer<br />

_____ f. millimeter<br />

_____ g. decimeter<br />

_____ d. dekameter<br />

Use your knowledge of the prefixes used in SI to answer the following questions in the spaces<br />

provided.<br />

7. One part of the Olympic games involves an activity called the decathlon. How many events do you<br />

think make up the decathlon?_____________________________________________________<br />

8. How many years make up a decade? _______________________________________________<br />

9. How many years make up a century? ______________________________________________<br />

10. What part of a second do you think a millisecond is? __________________________________


Dimensional Analysis<br />

This is a way to convert from one unit of a given substance to<br />

another unit using ratios or conversion units. What this video<br />

www.youtube.com/watch?v=aZ3J60GYo6U<br />

Let’ look at a couple of examples:<br />

1. Convert 2.6 qt to mL.<br />

First we need a ratio or conversion unit so that we can go from quarts to milliliters. 1.00 qt = 946 mL<br />

Next write down what you are starting with<br />

2.6 qt<br />

Then make you conversion tree<br />

2.6 qt<br />

Then fill in the units in your ratio so that you can cancel out the original unit and will be left with the<br />

unit you need for the answer. Cross out units, one at a time that are paired, and one on top one on<br />

the bottom.<br />

2.6 qt mL<br />

qt<br />

Now fill in the values from the ratio.<br />

2.6 qt 946 mL<br />

1.00 qt<br />

Now multiply all numbers on the top and multiply all numbers on the bottom and write them as a<br />

fraction.<br />

2.6 qt 946 mL = 2,459.6 mL<br />

1.00 qt 1.00<br />

Now divide the top number by the bottom number and write that number with the unit that was not<br />

crossed out.


1qt=32 oz 1gal = 4qts 1.00 qt = 946 mL 1L = 1000mL<br />

2. Convert 8135.6 mL to quarts<br />

=<br />

3. Convert 115.2 oz to mL<br />

=<br />

4. Convert 2.3 g to Liters<br />

=<br />

5. Convert 8.42 L to oz<br />

=<br />

Go to http://science.widener.edu/svb/tutorial/ chose #7 “Converting Volume” and do 5 more in the<br />

space provided.<br />

1. Convert _________ to _________<br />

=<br />

2. Convert _________ to _________<br />

=<br />

3. Convert _________ to _________<br />

=<br />

4. Convert _________ to _________<br />

=<br />

5. Convert _________ to _________<br />

=


Converting Real Things<br />

Table 1<br />

Using the scale, come up with a conversion ratio just by looking at the scale and prove that it works<br />

but converting 10 grams to ounces. (Hint: 7grams and 15 grams)<br />

Table 2<br />

Using a 50 mL graduated cylinder, fill a 600mL beaker 66.7% full.<br />

Table 3<br />

Using the measuring cup determine how many mL are in 4 ounces of water. Make a conversion ratio<br />

you could use to do other conversions.<br />

Table 4<br />

Using a meter stick, measure the back table in inches, feet and yards and convert them into<br />

centimeters and meters.<br />

Table 5<br />

Using the scale, find the mass of a text book on your table in ounces (round to the nearest ounce)<br />

and cover it to grams.<br />

Table 6<br />

Using the ruler, measure the length of a piece of paper in inches and then convert that into meters.<br />

Make a conversion ratio you could use to do other conversions.


Atoms Are Building Blocks<br />

Atoms are the basis of chemistry. They are the basis for everything in the Universe. You<br />

should start by remembering that matter is composed of atoms. Atoms and the study of<br />

atoms are a world unto themselves. We're going to cover basics like atomic structure<br />

and bonding between atoms.<br />

Smaller Than Atoms?<br />

Are there pieces of matter that are smaller than atoms?<br />

Sure there are. You'll soon be learning that atoms are<br />

composed of pieces like electrons, protons, and neutrons.<br />

But guess what? There are even smaller particles moving<br />

around in atoms. These super-small particles can be found<br />

inside the protons and neutrons. Scientists have many<br />

names for those pieces, but you may have heard of<br />

nucleons and quarks. Nuclear chemists and physicists<br />

work together at particle accelerators to discover the<br />

presence of these tiny, tiny, tiny pieces of matter.<br />

Even though super-tiny atomic particles exist, you only<br />

need to remember the three basic parts of an atom: electrons, protons, and neutrons.<br />

What are electrons, protons, and neutrons? A picture works best to show off the idea.<br />

You have a basic atom. There are three types of pieces in that atom: electrons, protons,<br />

and neutrons. That's all you have to remember. Three things! As you know, there are<br />

almost 120 known elements in the periodic table. Chemists and physicists haven't<br />

stopped there. They are trying to make new ones in labs every day. The thing that<br />

makes each of those elements different is the number of electrons, protons, and<br />

neutrons. The protons and neutrons are always in the center of the atom. Scientists call<br />

the center region of the atom the nucleus. The nucleus in<br />

a cell is a thing. The nucleus in an atom is a place where<br />

you find protons and neutrons. The electrons are always<br />

found whizzing around the center in areas called shells or<br />

orbitals.<br />

You can also see that each piece has either a "+", "-", or a<br />

"0." That symbol refers to the charge of the particle. Have<br />

you ever heard about getting a shock from a socket, static<br />

electricity, or lightning? Those are all different types of<br />

electric charges. Those charges are also found in tiny particles of matter. The electron<br />

always has a "-", or negative, charge. The proton always has a "+", or positive, charge. If<br />

the charge of an entire atom is "0", or neutral, there are equal numbers of positive and<br />

negative pieces. Neutral means there are equal numbers of electrons and protons. The<br />

third particle is the neutron. It has a neutral charge, also known as a charge of zero. All<br />

atoms have equal numbers of protons and electrons so that they are neutral. If there are<br />

more positive protons or negative electrons in an atom, you have a special atom called<br />

an ion.


http://www.learner.org/interactives/periodic/basics_interactive.html


Looking at Ions<br />

We haven’t talked about ions before, so let’s get down to basics. The<br />

atomic number of an element, also called a proton number, tells you the<br />

number of protons or positive particles in an atom. A normal atom has a<br />

neutral charge with equal numbers of positive and negative particles.<br />

That means an atom with a neutral charge is one where the number of<br />

electrons is equal to the atomic number. Ions are atoms with extra<br />

electrons or missing electrons. When you are missing an electron or<br />

two, you have a positive charge. When you have an extra electron<br />

or two, you have a negative charge.<br />

What do you do if you are a sodium (Na) atom? You have eleven<br />

electrons — one too many to have an entire shell filled. You need to<br />

find another element that will take that electron away from you. When you lose that<br />

electron, you will you’ll have full shells. Whenever an atom has full shells, we say it is<br />

