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Earth and Plan<strong>et</strong>ary Science L<strong>et</strong>ters 227 (<strong>2004</strong>) 231–247<br />

www.elsevier.com/locate/epsl<br />

Towards an astrochronologic<strong>al</strong> framework for the eastern<br />

Parat<strong>et</strong>hys Mio–Pliocene sedimentary sequences<br />

of the FocYani basin (Romania)<br />

Iuliana <strong>Vasiliev</strong> a,b, *, Wout Krijgsman a , Cor G. Langereis a , Cristina E. Panaiotu c ,<br />

Liviu MatSenco b,d , Giovanni Bertotti d<br />

a P<strong>al</strong>eomagn<strong>et</strong>ic Laboratory dFort HoofddijkT, Utrecht University, Budapestlaan 17, 3584 CD Utrecht, The N<strong>et</strong>herlands<br />

b N<strong>et</strong>herlands Centre for Integrated Solid Earth Sciences, The N<strong>et</strong>herlands<br />

c Department of Miner<strong>al</strong>ogy, Faculty of Geology and Geophysics, Bucharest University, Bălcescu Bd. 1, 010041 Bucharest, Romania<br />

d Department of Tectonics/Structur<strong>al</strong> Geology, Vrije Universiteit Amsterdam, De Boelelaan 1085, 1081 HV Amsterdam, The N<strong>et</strong>herlands<br />

Received 10 May <strong>2004</strong>; received in revised form 4 August <strong>2004</strong>; accepted 4 September <strong>2004</strong><br />

Available online 12 October <strong>2004</strong><br />

Editor: V. Courtillot<br />

Abstract<br />

A reliable geologic<strong>al</strong> timesc<strong>al</strong>e for the Neogene sedimentary deposits of the Romanian Carpathian foredeep did not exist so<br />

far due to the lack of accurate isotopic datings and straightforward magn<strong>et</strong>ostratigraphic correlations. Here we present a new<br />

chronology for the Upper Miocene to Pliocene deposits of the westernmost part of the eastern Parat<strong>et</strong>hys based on highresolution<br />

magn<strong>et</strong>ostratigraphic data from the FocYani basin. The thick and continuous river sections of Putna (2.35 km) and<br />

Rîmnicu Sărat (7.32 km) yield excellent magn<strong>et</strong>ostratigraphic results and <strong>al</strong>low an unambiguous correlation to the polarity<br />

timesc<strong>al</strong>e for the interv<strong>al</strong> b<strong>et</strong>ween 7 and 2.5 Ma. The new age control permits the c<strong>al</strong>culation of accumulation rates for each<br />

polarity zone, which shows a significant increase at approximately 5.8–6 My. The Upper Miocene to Pliocene sedimentary<br />

rocks of the FocYani basin display cyclic <strong>al</strong>ternations of sandy units and finer interv<strong>al</strong>s. The c<strong>al</strong>culated v<strong>al</strong>ues for the average<br />

duration of the observed sedimentary cycles are very close to the average duration of precession (21.7 ky), which indicates that<br />

the sedimentary cycles from the eastern Carpathian foredeep deposits are astronomic<strong>al</strong>ly forced. We show that the usage of the<br />

unambiguous time-control offered by magn<strong>et</strong>ic polarity stratigraphy would give a more re<strong>al</strong>istic picture of the processes that<br />

have taken place in this tectonic<strong>al</strong>ly active region.<br />

D <strong>2004</strong> Elsevier B.V. All rights reserved.<br />

Keywords: eastern Parat<strong>et</strong>hys; FocYani basin; Miocene; p<strong>al</strong>aeomagn<strong>et</strong>ism; astronomic<strong>al</strong> forcing<br />

* Corresponding author. Tel.: +31 30 253 1361; fax: +31 30 253 1677.<br />

E-mail address: vasiliev@geo.uu.nl (I. <strong>Vasiliev</strong>).<br />

0012-821X/$ - see front matter D <strong>2004</strong> Elsevier B.V. All rights reserved.<br />

doi:10.1016/j.epsl.<strong>2004</strong>.09.012


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1. Introduction<br />

During the Mesozoic and early Cenozoic, the<br />

Eurasian and African continents were separated by a<br />

large oceanic basin c<strong>al</strong>led the T<strong>et</strong>hys. Glob<strong>al</strong> plate<br />

tectonic processes caused a northward motion of the<br />

African plate with respect to Eurasia and led to<br />

continent<strong>al</strong> collision and the gradu<strong>al</strong> closure of the<br />

T<strong>et</strong>hys Ocean. These tectonic movements generated<br />

the elevation of the Alpine–Him<strong>al</strong>ayan mountain belt,<br />

which started to act as an E–W striking barrier since<br />

the beginning of the Oligocene. Consequently, the<br />

T<strong>et</strong>hys Ocean evolved into two different domains, the<br />

Mediterranean basin to the south and the Parat<strong>et</strong>hys to<br />

the north (Fig. 1). The Mediterranean remained an<br />

open marine basin because the connection to the<br />

Atlantic [1] guaranteed the exchange of water masses<br />

and organisms, permitting a direct biostratigraphic<br />

correlation to the world’s oceanic record. The Parat<strong>et</strong>hys<br />

became semi-isolated with brackish to fresh<br />

water environments that led to the development of<br />

endemic faunas and different biozonations. In addition,<br />

ongoing tectonics caused a fragmentation of the<br />

Parat<strong>et</strong>hys into various subbasins, which were<br />

affected by a continuous changing of the water<br />

surface extent and of the water connections b<strong>et</strong>ween<br />

subbasins (Fig. 1) and the Mediterranean and Indian<br />

Ocean.<br />

The Parat<strong>et</strong>hys region is divided into a western and<br />

eastern Parat<strong>et</strong>hys, which are separated from each<br />

other by the Carpathian mountain range [2,3]. The<br />

western Parat<strong>et</strong>hys formed in the back (to the north<br />

and west) of the Alpine–Carpathian belt and comprises<br />

the Pannonian and Transylvanian basins (Austria,<br />

Hungary and NW Romania). The eastern<br />

Parat<strong>et</strong>hys developed in the Alpine–Carpathian foredeep<br />

and consists of the Dacian, Euxinian and<br />

Caspian basins (SE Romania, Moldavia, Ukraine,<br />

SW Russia). The Black Sea and the Caspian Sea are<br />

the actu<strong>al</strong> brackish water remains of this ancient water<br />

mass.<br />

Chronostratigraphic control for the fresh to<br />

brackish water deposits of the Parat<strong>et</strong>hys domain is<br />

gener<strong>al</strong>ly poor and largely based on biostratigraphic<br />

data from endemic molluscs and ostracods. The<br />

complex p<strong>al</strong>eogeographic configuration of the region<br />

resulted in the development of different biozonations<br />

and different chronostratigraphic stages for the<br />

various subbasins [2,4–8] (Fig. 2). Correlations of<br />

the Parat<strong>et</strong>hys stages to the marine biochronologies<br />

of the Mediterranean and glob<strong>al</strong> oceans are gener<strong>al</strong>ly<br />

impossible because of the semi-isolated position and<br />

the lack of water exchange. In addition, the politic<strong>al</strong><br />

situation before 1990 did not facilitate communication<br />

b<strong>et</strong>ween scientists of the various Parat<strong>et</strong>hys<br />

countries.<br />

Fig. 1. Schematic p<strong>al</strong>eogeographic map of the late Miocene, showing the Parat<strong>et</strong>hys area (darker gray), the Mediterranean (lighter gray) and the<br />

present-day land contribution. The gateways (dashed) are drawn according to Krijgsman [1].


