IMPRÄGNIERSIEGEL IS 75_ GB - Murexin

36.0.8
Safety data sheet
according to 1907/2006/EC, Article 31
Page 1/8
Printing date 19.04.2013 Version number 2
Revision: 19.04.2013
* 1 Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name IMPRÄGNIERSIEGEL IS 75
1.2 Relevant identified uses of the substance or mixture and uses advised against -
Application of the substance / the preparation Wood-preservative impregnation
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
MUREXIN AG
Franz v. Furtenbachstr. 1
A-2700 Wiener Neustadt
Tel.: +43 (0)2622/27401
Informing department: r.wachlhofer@murexin.com
1.4 Emergency telephone number:
UK National poisons Emergency number.: +44 (0) 870 600 6266
* 2 Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
Muta. 1B
Carc. 1B
GHS08 health hazard
H340 May cause genetic defects.
H350 May cause cancer.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
R10-66-67: Flammable. Repeated exposure may cause skin dryness or cracking. Vapours may
cause drowsiness and dizziness.
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification
guideline for preparations of the EU" in the latest valid version.
At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the
solvent.
Has a narcotizing effect.
Classification system:
The classification is in line with current EC lists. It is expanded, however, by information from
technical literature and by information furnished by supplier companies.
2.2 Label elements
Labelling according to EU guidelines:
The product has been classified and labelled in accordance with EC Directives.
Hazard-determining components of labelling:
2-butanone oxime
cobalt bis(2-ethylhexanoate)
Risk phrases:
10 Flammable.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
(Contd. on page 2)
GB

36.0.8
Safety data sheet
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Printing date 19.04.2013 Version number 2
Revision: 19.04.2013
Trade name IMPRÄGNIERSIEGEL IS 75
(Contd. of page 1)
Safety phrases:
2 Keep out of the reach of children.
23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the
manufacturer).
24 Avoid contact with skin.
38 In case of insufficient ventilation, wear suitable respiratory equipment.
51 Use only in well-ventilated areas.
Additional information:
EUH066 Repeated exposure may cause skin dryness or cracking.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
* 3 Composition/information on ingredients
3.2 Chemical characterization: Mixtures
Description: Mixture consisting of the following components.
Dangerous components:
CAS: 64742-48-9
EC number: 918-481-9
Reg.nr.: 01-2119457273-39-xxxx
CAS: 64742-48-9
EINECS: 265-150-3
CAS: 64742-47-8
EINECS: 265-149-8
CAS: 34590-94-8
EINECS: 252-104-2
CAS: 112-07-2
EINECS: 203-933-3
CAS: 64742-95-6
EINECS: 265-199-0
CAS: 162627-17-0
EC number: 605-296-0
N AP HT HA ( E RDÖL) , MI T W AS S ER ST O F F
BEHANDELTE SCHWERE
Xn R65
R66
Asp. Tox. 1, H304
10-25%
Naphtha (petroleum), hydrotreated heavy
5-10%
Xn R65
Flam. Liq. 3, H226
Muta. 1B, H340; Carc. 1B, H350; Asp. Tox. 1,
H304
Distillates (petroleum), hydrotreated light
2.5-5%
Xn R65
Asp. Tox. 1, H304
(2-methoxymethylethoxy)propanol
2.5-5%
substance with a Community workplace exposure limit
2-butoxyethyl acetate
< 2.5%
Xn R20/21
Acute Tox. 4, H312; Acute Tox. 4, H332
Solvent naphtha (petroleum), light arom.
0.5-1.0%
N R51/53
R66-67
Carc. Cat. 2, Muta. Cat. 2
Muta. 1B, H340; Carc. 1B, H350; Asp. Tox. 1,
H304
F e t t s ä u r e n , C 1 8 - u n g e s ä t t i g t . , D i m e r e , 0.5-1.0%
R e a k t i o n s p r o d u k t e m i t N , N - D i m e t h y l - 1 , 3 -
Propanediamin
Xi R43
Skin Sens. 1, H317
(Contd. on page 3)
GB

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Printing date 19.04.2013 Version number 2
Revision: 19.04.2013
Trade name IMPRÄGNIERSIEGEL IS 75
CAS: 136-52-7
EINECS: 205-250-6
CAS: 96-29-7
EINECS: 202-496-6
cobalt bis(2-ethylhexanoate)
Xn R22
Xi R43
Acute Tox. 4, H302; Skin Sens. 1, H317
2-butanone oxime
Xn R21-40
Xi R41
Xi R43
Carc. Cat. 3
Carc. 2, H351
Eye Dam. 1, H318
Acute Tox. 4, H312; Skin Sens. 1, H317
Additional information
For the wording of the listed risk phrases refer to section 16 "List of relevant R phrases:".
(Contd. of page 2)
0.5-1.0%
0.5-1.0%
* 4 First aid measures
4.1 Description of first aid measures
After inhalation Supply fresh air; consult doctor in case of symptoms.
After skin contact Instantly wash with water and soap and rinse thoroughly.
After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor.
After swallowing
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; instantly call for medical help.
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Firefighting measures
5.1 Extinguishing media
Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
For safety reasons unsuitable extinguishing agents Water with a full water jet.
5.2 Special hazards arising from the substance or mixture Can form explosive gas-air mixtures.
5.3 Advice for firefighters
Protective equipment: Put on breathing apparatus.
Additional information
Cool endangered containers with water spray jet.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
* 6 Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Wear protective clothing.
6.2 Environmental precautions:
Do not allow product to reach sewage system or water bodies.
Inform respective authorities in case product reaches water or sewage system.
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
6.4 Reference to other sections
See Section 7 for information on safe handling
(Contd. on page 4)
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Printing date 19.04.2013 Version number 2
Revision: 19.04.2013
Trade name IMPRÄGNIERSIEGEL IS 75
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
(Contd. of page 3)
* 7 Handling and storage
7.1 Precautions for safe handling
Keep containers tightly sealed.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Fumes can combine with air to form an explosive mixture.
Protect against electrostatic charges.
7.2 Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and containers: Store only in the original container.
Information about storage in one common storage facility:
Do not store together with oxidizing and acidic materials.
Do not store together with alkalis (caustic solutions).
Further information about storage conditions:
Store in cool, dry conditions in well sealed containers.
Keep container tightly sealed.
7.3 Specific end use(s) No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems: No further data; see item 7.
8.1 Control parameters
Components with critical values that require monitoring at the workplace:
34590-94-8 (2-methoxymethylethoxy)propanol
WEL Long-term value: 308 mg/m³, 50 ppm
Sk
112-07-2 2-butoxyethyl acetate
WEL Short-term value: 332 mg/m³, 50 ppm
Long-term value: 133 mg/m³, 20 ppm
Sk
Additional information: The lists that were valid during the compilation were used as basis.
8.2 Exposure controls
Personal protective equipment
General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or
longer exposure use breathing apparatus that is independent of circulating air.
Protection of hands: Protective gloves.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
(Contd. on page 5)
GB

