Liquefaction co-processing of coal shale oil at - Argonne National ...

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100 80 $ c 3 9 60- - t J 240- 5 0 - Calculated AVERAGE PSEUDOCOMPONENT BOILING POINT, O F Figure 3 -Composition of Vacuum Bottoms Pseudocomponents Using Petroleum Liquids Correlations. 20 - P= Pressure, psia 0 - --L - I I I I I I I I I I Experimental - Calculated I _ - 8 - - I - - 400 600 800 1000 AVERAGE PSEUDOCOMPONENT BOILING POINT, O F Figure 4 - Composition of Vacuum Bottoms Pseudocomponents Using Coal Liquids Correlations. 225
I I I I I I I I I 100- --- Experimental - Calcula tad $80- c 1 G c60 $40- 3 V - 20 - P= Pressure, psi0 0*-- 200 400 600 800 IO00 AVERAGE PSEUDOCOMPONENT BOILING POINT, O F Figure 5 - Composition of Vacuum Overhead Using Petroleum Liquids Correlations. - I I I I I I 100- --- Experimental Calculated $ 80- c 3 20 - P= Pressure, psia 200 400 600 800 1000 AVERAGE PSEUDOCOMPONENT BOILING POINT, OF Figure 6-Composltlon of Vacuum Overhead Using Coal Liquids Correlations. 226 - - d I ! 1 E f
Page 1 and 2:
ABSTRACT LIQUEFACTION CO-PROCESSING
Page 3 and 4:
eaction temperature, 1000-1500 psig
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6. 7. 8. 9. 10. 11. 12. 13. 14. 15
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I 0" 100- I I I WyO-3 P 3: 1500 psi
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11.3 A-6 yJ 600 OF, 1500 psig CO, 3
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Experimental UDqradinq and Cooroces
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catalytic to the thermal hydrogenat
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the reaction with oil production re
Page 17 and 18:
TET did not promote the production
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MICROAUTOCLAVE DESCRIPTION AND PROC
Page 21 and 22:
FEEDSTOCK PROPERTIES Some propertie
Page 23 and 24: CONCLUSIONS HRI's microautoclave ha
Page 25 and 26: 176
Page 27 and 28: 100. 2 8%. M = ?8. 38. .... . . . .
Page 29 and 30: CATALYTIC CO-PROCESSINS OF OHIO NO.
Page 31 and 32: CATALYST COMPARISON STUDY The premi
Page 33 and 34: fractions and a decrease of heavier
Page 35 and 36: TABLE 2 Coal Analyses I1 1 i noi s
Page 37 and 38: Temperature WHSV, G/hr/cc TABLE 6 C
Page 39 and 40: z FIGURE 3 COAL REACTIVITY SCREENIN
Page 41 and 42: COPROCESSING USING HzS AS A PROMOTE
Page 43 and 44: - 3 - that product yields depend on
Page 45 and 46: - 5 - occurs in the yields of aspha
Page 47 and 48: Table 1 Analysis of Feedstocks Fore
Page 49 and 50: THO-STAGE COPROCESSING OF SUBBITUMI
Page 51 and 52: esult in retrogressive reactions ta
Page 53 and 54: 8. 6. Ignasiak, L. Lewkowicz, G. Ko
Page 55 and 56: Table 4 OVERALL MASS BALANCE FOR TH
Page 57 and 58: BACKGROUND COAL LIQUEFACTION/RESID
Page 59 and 60: system, which could be operated wit
Page 61 and 62: TABLE 1 EFFECT OF LC-FINING~"' TEMP
Page 63 and 64: Figure 1. SCHEMATIC OF LCI CO-PROCE
Page 65 and 66: SIMULATION OF A COAL/PETROLEuII RES
Page 67 and 68: 20 pseudocomponents was developed t
Page 69 and 70: ottoms is less sensitive to the num
Page 71 and 72: Low Pressure Separator A temperatur
Page 73: 7. Gallier, P.W., Boston, J.F., Wu,
Page 77 and 78: Coprocessing Schemes The coprocessi