I. <strong>Vasiliev</strong> <strong>et</strong> <strong>al</strong>. / Earth and Plan<strong>et</strong>ary Science L<strong>et</strong>ters 227 (<strong>2004</strong>) 231–247 233<br />

Fig. 2. Eastern Parat<strong>et</strong>hys timesc<strong>al</strong>es constructed by different authors. Dashed lines show the highly varying limits of the Pontian.<br />

Radiom<strong>et</strong>ric datings of the eastern Parat<strong>et</strong>hys<br />

sequences are very rare [9] and magn<strong>et</strong>ostratigraphic<br />

studies are mainly applied to sm<strong>al</strong>l, scattered outcrops,<br />

gener<strong>al</strong>ly focusing on the youngest Plio–<br />

Pleistocene deposits [4,5,10–12]. Consequently, the<br />

Neogene chronology of the eastern Parat<strong>et</strong>hys is<br />

poorly defined. Ages of stages can easily vary by<br />

more than 1 or 2 million years b<strong>et</strong>ween different<br />

basins and different studies (Fig. 2). A good example<br />

is the Pontian Stage for which estimates of the<br />

duration vary from 3.0 My [5] to 0.3 My [7].<br />

Evidently, such uncertainties and differences in age<br />

dating will have serious consequences for studies that<br />

use these ages to establish the timing of different<br />

tectonic and climatic events or to c<strong>al</strong>culate accumulation<br />

and subsidence rates (e.g. [13–15]).<br />

The objective of this work is to establish a d<strong>et</strong>ailed<br />

geochronologic<strong>al</strong> framework for the Upper Miocene–<br />

Pliocene sedimentary deposits of the Romanian segment<br />

of the Carpathian foredeep (Fig. 3). From a<br />

p<strong>al</strong>eogeographic<strong>al</strong> viewpoint, the study area is known<br />

as the Dacian basin (Fig. 1) and represents the<br />

westernmost part of the eastern Parat<strong>et</strong>hys (Fig. 3a).<br />

We have selected the sedimentary sequences of the<br />

FocYani basin for a magn<strong>et</strong>ostratigraphic study,<br />

because the Mio–Pliocene units of this basin are very<br />

thick (N7 km) and continuously exposed <strong>al</strong>ong sever<strong>al</strong><br />

river v<strong>al</strong>leys. In addition, the Upper Neogene deposits<br />

of the east Carpathian foredeep express a distinct<br />

sedimentary cyclicity of <strong>al</strong>ternating siltstones/clays<br />

and sands. The regularity of the sandy interc<strong>al</strong>ations<br />

strongly suggests a relation with region<strong>al</strong> climate<br />

changes induced by the orbit<strong>al</strong> variations of the Earth.<br />

Consequently, these deposits could be very suitable to<br />

establish an astronomic<strong>al</strong> polarity timesc<strong>al</strong>e (APTS)<br />

for the sedimentary sequence of the eastern Parat<strong>et</strong>hys,<br />

<strong>al</strong>lowing d<strong>et</strong>ailed correlations to the Mediterranean<br />

marine and continent<strong>al</strong> record, for which such<br />

a timesc<strong>al</strong>e has <strong>al</strong>ready been developed [16].<br />

2. Geologic<strong>al</strong> s<strong>et</strong>ting and sections<br />

The Carpathians consist of two radi<strong>al</strong>ly directed<br />

fold and thrust belts: (1) an inner belt formed by<br />

Cr<strong>et</strong>aceous to early P<strong>al</strong>eogene thrusting, and (2) an


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I. <strong>Vasiliev</strong> <strong>et</strong> <strong>al</strong>. / Earth and Plan<strong>et</strong>ary Science L<strong>et</strong>ters 227 (<strong>2004</strong>) 231–247<br />

Fig. 3. (a) Location of the studied area in the Romanian Carpathians (in the rectangle); (b) d<strong>et</strong>ailed map of eastern Carpathians foredeep<br />

(including the most part of the FocYani basin) showing the location of the sampled sections (thicker lines); the dark-gray, bend-like successions<br />

are the sampled stages (Sarmatian, Meotian, Pontian, Dacian and Romanian); (c) Transect across Putna V<strong>al</strong>ley illustrating the geologic<strong>al</strong><br />

contacts within the studied area.<br />

outer belt that is the result of Neogene thrusting [17].<br />

The age of the last nappe emplacement in the<br />

Carpathians is considered to be intra-Sarmatian<br />

[18,19]. The FocYani area, located in front of the<br />

bended part of the southeast Carpathians (Fig. 3a),<br />

represents the main sedimentary basin of the Carpathian<br />

foredeep and contains more than 10 km [15] of<br />

Upper Miocene and Quaternary deposits. It is superimposed<br />

on the most rapidly subsiding and seismic<strong>al</strong>ly<br />

active area in Romania, which shows<br />

earthquakes up to 7.2 in magnitude [17,20]. Late<br />

Miocene to Quaternary basin evolution studies demonstrate<br />

that large-sc<strong>al</strong>e subsidence occurred in front<br />

of the SE Carpathians, culminating in significant<br />

differenti<strong>al</strong> vertic<strong>al</strong> motions <strong>al</strong>ong and across the arc<br />

during the later stages [21]. Active subduction in the<br />

Carpathian region ceased approximately 9 My ago<br />

[22], but the fin<strong>al</strong> phase of subduction and d<strong>et</strong>achment<br />

of oceanic lithosphere still produces seismicity and<br />

subsidence.<br />

The Miocene to Pliocene sedimentary sequences of<br />

the FocYani basin consist of cyclic <strong>al</strong>ternations of


I. <strong>Vasiliev</strong> <strong>et</strong> <strong>al</strong>. / Earth and Plan<strong>et</strong>ary Science L<strong>et</strong>ters 227 (<strong>2004</strong>) 231–247 235<br />

well-cemented coarse-grained rocks (sandstones and<br />

microconglomerates) and fine-grained rocks (siltstones<br />

and sh<strong>al</strong>es), which have been deposited in a<br />

lacustrine to deltaic environment. The cyclic pattern is<br />

constant for sever<strong>al</strong> kilom<strong>et</strong>ers, as can be observed in<br />

the various river incisions that cut through the tilted<br />

strata. A coarsening of the deposits and a decrease in<br />

faun<strong>al</strong> content take place from the south towards the<br />

northern part of the FocYani basin [23]. The sandy<br />

units are gener<strong>al</strong>ly regularly spaced, mostly well<br />

cemented, and show som<strong>et</strong>imes sm<strong>al</strong>l erosion<strong>al</strong><br />

surfaces at the base of channel and bar structures.<br />

Clays, marls or silts fill the space b<strong>et</strong>ween these<br />

sandstones. For our p<strong>al</strong>eomagn<strong>et</strong>ic study, we selected<br />

the sections <strong>al</strong>ong the Putna and Rîmnicu Sărat rivers<br />

that are located on the western flank of the FocYani<br />

basin, where the strata are tilted up to the vertic<strong>al</strong> (Fig.<br />