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according to 1907/2006/EC, Article 31
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Printing date 19.04.2013 Version number 2
Revision: 19.04.2013
Trade name IMPRÄGNIERSIEGEL IS 75
(Contd. of page 4)
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
Eye protection: Tightly sealed safety glasses.
Body protection: Protective work clothing.
* 9 Physical and chemical properties
9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form:
Fluid
Colour:
Yellowish
Smell:
Odourless
pH-value:
Not determined.
Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Flash point: 46 °C
Ignition temperature: 200 °C
Self-inflammability:
Danger of explosion:
Density at 20 °C
Solubility in / Miscibility with
Water:
Product is not selfigniting.
Product is not explosive. However, formation of explosive air/
steam mixtures is possible.
0.9 g/cm³
immiscible
Viscosity:
kinematic at 20 °C: 33 s (DIN 53211/4)
9.2 Other information No further relevant information available.
* 10 Stability and reactivity
10.1 Reactivity
10.2 Chemical stability
Conditions to be avoided: No decomposition if used according to specifications.
10.3 Possibility of hazardous reactions No dangerous reactions known
10.4 Conditions to avoid No further relevant information available.
10.5 Incompatible materials: No further relevant information available.
10.6 Hazardous decomposition products: None
* 11 Toxicological information
11.1 Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
64742-48-9 NAPHTHA (ERDÖL), MIT WASSERSTOFF BEHANDELTE SCHWERE
Oral LD50 >2000 mg/kg (rat)
Dermal LD50 >2000 mg/kg (rabbit)
(Contd. on page 6)
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Printing date 19.04.2013 Version number 2
Revision: 19.04.2013
Trade name IMPRÄGNIERSIEGEL IS 75
(Contd. of page 5)
Primary irritant effect:
on the skin: No irritant effect.
on the eye: No irritant effect.
Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EC
Classification Guidelines for Preparations as issued in the latest version:
* 12 Ecological information
12.1 Toxicity
Aquatic toxicity:
64742-48-9 NAPHTHA (ERDÖL), MIT WASSERSTOFF BEHANDELTE SCHWERE
IC 50 >100 mg/l (Pseudokirchneriella subcapitata (Alge))
LC50 >100 mg/l (Oncorhynchus mykiss (Regenbogenforelle))
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
12.4 Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Water hazard class (Germany) 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or
sewage system.
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available.
* 13 Disposal considerations
13.1 Waste treatment methods
Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage
system.
European waste catalogue
08 01 11* waste paint and varnish containing organic solvents or other dangerous substances
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
Empty contaminated packagings thoroughly. They can be recycled after thorough and proper
cleaning.
* 14 Transport information
14.1 UN-Number
ADR, IMDG, IATA
14.2 UN proper shipping name
ADR
IMDG, IATA
UN1263
1263 PAINT
PAINT
(Contd. on page 7)
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Printing date 19.04.2013 Version number 2
Revision: 19.04.2013
Trade name IMPRÄGNIERSIEGEL IS 75
14.3 Transport hazard class(es)
ADR, IMDG, IATA
(Contd. of page 6)
Class
3 Flammable liquids.
Label 3
14.4 Packing group
ADR, IMDG, IATA
14.5 Environmental hazards:
Marine pollutant:
14.6 Special precautions for user
Warning: Flammable liquids.
Kemler Number: 30
EMS Number:
F-E,S-E
14.7 Transport in bulk according to Annex II
of MARPOL73/78 and the IBC Code
Transport/Additional information:
III
No
ADR
Limited quantities (LQ)
5L
Transport category 3
Tunnel restriction code
D/E
UN "Model Regulation":
Not applicable.
UN1263, PAINT, 3, III
* 15 Regulatory information
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
* 16 Other information
Relevant phrases
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
H340 May cause genetic defects.
H350 May cause cancer.
H351 Suspected of causing cancer.
R20/21 Harmful by inhalation and in contact with skin.
R21 Harmful in contact with skin.
R22 Harmful if swallowed.
R40 Limited evidence of a carcinogenic effect.
R41 Risk of serious damage to eyes.
R43 May cause sensitisation by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R65 Harmful: may cause lung damage if swallowed.
(Contd. on page 8)
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36.0.8
Safety data sheet
according to 1907/2006/EC, Article 31
Page 8/8
Printing date 19.04.2013 Version number 2
Revision: 19.04.2013
Trade name IMPRÄGNIERSIEGEL IS 75
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
Contact: Hr. Ing. Wachlhofer
* Data compared to the previous version altered.
(Contd. of page 7)
GB