"happy." Let's look at chlorine (Cl). Chlorine has seventeen electrons and only needs<br />

one more to fill its third shell and be "happy." Chlorine will take your extra sodium<br />

electron and leave you with 10 electrons inside of two filled shells. You are now a happy<br />

atom too. You are also an ion and missing one electron. That missing electron gives you<br />

a positive charge. You are still the element sodium, but you are now a sodium ion (Na + ).<br />

You have one less electron than your atomic number.<br />

Ion Characteristics<br />

So now you've become a sodium ion. You have ten electrons.<br />

That's the same number of electrons as neon (Ne). But you<br />

aren't neon. Since you're missing an electron, you aren't really<br />

a complete sodium atom either. As an ion you are now<br />

something completely new. Your whole goal as an atom was<br />

to become a "happy atom" with completely filled electron<br />

shells. Now you have those filled shells. You have a lower<br />

energy. You lost an electron and you are "happy." So what<br />

makes you interesting to other atoms? Now that you have<br />

given up the electron, you are quite electrically attractive.<br />

Other electrically charged atoms (ions) of the opposite charge<br />

(negative) are now looking at you and seeing a good partner to<br />

bond with. That's where the chlorine comes in. It's not only chlorine. Almost any ion with<br />

a negative charge will be interested in bonding with you.


Electrovalence<br />

Don't get worried about the big word. Electrovalence is just another word for something<br />

that has given up or taken electrons and become an ion. If you look at the periodic table,<br />

you might notice that elements on the left side usually become positively charged ions<br />

(cations) and elements on the right side get a negative charge (anions). That trend<br />

means that the left side has a positive valence and the right side has a negative<br />

valence. Valence is a measure of how much an atom wants to bond with other atoms. It<br />

is also a measure of how many electrons are excited about bonding with other atoms.<br />

There are two main types of bonding, covalent and electrovalent. You may have heard<br />

of the term "ionic bonds." Ionic bonds are electrovalent bonds. They are just groups of<br />

charged ions held together by electric forces. When in the presence of other ions, the<br />

electrovalent bonds are weaker because of outside electrical forces and attractions.<br />

Sodium and chlorine ions alone have a very strong bond, but as soon as you put those<br />

ions in a solution with H + (Hydrogen ion), OH - (Hydroxide), F - (Fluorine ion) or Mg ++<br />

(Magnesium ion), there are charged distractions that break the Na-Cl bond.<br />

Look at sodium chloride (NaCl) one more time. Salt is a very strong bond when it is<br />

sitting on your table. It would be nearly impossible to break those ionic/electrovalent<br />

bonds. However, if you put that salt into some water (H 2 O), the bonds break very<br />

quickly. It happens easily because of the electrical attraction of the water. Now you have<br />

sodium (Na + ) and chlorine (Cl - ) ions floating around the solution. You should remember<br />

that ionic bonds are normally strong, but they are very weak in water.


Neutron Madness<br />

We have already learned that ions are atoms that are<br />

either missing or have extra electrons. Let's say an atom<br />

is missing a neutron or has an extra neutron. That type of<br />

atom is called an isotope. An atom is still the same<br />

element if it is missing an electron. The same goes for<br />

isotopes. They are still the same element. They are just a<br />

little different from every other atom of the same element.<br />

For example, there are a lot of carbon (C) atoms in the<br />

Universe. The normal ones are carbon-12. Those atoms have 6 neutrons. There are a<br />

few straggler atoms that don't have 6. Those odd ones may have 7 or even 8 neutrons.<br />

As you learn more about chemistry, you will probably hear about carbon-14. Carbon-14<br />

actually has 8 neutrons (2 extra). C-14 is considered an isotope of the element carbon.<br />

Messing with the Mass<br />

If you have looked at a periodic table, you may have noticed that the atomic mass of<br />

an element is rarely an even number. That happens because of the isotopes. If you are<br />

an atom with an extra electron, it's no big deal. Electrons don't have much of a mass<br />

when compared to a neutron or proton.<br />

Atomic masses are calculated by figuring out the<br />

amounts of each type of atom and isotope there are in<br />

the Universe. For carbon, there are a lot of C-12, a<br />

couple of C-13, and a few C-14 atoms. When you<br />

average out all of the masses, you get a number that is a<br />

little bit higher than 12 (the weight of a C-12 atom). The<br />

average atomic mass for the element is actually 12.011.<br />

Since you never really know which carbon atom you are<br />

using in calculations, you should use the average mass<br />

of an atom.<br />

Bromine (Br), at atomic number 35, has a greater variety of isotopes. The atomic mass<br />

of bromine (Br) is 79.90. There are two main isotopes at 79 and 81, which average out<br />

to the 79.90amu value. The 79 has 44 neutrons and the 81 has 46 neutrons. While it<br />

won't change the average atomic mass, scientists have made bromine isotopes with<br />

masses from 68 to 97. It's all about the number of neutrons. As you move to higher<br />

atomic numbers in the periodic table, you will probably find even more isotopes for<br />

each element.


I did not use publisher for this part because my computer does<br />

not have it to be used. I used a PDF file and used as much of it<br />

as I could.


I did not use publisher for this part because my computer does<br />

not have it to be used. I used a PDF file and used as much of it<br />

as I could.


I did not use publisher for this part because my computer does<br />

not have it to be used. I used a PDF file and used as much of it<br />

as I could.


I did not use publisher for this part because my computer does<br />

not have it to be used. I used a PDF file and used as much of it<br />

as I could.


P<br />

N<br />

P<br />

N


P<br />

N<br />

P<br />

N


Electron Configuration<br />

Color the sublevel:<br />

s = Red<br />

d = Green<br />

p = Blue<br />

f = Orange<br />

Write in sublevels<br />

Write period, sublevel and super scripts.<br />

Ctrl Shift =<br />

gives you super scripts


www.youtube.com/watch?v=jtYzEzykFdg<br />

www.youtube.com/watch?<br />

annotation_id=annotation_2076&feature=iv&src_vid=jtYzEzykFdg&v=cOlac8ruD_0<br />

www.youtube.com/watch?<br />

annotation_id=annotation_570977&feature=iv&src_vid=cOlac8ruD_0&v=lR2vqHZWb5A


Electron Configuration<br />

In order to write the electron configuration for an atom you must know the 3 rules of<br />

electron configurations.<br />

1. Aufbau<br />

Notation<br />

nO e<br />

where<br />

n is the energy level<br />

O is the orbital type (s, p, d, or f)<br />

e is the number of electrons in that orbital shell<br />

Principle<br />

electrons will first occupy orbitals of the lowest energy level<br />

2. Hund rule<br />

when electrons occupy orbitals of equal energy, one electron enters each orbital until<br />

all the orbitals contain one electron with the same spin.<br />

3. Pauli exclusion principle<br />

an orbital contains a maximum of 2 electrons and<br />

paired electrons will have opposite spin


In the space below, write the unabbreviated electron configurations of the following elements:<br />