Page 79 and 80: processing 25,000 and 150,000 bbl/d
Page 81 and 82: FIGURE 1 I DISTRIBUTION OF REFINERI
Page 83 and 84: Table 1. Samples Analyzed PNLNumber
Page 85 and 86: the coal itself. The chemical compo
Page 87 and 88: - - ITSL PAH Fraction PAH Fraction
Page 89 and 90: PROCESS DEVELOPMENT STUDIES OF TWO-
Page 91 and 92: SUMMARY e The major effect of close
Page 93 and 94: omw '??h 4NO WNID ?N? 000 wmm c9'1'
Page 95 and 96: tl f 246
Page 97 and 98: 248
Page 99 and 100: qkCqQ r! o! 0 0 0 0 0 0 0 I-UH ')I
Page 101 and 102: Materials The catalyst was shell 32
Page 103 and 104: CONCLUSIONS Separation of a light h
Page 105 and 106: Table 3. Results of activity testin
Page 107 and 108: feed coal and plant configuration a
Page 109 and 110: P1 #2 #3 114 115 #6 ITSL subbitumin
Page 111 and 112: temperature, time and solvent power
Page 113 and 114: TABLE 1 EXPERIMENTAL CONDITIONS AND
Page 115 and 116: la Figure 1. lH-NMR spectra of samp
Page 117 and 118: PERFORMANCE OF THE LOW TEMPERATURE
Page 119 and 120: BENCH UNIT DESCRIPTION Process deve
Page 121 and 122: Recycle Residuum Hydrogenati On Res
Page 123 and 124: FIRST STAGE HRI'S CATALYTIC TWO STA
Page 125 and 126:
FIRST-STAQ COAL CONVERSION (W I IIA
Page 127 and 128:
REACTOR SOLIOS HTOROGEN/CARBON ATOl
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TRANSPORTATION FUELS FROM TWO-STAGE
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Process Identification LV% Of AS- R
Page 133 and 134:
Table I11 HYDROTREATING TESTS WITH
Page 135 and 136:
Table IV HYDROTREATING TO 0.2 PPM N
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Table VI EFFECT OF BOILING RANGE ON
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(4) In all cases studied, the jet f
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292
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INTEGRATED TWO-STAGE LIQUEFACTION:
Page 145 and 146:
are over-riding features in its fav
Page 147 and 148:
Complementary fundamental studies o
Page 149 and 150:
Comparative Economics of Two-Stage
Page 151 and 152:
The variation in hydrotreating cost
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FIGURE 1: COMPARISONS OF ILLINOIS N
Page 155 and 156:
Process TABLE 1: TWO-STAGE PROCESSE
Page 157 and 158:
Abstract Temperature-Staged Catalyt
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Results and Discussion Reactions in
Page 161 and 162:
2. 3. 4. 5. 6. Derbyshire, F. J. an
Page 163 and 164:
I LL a rJJW ., .. ;> 0 i s W 8 a 31
Page 165 and 166:
Materials Feeds to the WGS-solvent
Page 167 and 168:
products. Thus, coupling the WGS an
Page 169 and 170:
5. R. J. Xottenstette, Sandia Natio
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ENHANCED COAL LIQUEFACTION WITH STE
Page 173 and 174:
change in weight being compared to
Page 175 and 176:
I I aromatic ring. The group of sig
Page 177 and 178:
T,\llI.l< I ASAI,YSIS OP \\YOl)Al\:
Page 179 and 180:
00 3000 2000 le00 1600 1400 1200 IO
Page 181 and 182:
THE EFFECT OF REACTION CONDITIONS O
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and may ultiontely form methyl-subs
Page 185 and 186:
! 5. Narain, N.K., Utz, B.R., Appel
Page 187:
4 (u I t + 9 (u I 337 - Q 0
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