Liquefaction co-processing of coal shale oil at - Argonne National ...
Liquefaction co-processing of coal shale oil at - Argonne National ...
Liquefaction co-processing of coal shale oil at - Argonne National ...
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20 pseudo<strong>co</strong>mponents was developed to represent the heavier <strong>co</strong>mponents; each<br />
pseudo<strong>co</strong>mponent represents about a 50°F cut <strong>of</strong> liquid distill<strong>at</strong>e. Since the<br />
process feed stream included both <strong>co</strong>al and petroleum liquids, separ<strong>at</strong>e simul<strong>at</strong>ion<br />
runs were made where thermophysical properties for each pseudo<strong>co</strong>mponent were<br />
analyzed using the <strong>co</strong>rrel<strong>at</strong>ion option set for <strong>co</strong>al liquids and the set ,for<br />
petroleum liquids. Comparisons have been made for the performance <strong>of</strong> each option<br />
set.<br />
RESULTS AND DISCUSSION<br />
The <strong>co</strong>mposition for the process feed stream to the high-pressure separ<strong>at</strong>or is<br />
estim<strong>at</strong>ed from experimental product sl<strong>at</strong>es for the vacuum fraction<strong>at</strong>or, the<br />
debutanizer, and the three-phase separ<strong>at</strong>or (see Table 1). Gases and identified<br />
<strong>co</strong>mpounds range from HZ to pentane. Liquid distill<strong>at</strong>es are represented as pseudo-<br />
<strong>co</strong>mponents and range from an average b<strong>oil</strong>ing point <strong>of</strong> lll°F to 1091OF (pseudo-<br />
<strong>co</strong>mponents are prefaced by PC and followed by the average b<strong>oil</strong>ing point <strong>of</strong> the<br />
approxim<strong>at</strong>ely 50°F cut). The initial b<strong>oil</strong>ing point (IBP) <strong>of</strong> the liquid distill<strong>at</strong>e<br />
is 69.80F. For <strong>co</strong>nciseness in the present<strong>at</strong>ion <strong>of</strong> results, the pseudo<strong>co</strong>mponents<br />
have been expressed as four distill<strong>at</strong>e fractions (see Table 2).<br />
TABLE 1. Process Feed Stream Composition for High Pressure Separ<strong>at</strong>or<br />
Components' Flows (lb/hr) Components* Flows (lb/hr)<br />
Ht<br />
<strong>co</strong><br />
HzS<br />
CH +<br />
0.0593<br />
0.0051<br />
0.0552<br />
0.0637<br />
PC428<br />
PC477<br />
PC525<br />
PC575<br />
0.0075<br />
0.0168<br />
0.0163<br />
0.0163<br />
C2H6 0.0364 PC625 0.0167<br />
CsHe 0.0255 PC675 0.0174<br />
CIHio 0.0105 PC725 0.0158<br />
I-C~HI o 0.0028 PC774 0.0139<br />
CsHi z<br />
I-CSHIZ<br />
HzO<br />
PClll<br />
PC176<br />
PC226<br />
PC276<br />
PC327<br />
PC376<br />
0.0034<br />
0.0034<br />
0.0108<br />
0.0052<br />
0.0017<br />
0.0020<br />
0.0025<br />
0.0041<br />
0.0053<br />
PC825<br />
PC876<br />
PC924<br />
pc973<br />
PC1022<br />
PC1091<br />
Ash<br />
Un<strong>co</strong>nverted Coal<br />
Nondistill<strong>at</strong>e Solids<br />
0.0128<br />
0.0113<br />
0.0113<br />
0.0048<br />
0.0034<br />
0.0503<br />
0.0108<br />
0.0135<br />
0.0456<br />
*Pseudo<strong>co</strong>mponents are 50°F cuts and are represented by PC followed by the average<br />
b<strong>oil</strong>ing point.<br />
TABLE 2. Process Feed Stream Distill<strong>at</strong>e Fractions Expressed as Pseudo<strong>co</strong>mponents.<br />
Distill<strong>at</strong>e Fraction Pseudo<strong>co</strong>mponent Range Flows (lb/hr)<br />
IBP-3500F PC111-PC327 0.0155<br />
350°-4500F PC376-PC428 0.0128<br />
45O0-95OOF PC477-PC924 0.149<br />
9500F+ PC973-PC1091 0.0585<br />
218<br />
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