1) sodium ________________________________________________<br />

2) iron ________________________________________________<br />

3) bromine ________________________________________________<br />

4) barium ________________________________________________<br />

5) neptunium ________________________________________________<br />

In the space below, write the abbreviated electron configurations of the following elements:<br />

6) cobalt ________________________________________________<br />

7) silver ________________________________________________<br />

8) tellurium ________________________________________________<br />

9) radium ________________________________________________<br />

10) lawrencium ________________________________________________<br />

Determine what elements are denoted by the following electron configurations:<br />

11) 1s²s²2p⁶3s²3p⁴ ____________________<br />

12) 1s²2s²2p⁶3s²3p⁶4s²3d¹⁰4p⁶5s¹ ____________________<br />

13) [Kr] 5s²4d¹⁰5p³ ____________________<br />

14) [Xe] 6s²4f¹⁴5d⁶ ____________________<br />

15) [Rn] 7s²5f¹¹ ____________________<br />

Identify the element or determine that it is not a valid electron configuration:<br />

16) 1s²2s²2p⁶3s²3p⁶4s²4d¹⁰4p⁵ ____________________<br />

17) 1s²2s²2p⁶3s³3d⁵ ____________________<br />

18) [Ra] 7s²5f⁸ ____________________<br />

19) [Kr] 5s²4d¹⁰5p⁵ ____________________<br />

20) [Xe] ____________________<br />

1)sodium 1s 2 2s 2 2p 6 3s 1 2)iron 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 6<br />

3)bromine 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 10 4p 5 4)barium 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 10 4p 6 5s 2 4d 10 5p 6 6s 2<br />

5)neptunium 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 10 4p 6 5s 2 4d 10 5p 6 6s 2 4f 14 5d 10 6p 6 7s 2 5f 5 6)cobalt [Ar] 4s 2 3d 7<br />

7)silver [Kr] 5s 2 4d 9 8)tellurium[Kr] 5s 2 4d 10 5p 4<br />

9)radium [Rn] 7s 2 10)lawrencium[Rn] 7s 2 5f 14 6d 1<br />

1s 2 2s 2 2p 6 3s 2 3p 4 sulfur 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 10 4p 6 5s 1 rubidium<br />

[Kr] 5s 2 4d 10 5p 3 antimony [Xe] 6s 2 4f 14 5d 6 osmium<br />

[Rn] 7s 2 5f 11 einsteinium 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 4d 10 4p 5 not valid (take a look at “4d”)<br />

1s 2 2s 2 2p 6 3s 3 3d 5 not valid (3p comes after 3s) [Ra] 7s 2 5f 8 not valid (radium isn’t a noble gas)<br />

[Kr] 5s 2 4d 10 5p 5 valid iodine<br />

20)[Xe] not valid (an element can’t be its own electron configuration)


Using Wikipedia define the 8 categories of elements on pages 168 and 169 on the left<br />

page.<br />

Color your periodic table similar to the one on Pages 168—169.


Create groups for these Scientist and explain your groupings<br />

(use the information you got from your research)


Research these Scientist and summarize their contributions to chemistry<br />

Antoine Henri Becquerel<br />

Niels Bohr<br />

Louis de Barogilie<br />

Glenn Seaborg<br />

Hantaro Nagaoka<br />

Democritus<br />

Marie and Pierre Curie<br />

Eugene Goldstein<br />

Dmitri Mendeleev<br />

J.J. Thomson<br />

James Chadwick<br />

Erwin Shrodinger<br />

John Dalton<br />

Lothar Meyer<br />

Robert Millikan<br />

J.W. Dobereiner<br />

Ernest Rutherford


Chapter 25 Notes<br />

Vocab:<br />

-25.1 Nuclear Radiation-<br />

<br />

<br />

<br />

<br />

<br />

<br />

Radioactivity – reference to the spontaneous emission of rays or particles from certain<br />

elements<br />

Nuclear radiation – the name of the rays and particles emitted from a radioactive source<br />

Radiosiotopes – unstable isotopes<br />

Alpha particle – the helium nuclei emitted by some radioactive sources, has 2 protons<br />

and 2 neutrons<br />

Beta particles – an electron resulting from the breaking apart of an atom, has 1 electron<br />

and 1 proton, but no neutron<br />

Gamma Ray – a high-energy photon emitted by a radioisotope, electromagnetic<br />

radiation with high penetration through the human body<br />

Notes:<br />

<br />

<br />

<br />

<br />

<br />

Antoine Henri Bequerel and Marie and Pierre Curie accidentally discovered that uranium<br />

salt emitted radioactive rays because of a fog left on a photographic plate, and used<br />

radioactivity to explain why this happened.<br />

Atoms become more stable in nuclear or chemical reactions.<br />

Nuclear reactions begin with unstable radioisotopes, which later become much more<br />

stable after the reaction.<br />

Unlike chemical reactions, nuclear reactions are not affected by changes in<br />

temperature, pressure, or the presence of catalysts. Nuclear reactions of a given<br />

radioisotope can’t be slowed down, sped up, or stopped.<br />

Radioactive decay doesn’t require input energy. Radioactivity is continued until unstable<br />

isotopes are changed to become stable isotopes of a different element.<br />

Type Particles Symbol Charge Mass Source Penetration<br />

Alpha Radiation Helium nuclei α 2+ 4 Radium Low (0.05<br />

mm body<br />

tissue)<br />

Beta Radiation Electrons β 1- 1/1837 Carbon Moderate (4<br />

mm body<br />

tissue)


Gamma<br />

Radiation<br />

High energy<br />

electromagnetic<br />

radiation<br />

γ 0 0 Cobalt Very High<br />

(penetrates<br />

body easily)<br />

-Chapter 25.2 Nuclear Transformations-<br />

Vocab:<br />

<br />

<br />

<br />

<br />

<br />

Nuclear force – an attractive force that acts between all nuclear particles that are<br />

extremely close together<br />

Positron – a particle with the mass of an electron but a positive charge<br />

Half-life – the time required for one-half of the nuclei in a radioisotope sample to decay<br />

to products<br />

Transmutation – the conversion of one atom of one element into another atom of<br />

another element<br />

Transuranium elements – elements with atomic numbers above 92 (uranium)<br />

Notes:<br />

<br />

<br />

<br />

The neutron-to-proton ratio in a radioscope determines the type of decay that occurs.<br />

All nuclei that have an atomic number over 83 are radioactive, these contain too many<br />

neutrons and protons that make the atom unstable.<br />

During each half-life, half of the remaining radioactivity atoms decay into atoms of a<br />

new element.<br />

Half-Life Amount Remaining<br />

0 A^0 X (1/2)^0 = A^O<br />

1 A^0 X (1/2)^1 = A^0<br />

2 A^0 X (1/2)^2 = A^0<br />

<br />

<br />

Radiocarbon dating measures the amount of the isotope carbon-14 an object contains.<br />

Can only be used the measure the time line of a carbon-based material or life form.<br />

Transmutation can occur by radioactive decay or when particles attack the nucleus of<br />

an atom.