3c). The composite of these sections covers the time<br />

span from late Sarmatian to late Romanian (Upper<br />

Miocene to Pliocene).<br />

A tot<strong>al</strong> number of 326 levels were sampled from<br />

the 2.35 km thick Putna section. The section starts<br />

stratigraphic<strong>al</strong>ly above the main Sarmatian thrust<br />

contact in the first Upper Sarmatian deposits and it<br />

ends at the top of the Pontian (or base of Dacian)<br />

deposits. Throughout the entire Putna section, the<br />

layers have a subvertic<strong>al</strong> bedding dip varying b<strong>et</strong>ween<br />

958 and 858. The Upper Sarmatian part contains<br />

relatively coarse materi<strong>al</strong>, with strongly cemented<br />

sandstones, som<strong>et</strong>imes with a fine conglomeratic<br />

base. Silty units separate the sandstones and are<br />

usu<strong>al</strong>ly laminated and friable. A reddish interv<strong>al</strong> with<br />

p<strong>al</strong>eosols (at approximately 175 m) indicates occasion<strong>al</strong><br />

subaeri<strong>al</strong> exposure of the deposits. At approximately<br />

480 m, there is a non-exposed gap in the<br />

section, which coincides with a change in strike of<br />

approximately 128. There is not any known or visible<br />

fault in this non-exposed part of the section. The<br />

Meotian and Pontian part is less coarse and the sandy<br />

units are often less cemented.<br />

From the 7.32 km thick Rîmnicu Sărat section, 396<br />

levels were sampled. The section starts in the Upper<br />

Sarmatian and ends in the Upper Romanian. The<br />

Sarmatian part is not very well exposed but the<br />

Meotian, Pontian, Dacian and Romanian have very<br />

good exposure. The sedimentary bedding shows a dip<br />

of approximately 908 in the lower part of the section,<br />

but goes progressively to a minimum of 208 in the<br />

upper part. The sedimentary deposits from Rîmnicu<br />

Sărat are less coarse than in the Putna section,<br />

suggesting that they were deposited in a more dist<strong>al</strong><br />

part of the deltaic system, where the basin energy was<br />

lower.<br />

Standard p<strong>al</strong>eomagn<strong>et</strong>ic cores were taken with an<br />

electric<strong>al</strong> drill and a generator as power supply. At<br />

each level, we took at least two standard-oriented<br />

cores. Addition<strong>al</strong> samples have been collected for<br />

future biostratigraphic, sedimentologic<strong>al</strong> and geochemic<strong>al</strong><br />

purposes.<br />

3. P<strong>al</strong>eomagn<strong>et</strong>ic results<br />

3.1. M<strong>et</strong>hods<br />

To establish a magn<strong>et</strong>ostratigraphy for the Putna<br />

and Rîmnicu Sărat sections, at least one specimen<br />

per sample layer was stepwise therm<strong>al</strong>ly demagn<strong>et</strong>ized.<br />

The demagn<strong>et</strong>isation was performed with sm<strong>al</strong>l<br />

temperature increments of 20–30 8C up to a<br />

maximum temperature of 620 8C, in a magn<strong>et</strong>ic<strong>al</strong>ly<br />

shielded, laboratory-built, furnace. The natur<strong>al</strong> remanent<br />

magn<strong>et</strong>isation (NRM) was measured on a<br />

horizont<strong>al</strong> 2G Enterprises DC SQUID cryogenic<br />

magn<strong>et</strong>om<strong>et</strong>er (noise level 310 12 Am 2 ). The<br />

directions of the NRM components were c<strong>al</strong>culated<br />

by princip<strong>al</strong> component an<strong>al</strong>ysis [24]. The large dip<br />

(mostly b<strong>et</strong>ween 658 and 908) of the layers was<br />

helpful to distinguish b<strong>et</strong>ween primary and secondary<br />

components and to recognize a present-day<br />

overprint.<br />

Furthermore, sever<strong>al</strong> rock magn<strong>et</strong>ic experiments<br />

were performed to identify the carriers of the magn<strong>et</strong>isation.<br />

Thermomagn<strong>et</strong>ic measurements were performed<br />

in air up to 700 8C for 36 powdered samples<br />

from diverse lithologies on a modified horizont<strong>al</strong><br />

translation type Curie b<strong>al</strong>ance (noise level 510 9 A<br />

m 2 ). The initi<strong>al</strong> susceptibility and the anisotropy were<br />

measured on a Kappabridge KLY-2 or KLY-3.<br />

Hysteresis loops were measured for 35 samples of<br />

selected lithologies on an <strong>al</strong>ternating gradient magn<strong>et</strong>om<strong>et</strong>er<br />

(MicroMag Model, Princ<strong>et</strong>on, noise level<br />

210 8 Am 2 ) to d<strong>et</strong>ermine the saturation magn<strong>et</strong>isation<br />

(Ms), remanent saturation (Msr), coercive<br />

force (Bc) and remanent coercivity (Bcr). First-order<br />

revers<strong>al</strong> curves (FORC) [25,26] were measured for 33


236<br />

I. <strong>Vasiliev</strong> <strong>et</strong> <strong>al</strong>. / Earth and Plan<strong>et</strong>ary Science L<strong>et</strong>ters 227 (<strong>2004</strong>) 231–247<br />

samples to ev<strong>al</strong>uate the magn<strong>et</strong>ic domain situation, the<br />

presence of magn<strong>et</strong>ic interactions and the magn<strong>et</strong>ic<br />

miner<strong>al</strong>ogy. For each FORC diagram, 150 curves<br />

were measured with an averaging time of 0.2 s per<br />

data point.<br />

3.2. Therm<strong>al</strong> demagn<strong>et</strong>isation and rock magn<strong>et</strong>ism<br />

Therm<strong>al</strong> demagn<strong>et</strong>isation diagrams show different<br />

types of magn<strong>et</strong>ic behaviour that have a clear<br />

relationship with lithology. Clays and silts gener<strong>al</strong>ly<br />

provide good qu<strong>al</strong>ity diagrams. Sandstones commonly<br />

provide poor qu<strong>al</strong>ity demagn<strong>et</strong>isation diagrams (even<br />

though magn<strong>et</strong>ic intensity is gener<strong>al</strong>ly high). Based on<br />

rock magn<strong>et</strong>ic results, we divided the samples into<br />

two major groups.<br />

Iron oxide group (1) type of magn<strong>et</strong>ic behavior is<br />

typic<strong>al</strong> for the clays and most of the silts (Fig.<br />

4a,c,e,f), but it may <strong>al</strong>so occur in the sandstones. The<br />

iron oxide group of samples characterizes the entire<br />

Putna section. Only a part of the Rîmnicu Sărat V<strong>al</strong>ley<br />

samples record this behaviour and are typic<strong>al</strong>ly found<br />

in the oldest and coarser (Sarmatian) part of the<br />

section.<br />

Fig. 4. Therm<strong>al</strong> demagn<strong>et</strong>isation diagrams. Closed (open) symbols represent the projection of the vector end-points on the horizont<strong>al</strong> (vertic<strong>al</strong>)<br />

plane; v<strong>al</strong>ues represent temperature in 8C; stratigraphic levels are in the lower left-hand corner; lithologies are in the right-hand corner. The lefthand<br />

side diagrams of figures a, b, c and d are represented without tectonic correction (th/no tc). The right-hand side diagrams of figures a, b, c<br />

and d and figures e, f, g and g are represented with tectonic correction (th/tc). The direction of the present-day overprint (pdf) represented with<br />

arrows in figure a.


