Liquefaction co-processing of coal shale oil at - Argonne National ...
Liquefaction co-processing of coal shale oil at - Argonne National ...
Liquefaction co-processing of coal shale oil at - Argonne National ...
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Table 1<br />
Analysis <strong>of</strong> Feedstocks<br />
Forestburg Coal Cold-Lake<br />
vacum bottolns<br />
Proxim<strong>at</strong>e analysis Specific gravity, 15/15'C 1.038<br />
(wt %, as received) Pentane insolubles, wt % 23.8<br />
Pitch <strong>co</strong>ntent, wt % 83.2<br />
Moisture 19.7 Conradson Carbon, wt I 17.1<br />
Vol<strong>at</strong>ile 37.2 Elemental ccunposition,wt I<br />
Fixed carbon 36.1 C 83.34<br />
Ash 7.0 H<br />
N<br />
9.69<br />
0.45<br />
Ultim<strong>at</strong>e analysis S 5.84<br />
(wt I DAF) 0 0.68<br />
C 74.34 Metals, ppm<br />
H<br />
N<br />
4.81<br />
1.78<br />
V<br />
Ni<br />
235<br />
93<br />
0 18.58 Fe 18<br />
S 0.49<br />
Table 2<br />
Comparison <strong>of</strong> the Effects <strong>of</strong> H2S w ith FeSO(,<br />
Severity Low Moder<strong>at</strong>e<br />
H2'5 (1) no yes<br />
FeSOq yes no<br />
Distill<strong>at</strong>e yield (2) 22.9 27.3<br />
Coal <strong>co</strong>nversion (3) 53.7 67.9<br />
Pitch <strong>co</strong>nversion (4) 15.8 20.3<br />
(1)<br />
(3)<br />
no Yes<br />
Yes no<br />
36.3 43.2<br />
70.4 80.4<br />
34.1 42.5<br />
8 wt I, based on maf slurry feed (2) w t I, based on maf slurry feed<br />
w t I, based on maf <strong>co</strong>al, (4) maf (+525 "C) in - maf (+525'C) out<br />
defined as THF solubility<br />
maf (+525"C) in<br />
Table 3<br />
Comparison <strong>of</strong> The Effects <strong>of</strong> FeS04 and HpS + FeSO4<br />
-<br />
Severity Very low Low Moder<strong>at</strong>e Moder<strong>at</strong>e-hiqh<br />
HgS (1) no yes no yes no yes no yes<br />
FeSO4 yes yes yes yes yes yes yes yes<br />
Distill<strong>at</strong>e yield (2) 15.8 16.5 22.9 22.9 36.3 42.1 60.9 63.1<br />
Coal <strong>co</strong>nversion (3) 27.4 41.1 53.7 61.3 70.4 83.7 86.3 85.9<br />
Pitch <strong>co</strong>nversion (4) 8.1 7.5 15.8 18.6 34.1 42.4 64.8 69.7<br />
(1) 8 wt %, based on maf slurry feed (2) wt I, based on maf slurry feed<br />
(3) wt %, based on maf <strong>co</strong>al, (4) maf (+525'C) in - maf (+525"C) out<br />
defined as THF solubility maf (+525"C) in<br />
198