Learning Goal: The students will learn how molecular bonding is different than ionic bonding and<br />

electrons affect the shape of a molecule and its properties.<br />

Metallic or Ionic Bonds<br />

CCSTD HS <strong>Chemistry</strong> 2.a..<br />

A chemical bond is the “glue” that holds atoms together. Chemical bonds<br />

can be weak or strong, and everything in between!<br />

One thing that all chemical bonds share is that they are just an atom’s<br />

attempt to complete its outer (valence) shell of electrons. The closer an atom’s<br />

valence shell comes to being completely full, then the closer that atom comes to<br />

resemble an inert, or noble, gas.<br />

It turns out that all atoms strive to have the electronic configuration of an<br />

inert gas atom! Why is that such a desirable state? Inert gases are extremely stable.<br />

In fact, inert gases are so stable that they don’t bond, ever, to anything. They are<br />

perfectly content to remain just as they are.<br />

Ionic Bonds<br />

Another type of chemical bond, the ionic bond, involves a somewhat<br />

different arrangement of electrons within a molecule. Ionic bonds form when a<br />

“give and take” situation exists between atoms. One atom within the molecule


gives an electron (to leave behind a positively charged atom), and another atom<br />

takes an electron (to result in a negatively charged atom).<br />

You can just imagine what will happen if you put a positively charged atom<br />

(cation) next to a negatively charged atom (anion)! They are attracted to each other<br />

and we call this type of attraction an ionic bond.<br />

Think of an ionic bond as one valence shell cloud with a positive charge<br />

being attracted to another valence shell cloud with a negative charge. When those<br />

two clouds are next to each other, they “stick” together and the resultant molecule<br />

has no net charge.<br />

Table salt, or Sodium Chloride (NaCl), is a compound that has an ionic bond<br />

(see Figure 3.1.2). The Sodium within the molecule donates its electron and the<br />

Chloride accepts the electron. This condition gives the Sodium atom the electronic<br />

configuration of a Neon atom (an inert gas), and the Chloride atom the electronic<br />

configuration of an Argon atom (another inert gas!).<br />

` An ionic bond can involve the loss of more than one electron, with the other<br />

atom in the ionic compound gaining the same number of electrons. Magnesium<br />

Chloride (MgCl2) is an example of a doubly ionic compound. Once again,<br />

Magnesium Chloride has no net charge, and in this case, one Magnesium atom has<br />

lost two electrons (achieving the electronic configuration of Neon), with each of<br />

two Chloride atoms accepting one electron.<br />

Ionic bonds have distinctive properties of:<br />

When in solid form, all ionic compounds are crystalline solids at room temperature<br />

(the alternating positive and negative ions are arranged in a crystal lattice<br />

structure),


Strong ionic bonding forces making the solid structures hard with high melting and<br />

boiling points,<br />

Multiple charges within the ionic bond lead to stronger bonding forces (i.e. the<br />

bonding of MgCl2 is stronger than the bonding of NaCl), and<br />

Most ionic compounds are soluble in water (once they are fused (melted), or<br />

dissolved in water, ionic compounds conduct electricity because the anions are<br />

then free to move freely). Most often, ionic compounds are combinations of<br />

cations of atoms from the furthest left of the periodic (groups IA and IIA), with<br />

anions of atoms from the right of the periodic table (group VIIA), immediately<br />

preceding the inert gases.<br />

Metallic Bonds<br />

The metallic bond is actually a special case of an ionic bond. Think of metallic<br />

bonding as a more or less static arrangement of positive ions within a moving array<br />

of mobile electrons.<br />

This unique arrangement of cations and electrons give metals their characteristic<br />

properties. Metallic properties include.<br />

Heat conductivity: mobile electrons can carry the kinetic energy of heat.<br />

Shiny appearance: the rapidly moving electrons emit energy in the form of light.<br />

Electricity conductors: electricity is the flow of electrons.<br />

Malleability: ability to be easily shaped into flat sheets or drawn into wires.


More notes…<br />

Ionic Bonds<br />

Ionic bonds are the fusing together of metals and nonmetals<br />

Cross multiply the charges, and the charges become subscripts<br />

Names: Metal Nonmetal (NaCl), the nonmetal adds the suffix ‘ide’ for the full<br />

name (Sodium Chloride)<br />

The metal atoms give away their electrons to become a positively charged ion, and<br />

the nonmetal takes electrons to become a negatively charged ion.<br />

H 1 0<br />

H 2 0<br />

H 3 0<br />

H 4 0<br />

1-No pronunciation (Hydrogen Oxide)<br />

2-Di (Hydrogen Dioxide)<br />

3- Tri (Hydrogen Trioxide)<br />

4-Tetra (Hydrogen Tetraoxide)


Learning Goal: The students will learn how molecular bonding is different than ionic bonding and<br />

electrons affect the shape of a molecule and it's properties.<br />

Covalent Bond Notes<br />

When 2 nonmetals bond together, they share electrons<br />

Charges are not needed, because the mixtures are always stabilized.<br />

Sometimes they are called strong bonds because of the high difficulty of breaking these atoms<br />

apart aside from using special enzymes.<br />

Hydrogen and ionic bonds are easily broken by anything as small as temperature change.<br />

Covalent bonds form definite and easily predictable shapes.<br />

Another form of covalent bonding is polar bonding, where an atom shares atoms with<br />

hydrogen atoms. Water is an example of polar bonding.<br />

The Octet rule includes that all atoms excluding hydrogen and helium have to have 8 total<br />

electrons in their valence shell to become stable.<br />

This process can be achieved through many forms of bonding, with covalent being the most<br />

powerful.