I. <strong>Vasiliev</strong> <strong>et</strong> <strong>al</strong>. / Earth and Plan<strong>et</strong>ary Science L<strong>et</strong>ters 227 (<strong>2004</strong>) 231–247 237<br />

The initi<strong>al</strong> intensities of the NRM are in the range<br />

10–300 mA/m and susceptibilities 0.14–2010 3 SI.<br />

Most of the samples show no significant change in<br />

susceptibility during the heating treatment. Therm<strong>al</strong><br />

demagn<strong>et</strong>isation diagrams illustrate that, in most<br />

cases, a large secondary present-day field component<br />

is removed at temperatures varying b<strong>et</strong>ween 240 and<br />

380 8C (Fig. 4a). Another proportion of the samples<br />

shows the remov<strong>al</strong> of the present-day overprint after<br />

heating at only 100 8C. Taking into consideration the<br />

maximum temperature up to which the NRM was<br />

preserved, this group can be subdivided in two<br />

subgroups:<br />

Subgroup 1A (magn<strong>et</strong>ite) is characterized by<br />

samples of which susceptibility decreases continuously,<br />

without any visible increase upon heating to the<br />

highest temperatures (585 8C). The therm<strong>al</strong> demagn<strong>et</strong>isation<br />

diagrams of this subgroup are characterized by<br />

linear decay of the NRM to temperatures of 585 8C.<br />

The Curie b<strong>al</strong>ance measurements reve<strong>al</strong> that the<br />

dominant magn<strong>et</strong>ic carrier for this group of samples<br />

is a miner<strong>al</strong> with a maximum unblocking temperature<br />

(Tb) in the range 540–580 8C, close to the Curie<br />

temperature (Tc) of magn<strong>et</strong>ite (Fig. 5a). The lowering<br />

of the Tc can be induced by enrichment in titanium or<br />

some other type of impurities. The hysteresis curves,<br />

up to fields of 1.6 T, are closed well below 150 mT<br />

(Fig. 6a), and confirm the presence of a low coercivity<br />

miner<strong>al</strong> like magn<strong>et</strong>ite. The FORC diagrams (Fig. 7a)<br />

furthermore infer an interacting multi-domain (MD)<br />

state of the magn<strong>et</strong>ic miner<strong>al</strong>s [25,26].<br />

Subgroup 1B (magn<strong>et</strong>ite–hematite). The hysteresis<br />

loops acquired for this subgroup are not closed in<br />

fields of 300 mT (they are saturated at approximately<br />

800 mT) and indicate the presence of a highcoercivity<br />

miner<strong>al</strong> (Fig. 6b). The unblocking temperature<br />

(Tb) observed in thermomagn<strong>et</strong>ic runs on the<br />

Curie b<strong>al</strong>ance is approximately 650 8C. The demagn<strong>et</strong>isation<br />

diagrams combined with the hysteresis loop<br />

interpr<strong>et</strong>ations (Fig. 6b) indicate that the high coercivity<br />

miner<strong>al</strong> with Tb around 650 8C is hematite. The<br />

magn<strong>et</strong>ite–hematite type magn<strong>et</strong>isation is limited to<br />

the 28 m containing p<strong>al</strong>eosol levels from the<br />

Sarmatian/Meotian part of the Putna section, where<br />

the red-orange color of the samples indeed indicates<br />

the existence of hematite in the sediment.<br />

Iron sulphide group (2) characterizes the largest<br />

(and younger) part of the Rîmnicu Sărat samples.<br />

Fig. 5. Representative thermomagn<strong>et</strong>ic runs for samples: (a) iron<br />

oxide group; (b) iron sulphide group. The measurements have been<br />

performed in air on a modified horizont<strong>al</strong> translation-type Curie<br />

b<strong>al</strong>ance. Heating (solid line) and cooling (dashed line) were<br />

performed with rates of 10 8C/min. The cycling field varied<br />

b<strong>et</strong>ween 150 and 300 mT.<br />

Also, in the younger (Pontian) part of Putna are<br />

sever<strong>al</strong> levels where the iron sulphide type occurs<br />

(Fig. 4b,d,g,h).<br />

This group of magn<strong>et</strong>ic behavior is characterized<br />

by the dominance of a higher coercivity miner<strong>al</strong> with<br />

maximum unblocking temperature in the range 320–<br />

340 8C (Fig. 5b). The therm<strong>al</strong> demagn<strong>et</strong>isation<br />

diagrams are described by linear decay of the NRM<br />

to the same temperature of 320–340 8C. The samples<br />

record an important increase of susceptibility after<br />

heating above 330–390 8C, indicating the result of<br />

oxidation of an iron sulphide. The initi<strong>al</strong> intensities of<br />

these samples vary, in gener<strong>al</strong>, b<strong>et</strong>ween 3 and 40 mA/<br />

m and susceptibilities range 0.055–2.16510 3 SI.<br />

Therm<strong>al</strong> demagn<strong>et</strong>isation diagrams show that in most<br />

of the samples a low temperature component is


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90 mT (Fig. 7b). The hysteresis loops recorded for<br />

this group have a rectangular shape (Fig. 6c), which is<br />

characteristic for pyrrhotite [27]. Using the biplot of<br />

SIRM/m versus remanent acquisition coercivity for<br />

magn<strong>et</strong>ic miner<strong>al</strong>s, we observed that <strong>al</strong>l the an<strong>al</strong>yzed<br />

samples from this group fit perfectly in the pyrrhotite<br />

area [28]. An identic<strong>al</strong> conclusion was reached by<br />

plotting the results of the same samples on the biplot<br />

of M RS /M S versus (Bo) C /(Bo) CR [28].<br />

3.3. Magn<strong>et</strong>ostratigraphy<br />

Fig. 6. Hysteresis curves for characteristic samples. (a) PU 025,<br />

magn<strong>et</strong>ite subgroup; (b) PU 038, magn<strong>et</strong>ite–Hematite subgroup; (c)<br />

RR 104, iron sulphide group. Curves were measured for<br />

2TVBV2T. The larger (sm<strong>al</strong>ler) figures present the results up to<br />

F300 mT (F1600 mT) with applied paramagn<strong>et</strong>ic contribution and<br />

mass corrections.<br />

removed at temperatures of 100–180 8C (Fig.<br />

4b,d,g,h). In about 20% of the samples, there is<br />

(virtu<strong>al</strong>ly) no low temperature overprint component<br />

(Fig. 4h). Some of the samples record a low temperature<br />

secondary component of reversed polarity (Fig.<br />

4b). Curie b<strong>al</strong>ance measurements of samples from<br />

group 2 show invariably an increase of tot<strong>al</strong> magn<strong>et</strong>isation<br />

after heating to 420 8C (or even after 290 8C)<br />

(Fig. 5b). This behavior may indicate the oxidation of<br />

an iron sulphide. The FORC diagrams show in the<br />

majority of these cases the strongly interacting single<br />

domain (SD) state with a B C varying b<strong>et</strong>ween 45 and<br />

In the Sarmatian and the lower Meotian segment of<br />

the Putna section, the occurrence of overprinted<br />

samples is higher than in the rest of the section. This<br />

is probably caused by the dominance of coarser<br />

sandy–silty sequences in this interv<strong>al</strong> and the relative<br />

lack of finer sediments capable of r<strong>et</strong>aining a b<strong>et</strong>ter<br />

