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Marine Ecosystems Research Department - jamstec japan agency ...

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Japan <strong>Marine</strong> Science and Technology Center<br />

Institute for Frontier <strong>Research</strong> on Earth Evolution (IFREE)<br />

<strong>Research</strong> Program for Geochemical Evolution<br />

1. <strong>Research</strong> Overview<br />

The crust and mantle, which are composed of silicate<br />

minerals, represent % of the Earth's mass.<br />

Although the crust is volumetrically insignificant in<br />

the solid Earth, it contains a large fraction of the elements<br />

that preferentially enter the melt when a silicate<br />

is melted. High concentrations of these elements in<br />

such a small volume mean that the Earth is an extensively<br />

differentiated body. While the Earth's mantle is<br />

much more homogeneous in compositions than the<br />

crust, it has been well established that at least four,<br />

compositionally distinct components are required to<br />

explain the isotopic compositions of mid-ocean ridge<br />

basalts (MORBs) and lavas of ocean islands that are<br />

built by the activity of deep-seated hotspots.<br />

Understanding the origin of such geochemical endmembers<br />

in the crust and mantle is essential to document<br />

the evolution of the solid Earth. The <strong>Research</strong><br />

Program for Geochemical Evolution aims to seek an<br />

understanding of the evolutionary processes of the<br />

solid Earth based on comprehensive studies of solid<br />

earth materials.<br />

2. Some <strong>Research</strong> Results for Fiscal year 2002<br />

2.1. The role of the subduction factory - the evolution<br />

of the Earth's mantle<br />

Subduction zones, where oceanic lithosphere is<br />

foundering into the Earth's interior, have been working<br />

as factories and have contributed significantly to the<br />

evolution of the solid Earth. Raw materials, such as<br />

pelagic or terrigenous sediment, oceanic crust, and<br />

mantle lithosphere, are supplied into the factory<br />

(Fig.). In the process of transportation and processing<br />

of these raw materials, the factory causes vibrations<br />

as earthquakes. The major products of the factory<br />

are arc magmas and their solidified materials, continental<br />

crust. The waste materials processed in the subduction<br />

factory, such as chemically modified lithosphere<br />

and delaminated lower continental crust, sink<br />

into the deep mantle (Fig.).<br />

continental<br />

crust<br />

mantle<br />

wedge<br />

residual<br />

materials<br />

volatiles<br />

volcanoes<br />

earthquake<br />

oceanic<br />

materials<br />

Raw Materials<br />

- oceanic material<br />

- mantle material<br />

Products<br />

- magma/volcanoes<br />

- volatiles<br />

- continental crust<br />

Residues<br />

- chemically modified slab<br />

- delaminated lower crust<br />

Fig.13 The processes occurring in the subduction factory. Raw<br />

materials, such as oceanic sediments, oceanic crust, and<br />

mantle lithosphere, are fed into the factory and are manufactured<br />

into arc magmas and continental crust. The<br />

waste materials processed in this factory, such as chemically<br />

modified oceanic crust/sediments and delaminated<br />

lower continental crust, sink into the deep mantle and are<br />

likely to have greatly contributed to the mantle evolution.<br />

Dehydration reactions within subducting hydrated<br />

basaltic crust occur continuously from very shallow<br />

levels to over km depth, but experimental studies<br />

on trace element behavior during dehydration are<br />

generally limited to those related to the amphiboliteeclogite<br />

transformation and element partitioning<br />

between aqueous fluids and garnet/clinopyroxene.<br />

A notable feature demonstrated by these experiments<br />

is that Pb is more preferentially partitioned into<br />

H <br />

O fluids than U and Th, leaving the residue, after<br />

dehydration, with higher U/Pb and Th/Pb than its<br />

original composition. It has also been demonstrated<br />

that Rb and Nd are released from the subducting crust<br />

more readily than Sr and Sm. Thus, residual basaltic<br />

crust after the amphibolite-eclogite transformation<br />

will have lower Sr/ Sr, higher Nd/ Nd, and<br />

higher Pb/ Pb values than hydrated basaltic crust<br />

(Fig.). Pb/ Pb ratios of the dehydrated residue<br />

95

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