A single bond is when two pair of electrons are shared between two atoms.<br />

A Double pair is when an atom shares two pairs of electrons to another atom<br />

A Triple pair is when an atom shares 3 pairs of electrons (total of 6) with another atom<br />

A polar covalent bond is a bond made, but is not equally shared because of the higher<br />

electronegativity of one of the atoms is higher than the other, which causes higher attraction<br />

with the electron<br />

A nonpolar covalent bond is bond made and is equally shared because of the equal<br />

electronegativity and therefore equally magnetic pull of the electron between the atoms


Name Formula Charge<br />

Dichromate Cr₂O₇ 2-<br />

Sulfate SO₄ 2-<br />

Hydrogen Carbonate HCO₃ 1-<br />

Hypochlorite ClO 1-<br />

Phosphate PO₄ 3-<br />

Nitrite NO₂ 1-<br />

Chlorite ClO₂ 1-<br />

Dihydrogen phosphate H₂PO₄ 1-<br />

Chromate CrO₄ 2-<br />

Carbonate CO₃ 2-<br />

Hydroxide OH 1-<br />

Hydrogen phosphate HPO₄ 2-<br />

Ammonium NH₄ 1+<br />

Acetate C₂H₃O₂ 1-<br />

Perchlorate ClO₄ 1-<br />

Permanganate MnO₄ 1-<br />

Chlorate ClO₃ 1-<br />

Hydrogen Sulfate HSO₄ 1-<br />

Phosphite PO₃ 3-<br />

Sulfite SO₃ 2-<br />

Silicate SiO₃ 2-<br />

Nitrate NO₃ 1-<br />

Hydrogen Sulfite HSO₃ 1-<br />

Oxalate C₂O₄ 2-<br />

Cyanide CN 1-<br />

Hydronium H₃O 1+<br />

Thiosulfate S₂O₃ 2-


Orbital Equation Lone Pairs Angle Name


Linear AX 2<br />

sp<br />

Bent AX 2 E<br />

Bent AX 2 E 2<br />

One pair of electrons Two pairs of electrons.<br />

sp 2 sp 3<br />

Tetrahedral AX 4<br />

Octahedral


Trig.plannar<br />

AX 3 sp 3 Trig. Pyramidal AX 3 E<br />

sp 3 d<br />

T-shaped AX 3 E 2<br />

sp 3 d<br />

Trig.Bipyramidal<br />

AX 5<br />

sp 3 d<br />

Square plannar<br />

AX 4 E 2 sp 3 d 2


www.youtube.com/watch?v=AsqEkF7hcII<br />

www.youtube.com/watch?v=tEn0N4R2dqA<br />

www.youtube.com/watch?v=Pft2CASl0M0<br />

www.youtube.com/watch?v=rwhJklbK8R0<br />

The Mole


www.youtube.com/watch?v=BTRm8PwcZ3U<br />

www.youtube.com/watch?v=F9NkYSKJifs<br />

www.youtube.com/watch?v=xPdqEX_WMjo<br />

Molar Mass


Mole Conversions


Steps for Mole Conversions


Answer the following questions:<br />

1) How many moles are in 25 grams of water?<br />

Mole Calculation Practice<br />

2) How many grams are in 4.5 moles of Li 2 O?<br />

3) How many molecules are in 23 moles of oxygen?<br />

4) How many moles are in 3.4 x 10 23 molecules of H 2 SO 4 ?<br />

5) How many molecules are in 25 grams of NH 3 ?<br />

6) How many grams are in 8.2 x 10 22 molecules of N 2 I 6 ?


7) How many grams does 0.500 moles of CuBr weigh?<br />

8) How many molecules are there in 0.655 moles of C6H14?<br />

9) How many moles are there in 2.35 x 1024 molecules of water?<br />

10) How many grams does 5.60 x 1022 molecules of SiO2 weigh?<br />

11) How many molecules are there in 21.6 grams of CH4?<br />

1) 1.39 moles<br />

2) 134.1 grams<br />

3) 1.38 x 10 25 molecules<br />

4) 0.56 moles<br />

5) 8.85 x 10 23 molecules<br />

6) 106.7 grams<br />

7) How many grams does 0.500 moles of CuBr weigh? 31.8 grams<br />

8) How many molecules are there in 0.655 moles of C 6H 14? 3.94 x 10 23 molecules<br />

9) How many moles are there in 2.35 x 10 24 molecules of water? 3.90 moles<br />

10) How many grams does 5.60 x 10 22 molecules of SiO 2 weigh? 5.59 grams<br />

11) How many molecules are there in 21.6 grams of CH 4? 8.13 x 10 23


How to Balance Chemical Equations<br />

A chemical equation is a theoretical or written representation of what happens during a chemical<br />

reaction. The law of conservation of mass states that no atoms can be created or destroyed in a<br />

chemical reaction, so the number of atoms that are present in the reactants has to balance the<br />

number of atoms that are present in the products. Follow this guide to learn how to balance chemical<br />

equations.<br />

Step 1<br />

Write down your given equation. For this example, we will use:<br />

C 3 H 8 + O 2 --> H 2 O + CO 2<br />

Step 2<br />

Write down the number of atoms that you have on each side of the equation. Look at the subscripts<br />

next to each atom to find the number of atoms in the equation.<br />

Left side: 3 carbon, 8 hydrogen and 2 oxygen<br />

Right side: 1 carbon, 2 hydrogen and 3 oxygen


Step 3<br />

Always leave hydrogen and oxygen for last. This means that you will need to balance the carbon<br />

atoms first.<br />

Step 4<br />

Add a coefficient to the single carbon atom on the right of the equation to balance it with the 3 carbon<br />

atoms on the left of the equation.<br />

C 3 H 8 + O 2 --> H 2 O + 3CO 2<br />

The coefficient 3 in front of carbon on the right side indicates 3 carbon atoms just as the subscript 3<br />

on the left side indicates 3 carbon atoms.<br />

In a chemical equation, you can change coefficients, but you should never alter the subscripts.


Step 5<br />

Balance the hydrogen atoms next. You have 8 on the left side, so you'll need 8 on the right side.<br />

C 3 H 8 + O 2 --> 4H 2 O + 3CO 2<br />

On the right side, we added a 4 as the coefficient because the subscript showed that we already<br />

had 2 hydrogen atoms.<br />

When you multiply the coefficient 4 times the subscript 2, you end up with 8.<br />

Step 6<br />

Finish by balancing the oxygen atoms.<br />

Because we've added coefficients to the molecules on the right side of the equation, the number of<br />

oxygen atoms has changed. We now have 4 oxygen atoms in the water molecule and 6 oxygen<br />

atoms in the carbon dioxide molecule. That makes a total of 10 oxygen atoms.<br />

Add a coefficient of 5 to the oxygen molecule on the left side of the equation. You now have 10<br />

oxygen molecules on each side.<br />

C 3 H 8 + 5O 2 --> 4H 2 O + 3CO 2.<br />

The carbon, hydrogen and oxygen atoms are balanced. Your equation is complete.