magn<strong>et</strong>ic sign<strong>al</strong>. Nevertheless, sufficient samples with<br />

a good sign<strong>al</strong> <strong>al</strong>low a convincing interpr<strong>et</strong>ation of the<br />

over<strong>al</strong>l polarity in this part of the section. Typic<strong>al</strong>ly,<br />

the occurrence of a present-day overprint is rare in the<br />

Rîmnicu Sărat section and is only associated with<br />

yellowish, coarser materi<strong>al</strong>. In both sections, some<br />

coarser-grained rocks show viscous scattering of the<br />

NRM component. We include the present-day overprint<br />

and viscous NRM types in the category of<br />

unreliable directions. In some levels, in the vicinity of<br />

a polarity revers<strong>al</strong>, the antipod<strong>al</strong> magn<strong>et</strong>isation of two<br />

different components could be observed (Fig. 4b). We<br />

believe that in these cases early diagen<strong>et</strong>ic processes<br />

cause a delayed acquisition and a (parti<strong>al</strong>) overprint of<br />

the origin<strong>al</strong> (earlier acquired) component [29,30].<br />

Hence, the direction of the following (younger)<br />

polarity interv<strong>al</strong> will overprint the origin<strong>al</strong> direction<br />

of the studied level. For this reason, it was very<br />

important to separate the low and high temperature<br />

components.<br />

The magn<strong>et</strong>isation for the iron sulphide group,<br />

most probably, was acquired during early diagenesis<br />

of the sediments [31]. The acquisition of the magn<strong>et</strong>isation<br />

for hematite is uncertain [29]. The contribution<br />

of the magn<strong>et</strong>ite–hematite type of magn<strong>et</strong>isation to the<br />

tot<strong>al</strong> amount of samples is less than 2%. The hematite<br />

contribution to the tot<strong>al</strong> magn<strong>et</strong>isation is very sm<strong>al</strong>l<br />

and the directions are the same as of the magn<strong>et</strong>ite<br />

(the main magn<strong>et</strong>ic miner<strong>al</strong> in that samples). Most<br />

likely, the occurrence of hematite in our sections


I. <strong>Vasiliev</strong> <strong>et</strong> <strong>al</strong>. / Earth and Plan<strong>et</strong>ary Science L<strong>et</strong>ters 227 (<strong>2004</strong>) 231–247 239<br />

Fig. 7. Representative FORC diagrams. (a) Iron oxide group, Sarmatian, silty sediment, smoothing factor (SF)=3, 10 contours, MD with low<br />

coercivity and peak position ~15 mT. (b) Iron sulphide group, Romanian, gray clay, SF=3, 10 contours, particle–particle interacting SD with<br />

higher coercivity and peak position ~95 mT. See Materi<strong>al</strong>s and m<strong>et</strong>hods for measuring s<strong>et</strong>tings.<br />

suggests a magn<strong>et</strong>isation acquired during or soon after<br />

deposition.<br />

Based on the results of rock magn<strong>et</strong>ic an<strong>al</strong>yses,<br />

the ChRM component can be reliably d<strong>et</strong>ermined in<br />

the demagn<strong>et</strong>isation diagrams of both groups 1 and<br />

2. Both norm<strong>al</strong> and reversed components are<br />

reve<strong>al</strong>ed in both sections, which suggest a primary<br />

origin of the magn<strong>et</strong>ic components. Due to the large<br />

dip of the strata, the viscous secondary magn<strong>et</strong>isations<br />

(Fig. 4a,b) can easily be distinguished from<br />

what we interpr<strong>et</strong> as the characteristic remanent<br />

magn<strong>et</strong>isation (ChRM), which is here the component<br />

acquired before tilting [32]. The consistent directions<br />

after (variable) tilt corrections and the results of the<br />

rock magn<strong>et</strong>ic an<strong>al</strong>yses warrant the conclusion that<br />

the ChRM is the origin<strong>al</strong> NRM acquired during<br />

deposition.<br />

The ChRM directions and polarity zones of the<br />

Putna section (Fig. 8) reve<strong>al</strong> 16 polarity revers<strong>al</strong>s: 8<br />

norm<strong>al</strong> and 8 reversed interv<strong>al</strong>s. The Rîmnicu Sărat<br />

section (Fig. 9) recorded at least 17 revers<strong>al</strong>s with 8<br />

norm<strong>al</strong> and 9 reversed polarity interv<strong>al</strong>s. Some<br />

revers<strong>al</strong> boundaries are not exactly d<strong>et</strong>ermined<br />

because of non-exposed interv<strong>al</strong>s, but the long and<br />

clear polarity patterns <strong>al</strong>low an excellent correlation to<br />

the APTS.<br />

4. Correlation to the APTS<br />

We used the most recent APTS [16] to establish the<br />

magn<strong>et</strong>ostratigraphic correlation of our sections. The<br />

most striking polarity pattern in the overlap interv<strong>al</strong><br />

b<strong>et</strong>ween the Putna (Fig. 8) andRîmnicu Sărat (Fig. 9)<br />

sections concerns the two relatively short norm<strong>al</strong><br />

polarity zones in the Meotian, which are followed by a<br />

very long reversed zone in the Pontian (Fig. 10). The<br />

lengths of these polarity zones are in excellent<br />

agreement b<strong>et</strong>ween the two sections. This characteristic<br />

pattern suggests a correlation to the interv<strong>al</strong> in the<br />

timesc<strong>al</strong>e comprising subchrons C3An.2n, C3An.1r,<br />

C3An.1n and C3r, covering the time span b<strong>et</strong>ween 6.7<br />

and 5.2 Ma (Fig. 10). Upwards, this sequence is<br />

followed in Rîmnicu Sărat by an interv<strong>al</strong> of four short<br />

norm<strong>al</strong> zones (and three short reversed zones) until<br />

another very long reversed zone is found. The four<br />

norm<strong>al</strong> interv<strong>al</strong>s correlate very well with the four C3n<br />

subchrons (Thvera, Sidufj<strong>al</strong>l, Nunivak and Cochiti) of<br />

the reversed Gilbert Chron. The uppermost part of the<br />

Rîmnicu Sărat section then probably comprises the<br />

Gauss Chron with norm<strong>al</strong> subchrons C2An.3n and<br />

C2An.1n. The absence of the subchron C2An.2n in<br />

the Rîmnicu Sărat magn<strong>et</strong>ostratigraphic record can be<br />

explained by the lack of exposure in the interv<strong>al</strong>


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b<strong>et</strong>ween 5500 and 6100 m. The correlation of the<br />

polarity record of the lowermost part of the Putna<br />

section, below the gap coinciding with the 128 change<br />

in strike, is far from straightforward. The two most<br />

likely correlations of the relatively long norm<strong>al</strong><br />

interv<strong>al</strong> are to C4n.2n or C4An (Fig. 10). Apparently,<br />

the change in strike is related to some serious<br />

deformation and/or possibly to a significant hiatus in<br />

the sequence.<br />

By plotting the stratigraphic thickness versus the<br />

c<strong>al</strong>ibrated APTS ages (ins<strong>et</strong> in Fig. 10), we observe<br />

that the accumulation rate records two clearly distinct<br />

trends, each having a nearly constant slope. The mean<br />

accumulation rate is 60 cm/ky for most of the<br />

Meotian. The accumulation rate increases more than<br />

two times (150 cm/ky) for the Pontian–Romanian<br />

interv<strong>al</strong>.<br />

5. Discussion<br />

5.1. Astronomic<strong>al</strong> forcing of sedimentary cyclicity<br />

Astronomic<strong>al</strong> forcing of the sedimentary cycles can<br />

be demonstrated by an<strong>al</strong>yzing the average duration of<br />

a cycle. When the average period of the cycles in the<br />

time domain is constant and identic<strong>al</strong> to one of the<br />

known Milankovitch periods, astronomic<strong>al</strong> forcing is<br />

the most probable cause. Knowing the average<br />

sedimentation rate (per polarity zone) and the mean<br />

cycle thickness for specific interv<strong>al</strong>s the average<br />

periodicity of the sedimentary cyclicity can be<br />

estimated. For such a demonstration, we have selected<br />

those interv<strong>al</strong>s of the Putna and Rîmnicu Sărat<br />

Fig. 8. Polarity zones and lithologic<strong>al</strong> column of Putna V<strong>al</strong>ley<br />

section. In the polarity column, black and white denote the norm<strong>al</strong><br />

and reversed polarity interv<strong>al</strong>s, respectively. Solid dots represent<br />

reliable direction of demagn<strong>et</strong>isation diagrams. Open circles<br />

represent the unreliable directions corresponding to the presentday<br />

directions and scattered (viscous NRM) demagn<strong>et</strong>isation<br />

diagrams. The black sign<strong>al</strong> line connects only the straightforward<br />

(solid dots) directions. The lithologic<strong>al</strong> column displays variations<br />

of clayey and silty parts (the different tones of darker gray with a<br />

sm<strong>al</strong>ler width) and sandy units (the lighter gray and larger width).<br />

The stratigraphic level is in m<strong>et</strong>ers. Next to the lithologic<strong>al</strong> column<br />

are represented the levels of limits b<strong>et</strong>ween different stages<br />

according to the 29 Covasna, 1:200000 sc<strong>al</strong>e map [38]. The authors<br />

of the map had assigned the stage boundaries from the work of<br />

Saulea [36], Ciocîrdel [35] and IonitSă [37].


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sections where the cyclicity is regular and well<br />

developed.<br />

Sedimentary cyclicity is very distinct in the Pontian<br />

of the Putna section (Fig. 11a). The average sediment<br />

accumulation rate during the correlative reversed<br />

polarity interv<strong>al</strong> of C3r is 137 cm/ky. The average<br />

thickness of the sedimentary cycles is 31.1 m, which<br />

results in a periodicity of 22.7 ky. The Meotian part of<br />

the Putna section <strong>al</strong>so displays a clear sedimentary<br />

cyclicity, especi<strong>al</strong>ly in the interv<strong>al</strong> corresponding to<br />

C3An.1r (Fig. 11b). Sediment accumulation rate<br />

during this subchron is 80 cm/ky and the average<br />

thickness of the cycles is 18.5 m. The average<br />

periodicity for the sedimentary cyclicity in the<br />

Meotian is thus 23.5 ky. These results from the Putna<br />

section are in excellent agreement with the periodicity<br />

for precession<strong>al</strong> cycles of the Earth’s axis, and suggest<br />

that the sedimentary cyclicity in the Pontian and<br />

Meotian is indeed astronomic<strong>al</strong>ly forced.<br />

The Pontian of the Rîmnicu Sărat section shows a<br />

similar type of cyclicity as in Putna <strong>al</strong>though the<br />

sandy units are less distinct (Fig. 12a). Here the<br />

average sedimentation rate during C3r is 133 cm/ky<br />

and the average cycle thickness is 30.6 m. This results<br />

in a periodicity of 23 ky for the sedimentary cyclicity.<br />

The Dacian deposits of the Rîmnicu Sărat <strong>al</strong>so show a<br />

cyclic <strong>al</strong>ternation of thick sandy units and more softer,<br />

clay-rich, interv<strong>al</strong>s (Fig. 12b). The best-exposed<br />

interv<strong>al</strong> correlates to subchron C3n.3n (Sidufj<strong>al</strong>l) in<br />

which the accumulation rate is 91 cm/ky. The average<br />

cycle thickness is 21.75 m, which gives a mean<br />

periodicity of 23.9 ky. This is again in excellent<br />

agreement with a precession<strong>al</strong> forcing for the sedimentary<br />

cycles.<br />

In <strong>al</strong>l four cases, the v<strong>al</strong>ues obtained for the<br />

duration of a cycle are very close to the average<br />

Fig. 9. Polarity zones and lithologic<strong>al</strong> column of Rîmnicu Sărat<br />

V<strong>al</strong>ley section. In the polarity column, black and white denote the<br />

norm<strong>al</strong> and reversed polarity interv<strong>al</strong>s, respectively. Solid dots<br />

represent reliable direction of demagn<strong>et</strong>isation diagrams. The white<br />

squares represent the direction of the clear low temperature<br />

components magn<strong>et</strong>ized in the opposite direction than the high<br />

temperature ones. Next to the lithologic<strong>al</strong> column are represented<br />

the levels of limits b<strong>et</strong>ween different stages according to the 29<br />

Covasna, 1:200000 sc<strong>al</strong>e map [38] and 113b DumitreYti, 1:50000<br />

sc<strong>al</strong>e map [39]. The authors of the map had assigned the stage<br />

boundaries from the work of Saulea [36], Ciocîrdel [35] and IonitSă<br />

[37]. See <strong>al</strong>so the caption of Fig. 8.


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periodicity of precession. If we assume that the very<br />

similar type of sedimentary cycles in the lower part of<br />

the Putna section are <strong>al</strong>so forced by precession, we<br />

can use this relation to estimate the durations of the<br />

polarity zones in the lower part of the Putna section.<br />

There, the Sarmatian–Meotian interv<strong>al</strong> <strong>al</strong>so shows an<br />

interv<strong>al</strong> with a similar regular <strong>al</strong>ternation of sands and<br />

silts, correlative to the longest norm<strong>al</strong> polarity zone of<br />

that part of the section (Fig. 13). Cycle thickness in<br />

this norm<strong>al</strong> interv<strong>al</strong> is 15 m, which suggests an<br />

accumulation rate of 0.69 m/ky and duration of 209<br />

ky. This accumulation rate agrees very well with the<br />

uppermost Meotian v<strong>al</strong>ues (Fig. 10), but the c<strong>al</strong>culated<br />

duration does not <strong>al</strong>low a positive discrimination<br />

b<strong>et</strong>ween the two most likely correlations (Fig. 10).<br />

In <strong>al</strong>l parts of the sections, the sedimentary<br />

cyclicity appears to be induced by precession/insolation<br />

processes. Clearly, a more rigorous an<strong>al</strong>ysis of<br />

quantitative records combined with biostratigraphicenvironment<strong>al</strong><br />