1) ___ NaNO 3 + ___ PbO ___ Pb(NO 3 ) 2 + ___ Na 2 O<br />

2) ___ AgI + ___ Fe 2 (CO 3 ) 3 ___ FeI 3 + ___ Ag 2 CO 3<br />

3) ___ C 2 H 4 O 2 + ___ O 2 ___ CO 2 + ___ H 2 O<br />

4) ___ ZnSO 4 + ___ Li 2 CO 3 ___ ZnCO 3 + ___ Li 2 SO 4<br />

5) ___ V 2 O 5 + ___ CaS ___ CaO + ___ V 2 S 5


6) ___ Mn(NO 2 ) 2 + ___ BeCl 2 ___ Be(NO 2 ) 2 + ___ MnCl 2<br />

7) ___ AgBr + ___ GaPO 4 ___ Ag 3 PO 4 + ___ GaBr 3<br />

8) ___ H 2 SO 4 + ___ B(OH) 3 __ B 2 (SO 4 ) 3 + ___ H 2 O<br />

9) ___ S 8 + ___ O 2 ___ SO 2<br />

10) ___ Fe + ___ AgNO 3 ___ Fe(NO 3 ) 2 + ___ Ag


1) 2 NaNO 3 + PbO Pb(NO 3 ) 2 + Na 2 O<br />

2) 6 AgI + Fe 2 (CO 3 ) 3 2 FeI 3 + 3 Ag 2 CO 3<br />

3) C 2 H 4 O 2 + 2 O 2 2 CO 2 + 2 H 2 O<br />

4) ZnSO 4 + Li 2 CO 3 ZnCO 3 + Li 2 SO 4<br />

5) V 2 O 5 + 5 CaS 5 CaO + V 2 S 5<br />

6) Mn(NO 2 ) 2 + BeCl 2 Be(NO 2 ) 2 + MnCl 2<br />

7) 3 AgBr + GaPO 4 Ag 3 PO 4 + GaBr 3<br />

8) 3 H 2 SO 4 + 2 B(OH) 3 B 2 (SO 4 ) 3 + 6 H 2 O<br />

9) S 8 + 8 O 2 8 SO 2<br />

10) Fe + 2 AgNO 3 Fe(NO 3 ) 2 + 2 Ag<br />

Additional Notes:


Categories of Reactions<br />

All chemical reactions can be placed into one of six categories. Here they are, in no<br />

particular order:<br />

1) Synthesis: A synthesis reaction is when two or more simple compounds combine to form a<br />

more complicated one. These reactions come in the general form of:<br />

A + B ---> AB<br />

One example of a synthesis reaction is the combination of iron and sulfur to form iron (II) sulfide:<br />

8 Fe + S 8 ---> 8 FeS<br />

If two elements or very simple molecules combine with each other, it’s probably a synthesis reaction.<br />

The products will probably be predictable using the octet rule to find charges.<br />

2) Decomposition: A decomposition reaction is the opposite of a synthesis reaction - a<br />

complex molecule breaks down to make simpler ones. These reactions come in the general form:<br />

AB ---> A + B<br />

One example of a decomposition reaction is the electrolysis of water to make oxygen and hydrogen<br />

gas:<br />

2 H 2O ---> 2 H 2 + O 2<br />

If one compound has an arrow coming off of it, it’s probably a decomposition reaction. The products<br />

will either be a couple of very simple molecules, or some elements, or both.<br />

3) Single displacement: This is when one element trades places with another element in a<br />

compound. These reactions come in the general form of:<br />

A + BC ---> AC + B<br />

One example of a single displacement reaction is when magnesium replaces hydrogen in water to<br />

make magnesium hydroxide and hydrogen gas:<br />

Mg + 2 H 2O ---> Mg(OH) 2 + H 2<br />

If a pure element reacts with another compound (usually, but not always, ionic), it’s probably a single<br />

displacement reaction. The products will be the compounds formed when the pure element switches<br />

places with another element in the other compound.<br />

Important note: these reactions will only occur if the pure element on the reactant side of the equation<br />

is higher on the activity series than the element it replaces.


4) Double displacement: This is when the anions and cations of two different molecules<br />

switch places, forming two entirely different compounds. These reactions are in the general form:<br />

AB + CD ---> AD + CB<br />

One example of a double displacement reaction is the reaction of lead (II) nitrate with potassium<br />

iodide to form lead (II) iodide and potassium nitrate:<br />

Pb(NO 3) 2 + 2 KI ---> PbI 2 + 2 KNO 3<br />

If two ionic compounds combine, it’s probably a double displacement reaction. Switch the cations<br />

and balance out the charges to figure out what will be made.<br />

Important note: These reactions will only occur if both reactants are soluble in water and only one<br />

product is soluble in water.<br />

5) Acid-base: This is a special kind of double displacement reaction that takes place when an<br />

acid and base react with each other. The H + ion in the acid reacts with the OH - ion in the base,<br />

causing the formation of water. Generally, the product of this reaction is some ionic salt and water:<br />

HA + BOH ---> H 2O + BA<br />

One example of an acid-base reaction is the reaction of hydrobromic acid (HBr) with sodium<br />

hydroxide:<br />

HBr + NaOH ---> NaBr + H 2O<br />

If an acid and a base combine, it’s an acid-base reaction. The products will be an ionic compound<br />

and water.<br />

6) Combustion: A combustion reaction is when oxygen combines with another compound to<br />

form water and carbon dioxide. These reactions are exothermic, meaning they produce heat. An<br />

example of this kind of reaction is the burning of napthalene:<br />

C 10H 8 + 12 O 2 ---> 10 CO 2 + 4 H 2O<br />

If something that has carbon and hydrogen reacts with oxygen, it’s probably a combustion reaction.<br />

The products will be CO 2 and H 2 O.<br />

Follow this series of questions. When you can answer "yes" to a question, then<br />

stop!<br />

1) Does your reaction have two (or more) chemicals combining to form one chemical? If yes, then it's<br />

a synthesis reaction<br />

2) Does your reaction have one large molecule falling apart to make several small ones? If yes, then<br />

it's a decomposition reaction<br />

3) Does your reaction have any molecules that contain only one element? If yes, then it's a single<br />

displacement reaction<br />

4) Does your reaction have water as one of the products? If yes, then it's an acid-base reaction<br />

5) Does your reaction have oxygen as one of it's reactants and carbon dioxide and water as<br />

products? If yes, then it's a combustion reaction<br />

6) If you haven't answered "yes" to any of the questions above, then you've got a double<br />

displacement reaction.