confirmation is needed to provide<br />

definitive proof for the astronomic<strong>al</strong> origin of the<br />

cyclicity and to understand the phase relation in the<br />

succession. For example, it is still uncertain if the<br />

sandy units from Putna and Rîmnicu Sărat are the<br />

expression of w<strong>et</strong> or dry periods. There are two<br />

possible scenarios. The first suggests that sandy units<br />

were deposited during w<strong>et</strong>ter periods, when the<br />

discharge from the rivers was bigger; the softer parts<br />

imply a low energy environment coincident with a<br />

decline of deposition. The second scenario presumes<br />

that the sand originated from the dry period, with poor<br />

coverage of veg<strong>et</strong>ation, causing a rapid erosion and<br />

Fig. 10. Correlation of the polarity sequences of the 2.3 km of Putna<br />

and of 7.3 km of Rîmnicu Sărat sections to APTS <strong>2004</strong>. Solid lines<br />

b<strong>et</strong>ween the section records and APTS <strong>2004</strong> connect (interpr<strong>et</strong>ative)<br />

simultaneous polarity boundaries. The doted lines connect the most<br />

possible position of the C2An.2n into the Rîmnicu Sărat record. The<br />

names of the subchrons are in the column attached to the APTS. The<br />

C (Cochiti), N (Nunivak), S (Sidufj<strong>al</strong>l) and T (Thvera) are the<br />

popular names for the names of the subchrons from the Gilbert<br />

Chron. The ages extracted from the map are on the right-hand side<br />

for Putna (intern<strong>al</strong> column) and Rîmnicu Sărat (extern<strong>al</strong> column).<br />

The lighter gray area suggests the first possible correlation of the<br />

older (Sarmatian–Lower Meotian) Putna V<strong>al</strong>ley, while the darker<br />

area is the second most possible correlation. The question marks<br />

indicate the position of the Sarmatian/Meotian boundary in the cases<br />

of the two possible correlations. The arrow indicates the place of the<br />

128 changing in strike and the beginning of the certain magn<strong>et</strong>ostratigraphic<br />

record. Inserted is the diagram illustrating the changes<br />

in the accumulation rates through time (according to APTS<br />

c<strong>al</strong>ibration points [2]). Note significant change of slope b<strong>et</strong>ween<br />

the two interv<strong>al</strong>s, at ca. 6 Ma. The c<strong>al</strong>culated v<strong>al</strong>ues are for the<br />

<strong>al</strong>ready compacted deposits.


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Fig. 11. Vertic<strong>al</strong>ly bedded sandstone units, <strong>al</strong>ternating with finer sediments on Putna V<strong>al</strong>ley expressing the Milankovitch precession cycles: (a)<br />

in Pontian and (b) in Meotian deposits. For sc<strong>al</strong>e, see highlighted human being in the white circle. Ins<strong>et</strong> in the top left-hand side of the pictures<br />

are the c<strong>al</strong>culated accumulation rates and the periodicity cycles. Beneath each picture are the lithologic<strong>al</strong> columns for the interv<strong>al</strong>s. The wider<br />

rectangles and the lighter gray suggest the sandy units, while the narrow and darker gray the finer interv<strong>al</strong>s.<br />

increased sediment transport. The softer parts are<br />

related, in this case, to more veg<strong>et</strong>ation and more<br />

protection against erosion and hence less sediment<br />

remov<strong>al</strong> and transport.<br />

The astronomic<strong>al</strong> forcing of the sedimentary<br />

succession of the westernmost part of the Dacian<br />

basin has earlier been reported by Van Vugt <strong>et</strong> <strong>al</strong>. [12],<br />

who demonstrated the expression of eccentricity in the<br />

siliciclastic Lupoaia section of the southern Carpathian<br />

foredeep. Van Vugt <strong>et</strong> <strong>al</strong>. [36] suggested that the<br />

lacustrine d<strong>et</strong>rit<strong>al</strong> basins are dominantly forced by<br />

eccentricity and that the lignite seams represent the<br />

eccentricity maxima while the d<strong>et</strong>rit<strong>al</strong> interv<strong>al</strong>s denote<br />

eccentricity minima. By an<strong>al</strong>yzing the pollen from the<br />

same Lupoaia section, Popescu <strong>et</strong> <strong>al</strong>. [33] arrived at<br />

the same conclusion. In our study, however, we find<br />

evidence for precession rather than eccentricityrelated<br />

cyclicity affecting the deposits of the eastern<br />

part of the Dacian basin. An explanation for this<br />

difference in response to astronomic<strong>al</strong> forcing could


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Fig. 12. Subvertic<strong>al</strong>ly bedded sandy interv<strong>al</strong>s, <strong>al</strong>ternating with finer sediments on Rîmnicu Sărat V<strong>al</strong>ley expressing the Milankovitch precession<br />

cycles: (a) in Pontian and (b) in Dacian deposits. See <strong>al</strong>so the caption of Fig. 11.<br />

Fig. 13. Vertic<strong>al</strong>ly bedded sandstones, <strong>al</strong>ternating with finer sediments on Putna V<strong>al</strong>ley at the transition b<strong>et</strong>ween Sarmatian and Meotian. See<br />

<strong>al</strong>so the caption of Fig. 11.


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be the difference in tectonic s<strong>et</strong>ting and basin<br />

configuration: the eastern Carpathian foredeep<br />

includes more than 8 km of Sarmatian–Romanian<br />

deposits, whereas the southern Carpathian foredeep<br />

consists of a maximum of 1.5 km for the timeequiv<strong>al</strong>ent<br />

deposits [34].<br />

5.2. Age constraints for the Parat<strong>et</strong>hys stages<br />

Many recent studies of the FocYani basin use the<br />

boundaries of the Parat<strong>et</strong>hys Sarmatian, Meotian,<br />

Pontian, Dacian and Romanian stages to estimate<br />

sediment accumulation rates and tectonic subsidence<br />

rates [13–15]. The stage boundaries are mainly<br />

defined by biostratigraphic studies [23,35–37] on<br />

molluscs and are displayed on the geologic<strong>al</strong> maps<br />

of the region (29 Covasna, 1:200 000 sc<strong>al</strong>e [38] and<br />

113b DumitreYti, 1:50000 sc<strong>al</strong>e [39]). These stage<br />

boundaries commonly correlate to lithologic<strong>al</strong><br />

changes and are recognized as such in the seismic<br />

reflection profiles of the Carpathian foredeep [13,15].<br />

Subsequently, the later<strong>al</strong> changes in sediment thickness<br />

can be quantified for each stage. For estimation<br />

of (subsidence and accumulation) rates, however,<br />

addition<strong>al</strong> age constraints have to be incorporated.<br />

The most recent studies on the tectonic evolution of<br />

the FocYani area use the timesc<strong>al</strong>e of Andreescu <strong>et</strong> <strong>al</strong>.<br />

[5] for ages of the stage boundaries [13–15].<br />

Although we would prefer to have a d<strong>et</strong>ailed<br />

biostratigraphic record directly tied to our sequences,<br />

we must limit ourselves, in this phase, to the<br />

biostratigraphic data and the stage boundaries from<br />

the published geologic<strong>al</strong> maps [38,39] and the seismic<br />

profiles. Using the direct correlation to the APTS and<br />

the (biostratigraphic<strong>al</strong>ly) d<strong>et</strong>ermined stages on the<br />

maps and profiles, we can now numeric<strong>al</strong>ly date the<br />

various stage boundaries of the sedimentary sequences<br />

of the Romanian segment of the eastern Carpathian<br />

foredeep (Fig. 10). We conclude that the<br />

Meotian/Pontian boundary is placed at the beginning<br />

of chron C3r at 5.9F0.1 Ma. The Pontian/Dacian<br />

boundary is located at the beginning of subchron<br />

C3n.3n (Sidufj<strong>al</strong>l) and dated at 4.9F0.1 Ma. The<br />

Dacian/Romanian limit is situated at the base of chron<br />

C2Ar with an age of 4.07F0.5 Ma. Note that our<br />

errors relate to uncertainties in magn<strong>et</strong>ostratigraphic<br />

age, but do not include uncertainties in the biostratigraphic<br />

positions of the stage boundaries. Nevertheless,<br />

our ages are in great contrast to the commonly<br />

used timesc<strong>al</strong>e of Andreescu <strong>et</strong> <strong>al</strong>. [5] (Fig. 2) and will<br />

thus have major consequences for tectonic studies.<br />

Correlation to the western Parat<strong>et</strong>hys timesc<strong>al</strong>e is not<br />

useful at this stage because of the lack of d<strong>et</strong>ailed<br />

biostratigraphic criteria. We do not appraise the age<br />

for the Sarmatian–Meotian boundary because of the<br />

uncertainties in correlation of the acquired magn<strong>et</strong>ostratigraphic<br />

record (of this older part) to the APTS.<br />

In a recent study [13], based on a composite of<br />

seven outcrops from the western and centr<strong>al</strong> part of<br />

Dacian basin (southern Carpathian foredeep), the<br />

Meotian–Pontian boundary had been estimated at<br />

6.15F0.11 Ma, within subchron C3An.1n, while the<br />

age of the Pontian–Dacian boundary is 5.30F0.1 Ma<br />

(Fig. 2). In the same source, the Dacian–Romanian<br />

boundary is recorded either at 4.58F0.05 Ma, in<br />

subchron C3n.2n (Nunivak), or at 4.25F0.0 Ma in<br />

subchron C3n.1n (Cochiti). These ages are slightly<br />

different from ages in our study. Nevertheless, both<br />

studies show the reduction in the duration of the<br />

Pontian to approximately 0.85 My.<br />

5.3. Consequences for tectonic processes<br />

Our magn<strong>et</strong>ostratigraphic results infer that the<br />

accumulation rate increased considerably at the<br />

Meotian–Pontian boundary, from an average of 60<br />

cm/ky during the Meotian to an average of 150 cm/ky<br />

during the Pontian to Romanian (Fig. 10). Until now,<br />

tectonic models suggested that the subsidence<br />

decreased during Meotian to Pontian times, but that<br />

a significant increase took place during the Dacian–<br />

Romanian time span [15]. Evidently, this difference in<br />

timing is related to the use of a different timesc<strong>al</strong>e [8],<br />

in which the Meotian is placed b<strong>et</strong>ween 10 and 8 Ma,<br />

and the Pontian b<strong>et</strong>ween 8 and 5 Ma. Our new results<br />

show that the duration of the Pontian is more than<br />

three times shorter than in most published timesc<strong>al</strong>es<br />

(Fig. 2). As a consequence, the c<strong>al</strong>culated sedimentation<br />

and subsidence rates will <strong>al</strong>so be significantly<br />

(about three times) higher. Our new age control<br />

demonstrates that the previous timesc<strong>al</strong>es for the<br />

eastern Parat<strong>et</strong>hys are not appropriate for c<strong>al</strong>culation<br />

of accumulation rates from the Carpathian foredeep.<br />

We show that the usage of unambiguous time control,<br />

offered by magn<strong>et</strong>ic polarity stratigraphy, would<br />

substanti<strong>al</strong>ly improve the interpr<strong>et</strong>ation of tectonic


246<br />

I. <strong>Vasiliev</strong> <strong>et</strong> <strong>al</strong>. / Earth and Plan<strong>et</strong>ary Science L<strong>et</strong>ters 227 (<strong>2004</strong>) 231–247<br />

models and give a more re<strong>al</strong>istic picture of the<br />

processes that have taken place in this tectonic<strong>al</strong>ly<br />

active region.<br />

A major change in accumulation rate in the eastern<br />

Parat<strong>et</strong>hys thus appears som<strong>et</strong>ime around the Meotian–Pontian<br />

transition, at approximately 5.8–6 Ma.<br />

This coincides remarkably well with the ons<strong>et</strong> of the<br />

Messinian S<strong>al</strong>inity Crisis of the Mediterranean, dated<br />

at 5.96 Ma [1]. The increase in accumulation rate<br />

probably indicates a change in basin configuration,<br />

which may be related to the closure of the water<br />

connection b<strong>et</strong>ween or within this part of the Parat<strong>et</strong>hys<br />

and the Mediterranean.<br />

6. Conclusions<br />

A magn<strong>et</strong>ostratigraphic record was made on long<br />

and continuous sections, comprising more than 7 km<br />

of sedimentary rocks, from the extremely thick<br />

FocYani sedimentary basin of the eastern Carpathian<br />

foredeep of Romania. The excellent results from the<br />

Putna and Rîmnicu Sărat sections show that an <strong>al</strong>most<br />

compl<strong>et</strong>e chronostratigraphic framework can be<br />

derived, from approximately 7.2 to 2.5 Ma. Correlation<br />

of the magn<strong>et</strong>ic polarity patterns to the APTS is<br />

straightforward (Fig. 10) except for the lowermost<br />

(Sarmatian) part of the Putna section.<br />

The Meotian/Pontian, Pontian/Dacian and Dacian/<br />

Romanian boundaries have been dated, according to<br />

their biostratigraphic position on the geologic<strong>al</strong> maps.<br />

We conclude that the Meotian/Pontian boundary is<br />

placed at the beginning of chron C3r at 5.9F0.1 Ma.<br />

The Pontian/Dacian boundary is located at the<br />

beginning of chron C3n.3n (Sidufj<strong>al</strong>l) and dated at<br />

4.9F0.1 Ma. The Dacian/Romanian limit is situated at<br />

the base of chron C2Ar and its age is 4.07F0.5 Ma.<br />

The new age control permits to c<strong>al</strong>culate the<br />

accumulation rates for each polarity zone, i.e. for<br />

well-defined time interv<strong>al</strong>s. Two major trends in the<br />

accumulation rate imply a significant increase (more<br />

than doubling) occurring at the transition Meotian to<br />

Pontian, during chron C3r. This change in accumulation<br />

rate appears at approximately 5.8–6 My, which<br />

coincides with the ons<strong>et</strong> of the Messinian S<strong>al</strong>inity<br />

Crisis from the Mediterranean.<br />

The c<strong>al</strong>culated v<strong>al</strong>ues for the average duration of<br />

the observed sedimentary cycles are very close to the<br />

average duration of a precession (21.7 ky) cycle, and<br />

indicate that the sedimentary cycles from the eastern<br />

Carpathian foredeep are astronomic<strong>al</strong>ly forced.<br />

Acknowledgements<br />

This work was carried out in the frame of activities<br />

sponsored by N<strong>et</strong>herlands Research Centre for Integrated<br />

Solid Earth Sciences (ISES). We thank Marius,<br />

Liliana, Cristian, Gabi and Guillaume for their help in<br />

the field. Tom Mullender assisted with remarkable<br />

patience at the rock magn<strong>et</strong>ic an<strong>al</strong>ysis. We thank<br />

J.E.T. Channell and W. Lowrie for constructive<br />

reviews that helped to improve the manuscript.<br />

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