1) double displacement<br />

2) combustion<br />

3) single displacement<br />

4) double displacement<br />

5) acid-base<br />

6) synthesis<br />

7) decomposition<br />

List what type the following reactions are: (answers)<br />

Predicting Reaction Products – Answers<br />

Predict the products of each of the following chemical reactions. If a reaction will not occur, explain why not:<br />

1) ____ Ag 2 SO 4 + ____ NaNO 3 → no reaction!<br />

Examining this reaction, it appears that a double displacement reaction will occur. This would lead to the conclusion that<br />

the products would be AgNO3 and Na2SO4. However, for this reaction to occur, both reactants and only one of the<br />

products must be soluble in water. If you look up the solubilities on a chart, you’ll find that Ag2SO3 is partly soluble in<br />

water, and all of the other compounds are totally soluble in water. This tells us that this reaction will not occur.<br />

2) ____ NaI + ____ CaSO 4 → no reaction!<br />

Another double displacement reaction, this time with Na2SO4 and CaI2 as products. Because both products are soluble<br />

in water and CaSO4 is only partially soluble in water, the conditions for a successful double displacement reaction are not<br />

met.<br />

3) 2 HNO 3 + 1 Ca(OH) 2 → 1 Ca(NO 3 ) 2 + 2 H 2 O<br />

It’s an acid-base reaction, and acid-base reactions occur readily whether or not the reactants are both soluble in water.<br />

4) 1 CaCO 3 → 1 CaO + 1 CO 2<br />

It’s a decomposition reaction. If you didn’t guess that these were the products, you should have at least known that it was<br />

a decomposition reaction and predicted that this would have broken into its constituent elements, Ca, C, and O2.<br />

5) 1 AlCl 3 (aq) + 1 (NH 4 ) 3 PO4(aq) → AlPO 4 (s) + 3 NH 4 Cl(aq)<br />

This is a double displacement reaction, except in this case both of the reactants and only one product are soluble in<br />

water. Because the conditions for a successful reaction are met, the reaction does occur!<br />

6) ____ Pb + ____ Fe(NO 3 ) 3 →<br />

Though this is a single displacement reaction, lead is lower on the activity series than the iron it would replace. As a<br />

result, this reaction does not occur.<br />

7) 2 C 3 H 6 + 9 O 2 → 6 CO 2 + 6 H 2 O<br />

The reactants suggest that this is a combustion reaction, meaning that the products must be carbon dioxide and water.<br />

Once you figure this out, the only thing left to do is balance it, as shown.<br />

8) 2 Na + 1 CaSO 4 → 1 Na 2 SO 4 + 1 Ca<br />

This should clearly be a single displacement reaction. Because sodium is higher on the activity series than calcium, this<br />

reaction does occur.


Balancing Equations Practice Problems<br />

From Widener <strong>Chemistry</strong> Practice<br />

1 page


Stoichiometry Practice Problems<br />

From Widener <strong>Chemistry</strong> Practice<br />

2 pages


Percent Yield Practice Problems<br />

from Widener <strong>Chemistry</strong> Practice<br />

1 pages


Cody Nichols<br />

Between the particles in gas, it is empty; this allows for more<br />

movement and kinetic energy that is caused by the particles hitting<br />

each other<br />

Because of no attractive and repulsive force between them, it<br />

allows for a balance state of gas. Due to this, the particles stay in a<br />

random walk .<br />

The collisions that occur during a random walk are perfectly<br />

elastic and the kinetic energy is transferred without any lose.<br />

Gases are very small particles, but humans<br />

have learned to harness the thousands<br />

of types of gases that exists,<br />

which aid them in everyday life, like<br />

propane, nitrogen, co 2, and other gases.


The particles in liquid have kinetic<br />

energy , this makes the particles<br />

flow past each other. The flow of theses particles is<br />

referred to as a fluid.<br />

Unlike gas though, liquid particles are atattracted<br />

to each other, depending on weather the<br />

attraction is disrupted determines the physical<br />

Liquid evaporates and then turns into a vapor<br />

or a gas, then it condensates and turns back<br />

into a liquid. The vapor pressure or the force exerted<br />

by a gas above a liquid is caused by the collision<br />

of particles in a container that contains evaporated<br />

liquid.<br />

Water is the most abundant<br />

source of liquid on<br />

earth. H 2 O can take the<br />

form of all three states of<br />

matter( solid, liquid, and<br />

gases). Examples of this<br />

are Ice as a solid, regular<br />

water as a liquid , and a<br />

rain cloud.


The particles in a solid are packed tightly together, they are dense<br />

and not easy to compress.<br />

When heating a solid, the particles start to break down and at<br />

freezing point, the solid is stuck in a fixed position.<br />

There are crystal, allotropes, and non-crystalline solids, which either<br />

have simple cubic unit cells, body centered unit cells or face<br />

centered unit cells.


Changes from a solid to a gas without going through liquid is called<br />

sublimation. Solid goes through sublimation to a vapor, then the vapor goes<br />

to deposition, back to a solid. A phase diagram shows the three states and<br />

what points that they will change at, the only point where they are equal is<br />

the triple point.<br />

Learning goal<br />

The students will learn what are the factors that determine and characteristics that distinguish<br />

gases liquids and solids and how substances change from one state to another.


Boyles law: V1 + P2 = P 2 + V2<br />

rearrange the equation to isolate V2:<br />

substitute the known values for P1 V1 and P2 into the equation and solve<br />

The finished equation is<br />

V2 = P1 X V1 / P2 = 104kPa X 2.50 L/ 12.0 L = 6.48 L


http://www.youtube.com/watch?v=N5xft2fIqQU


The volume of a fixed mass of<br />

directly proportional to its Kelvin<br />

temperature if the pressure is<br />

kept constant.<br />

As temperature increases, so does<br />

the volume of the substance being<br />

exposed to the heat.


V1<br />

T1 = V2<br />

T2<br />

Cross multiply the<br />

numbers<br />

11.<br />

6.80 L<br />

325 C = X<br />

25 C = 6.80<br />

L* 25 C/ 325 C = 170<br />

L/325=0.52 L


http://www.youtube.com/watch?v=7JKVtbe-hV8


Pressure of a gas<br />

corresponds to the kelvin<br />

temperature if the volume<br />

remains constant.


you put the numbers<br />

where they need to be<br />

108/41 = / 22Cross<br />

multiple 2376/41 then<br />

divide=57.9512195,<br />

then you use the least<br />

significant figures, so<br />

the least is 2, 58


http://www.youtube.com/watch?v=gFDS3bwAU-s


Indirect: 2*3=6 3*2=6 P1 x T1 = P2 x T2<br />

Direct: 6/1=6 12/2=6 P1 / T1 = P2 / T2<br />

Combined Gas Law<br />

P1 x V1/ T1 = P2 x V2/ T2<br />

V1 = 3110 mL T1 = x V2 = 651 mL T2 = 80.60 K Indirect equation<br />

3110 / x = 651 / 80.6 3110 * 80.6 / 651 = x 250, 666 / 651 x=385 K<br />

V1 = 2600 mL P1 = x V2 = 6570 mL P2 = 1500 torr Direct equation<br />

2600x = 6570 * 1500 2600x = 985500 x = 3790 torr 3790 torr = 4.965 atm x = 5.0 atm<br />

P1 = 1320 torr V1 = x T1 = 615 C P2 = 1.28 atm V1 = 7.11 L T2 = 905 K CGL equation<br />

Conversions: T1615 C = 888 K P11320 torr = 1.7292 atm<br />

1.7292*x/888 = 1.28*7.11/9051.7292x/888=0.010051.7292x=8.9244x=5.16 L<br />

P=Pressure V=Volume T=Tempurature n=# in mol r=8.31kpq OR 0.082 atm<br />

Ideal Gas Law PxV=nrT P=nrT/V<br />

P = 1470 torr V = 7.87 L T = 712 K n = x r = 0.082 atm IGL equation<br />

Conversions: P1470 torr = 195.51<br />

195.51 = 58.384x/7.87 1538.6637=58.384x 26.354=x x = 26.4<br />

P = 1.36 atm V = 8.53 L T = 499 K n = x r = 0.082 atm<br />

1.36*8.53 = 0.082*499*x 11.6008=40.918x 0.2835 = x x = 0.284 mol


P = Pressure must be in same units<br />

V = Volume must be in same units<br />

T = Temperature must be in Kelvin<br />

Direct relationship = as the temperature increases, the volume increases<br />

V1/T1 = V2/T2<br />

P1/T1 = P2/T2<br />

Indirect relationship = as volume increases, pressure increases<br />

V1 x P1 = V2 x P2<br />

Combined Gas Law<br />

P = Pressure in atm or kPa<br />

V = Volume must be in Liters<br />

N = number of moles<br />

R = Constant either 0.082 atm OR 8.31 kPa, depending on pressure<br />

T = Tempurature in Kelvin<br />

PV = NRT<br />

Ideal Gas Law<br />

P1 = 2.27 atm V1 = 7.94 L P2 =? V2 = 10.8 L<br />

2.27 x 7.94/ 10.8 = x x = 1.67 atm 1.67 atm = 1270 torr P2 = 1270 torr<br />

V1 = 12.6 L T1 = 383 K V2 = ? T2 = 45.3 K<br />

12.6/383=x/45.3 1.49 = x V2 = 1.5 L<br />

V1 = 2.83L T1 = 832K P1 = ? V2 = 3.85L T2 = 411K P2 = 0.396 atm<br />

2.83*x / 832 = 3.85 * 0.396 / 411 x = 3.85 * 0.396 * 832 / 411 * 2.83 x = 1.09056 P1 = 1.09 atm<br />

P = 1.6 atm N = 0.433 mol T = 346 K R = 0.082 atm V = ?<br />

1.6*x = 0.433*346*0.082 x= 7.678 7.678 L = 7678 mL V = 7680 mL<br />

P1 = 0.494 atm V1 = 2230 mL T1 = ? P2 = 0.150 atm V2 = 3590 mL T2 = 279 K<br />

0.494*2230/ x = 0.15*3590 / 279 x=0.00175 T1=0.002 K


Unit 5 & 6 Test Review<br />

Heat of Fusion<br />

q = m ∙ΔH f<br />

Specific Heat<br />

c = ____q____<br />

m ∙ ΔT ᵒC<br />

Heat of Fusion of Water<br />

334 J/g = 80 cal/g<br />

Specific Heat of Water<br />

4.18 J/g ∙ᵒC<br />

Heat of fusion is the amount of heat energy required to change the state of a substance from solid to<br />

liquid. This example problem demonstrates how to calculate the amount of energy required to melt a<br />

sample of water ice.<br />

With Graham's Law, you can find the effusion rates for two gases or the molecular mass of a gas.<br />

This ratio of effusion rates follows the pattern that the gas with the lesser molecular mass has a<br />

greater rate of effusion.<br />

Ideal Gas Law<br />

Combined Gas Law<br />

p∙v=n∙R∙T V 1 ∙P 1 = V 2 ∙P 2<br />

T 1 T 2<br />

R = .082 atm or 8.31kpa<br />

Boyle’s Law<br />

P 1 ∙V 1 = P 2 ∙V 2<br />

Charles’ Law<br />

Gay – Lussac’s Law<br />

V 1 = V 2 P 1 = P 2<br />

T 1 T 2 T 1 T 2<br />

Molarity<br />

M = moles<br />

L<br />

Gas Solubility<br />

S 1 = S 2<br />

P 1 P 2


Unit 5<br />

Chapter 13 States of Matter<br />

Chapter 14 The Behavior of Gases<br />

Chapter 15 Water and Aqueous Systems<br />

Unit 6<br />

Chapter 16 Solutions<br />

Chapter 17 Thermochemistry<br />

Chapter 18 Reaction Rates and Equilibrium<br />

Chapter 19 Acid and Bases<br />

Learning Goals<br />

The students will learn what are the factors that determine and characteristics that distinguish gases<br />

liquids and solids and how substances change from one state to another.<br />

The students will learn how gases respond to changes in pressure, volume, and temperature and why<br />

the ideal gas law is useful even though ideal gases do not exist.<br />

The students will learn how the interactions between water molecules account for the unique<br />

properties of water and how aqueous solutions form.<br />

The student will learn how energy is converted in a chemical or physical process and how to<br />

determine the amount of energy is absorbed or released in that process.


#1<br />

What is the heat in Joules required to melt 25 grams of ice? What is the heat in calories?<br />

#2<br />

How much energy is released when 20 g of water is frozen at 0ᵒ C?


#3<br />

A sample of water of unknown mass undergoes a temperature change from 58.85ᵒC to 16.06 ᵒC with<br />

a concomitant change in heat content of -123200 Joules. What is the mass of the water?<br />

#4<br />

A sample of water with a mass of 597.9g and an unknown temperature loses 18890 Joules. If the<br />

final temperature is found to be 35.76ᵒC .What was the initial temperature?


#5<br />

A gas system has volume, moles and temperature of 9.76L, 0.264moles and 308.0C, respectively.<br />

What is the pressure in atm?<br />

#6<br />

A gas system has pressure, volume and temperature of 1.43atm, 6.86L and 394K, respectively. How<br />

many moles of gas are present?


#7<br />

A gas system has pressure, volume and moles of 1.44atm, 8.16L and 0.427moles, respectively. What<br />

is the temperature in K?<br />

#8<br />

What is the molarity of a solution of sodium bromide which contains 64.1 grams of solute in a total<br />

volume of 0.436L?


#9<br />

What volume in mL of a 0.942M solution of sodium bromide would be required if you wanted<br />

0.692moles of solute?<br />

#10<br />

What is the percent by mass of water in CuSO 4 ∙ 5H 2 0?

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