Liquefaction co-processing of coal shale oil at - Argonne National ...
Liquefaction co-processing of coal shale oil at - Argonne National ... Liquefaction co-processing of coal shale oil at - Argonne National ...
Catalyst Type API Gravity at 15.6"C Specific Gravity Carbon, wt-% Hydrogen, wt-% Oxygen, wt-% Sulfur, wt-% Nitrogen, wt-% Ash, wt-% Heptane Insolubles, wt-% Carbon Residue, wt-% Vanadium and Nickel, wt-ppm *Estimated TABLE 4 Catalyst Comparison Study Total Liquid Product Properties None 9.3 1.0050 85.15 10.05 1.00 2.75 0.60 0.005 37.03 14.6 19 TABLE 5 Fe203 8.5 1.0107 84.40 9.6* - 2.30 0.90
Temperature WHSV, G/hr/cc TABLE 6 Continuous Bench-Scale Operations Effect of Residence Time Base + 4 0.62 Product Distribution Hetero Gases + HvO, wt-% 6.3 Hcbn. Gas C4-, wt-% 3.1 C - 371"C, wt-% 42.0 391 - 510°C, wt-% 43.4 510°C + 4.1 MAF Coal Total, wt-% 3.3 102.2 Conversion Coal, wt-% MAF Coal 90.5 C Insolubles, wt-% 69.9 51OoC+, wt-% 67.7 371"C+, wt-% 38.7 H2 Consumption, wt-% 2.19 Base + 6 0.78 8.9 2.5 38.0 40.1 10.1 3.0 102.6 91.8 82.2 64.2 40.1 2.58 Base +5 1.01 8.4 2.3 31.1 41.9 13.9 4.7 102.3 86.8 75.7 56.8 33.2 2.29
- Page 1 and 2: ABSTRACT LIQUEFACTION CO-PROCESSING
- Page 3 and 4: eaction temperature, 1000-1500 psig
- Page 5 and 6: 6. 7. 8. 9. 10. 11. 12. 13. 14. 15
- Page 7 and 8: I 0" 100- I I I WyO-3 P 3: 1500 psi
- Page 9 and 10: 11.3 A-6 yJ 600 OF, 1500 psig CO, 3
- Page 11 and 12: Experimental UDqradinq and Cooroces
- Page 13 and 14: catalytic to the thermal hydrogenat
- Page 15 and 16: the reaction with oil production re
- Page 17 and 18: TET did not promote the production
- Page 19 and 20: MICROAUTOCLAVE DESCRIPTION AND PROC
- Page 21 and 22: FEEDSTOCK PROPERTIES Some propertie
- Page 23 and 24: CONCLUSIONS HRI's microautoclave ha
- Page 25 and 26: 176
- Page 27 and 28: 100. 2 8%. M = ?8. 38. .... . . . .
- Page 29 and 30: CATALYTIC CO-PROCESSINS OF OHIO NO.
- Page 31 and 32: CATALYST COMPARISON STUDY The premi
- Page 33 and 34: fractions and a decrease of heavier
- Page 35: TABLE 2 Coal Analyses I1 1 i noi s
- Page 39 and 40: z FIGURE 3 COAL REACTIVITY SCREENIN
- Page 41 and 42: COPROCESSING USING HzS AS A PROMOTE
- Page 43 and 44: - 3 - that product yields depend on
- Page 45 and 46: - 5 - occurs in the yields of aspha
- Page 47 and 48: Table 1 Analysis of Feedstocks Fore
- Page 49 and 50: THO-STAGE COPROCESSING OF SUBBITUMI
- Page 51 and 52: esult in retrogressive reactions ta
- Page 53 and 54: 8. 6. Ignasiak, L. Lewkowicz, G. Ko
- Page 55 and 56: Table 4 OVERALL MASS BALANCE FOR TH
- Page 57 and 58: BACKGROUND COAL LIQUEFACTION/RESID
- Page 59 and 60: system, which could be operated wit
- Page 61 and 62: TABLE 1 EFFECT OF LC-FINING~"' TEMP
- Page 63 and 64: Figure 1. SCHEMATIC OF LCI CO-PROCE
- Page 65 and 66: SIMULATION OF A COAL/PETROLEuII RES
- Page 67 and 68: 20 pseudocomponents was developed t
- Page 69 and 70: ottoms is less sensitive to the num
- Page 71 and 72: Low Pressure Separator A temperatur
- Page 73 and 74: 7. Gallier, P.W., Boston, J.F., Wu,
- Page 75 and 76: I I I I I I I I I 100- --- Experime
- Page 77 and 78: Coprocessing Schemes The coprocessi
- Page 79 and 80: processing 25,000 and 150,000 bbl/d
- Page 81 and 82: FIGURE 1 I DISTRIBUTION OF REFINERI
- Page 83 and 84: Table 1. Samples Analyzed PNLNumber
- Page 85 and 86: the coal itself. The chemical compo
Temper<strong>at</strong>ure<br />
WHSV, G/hr/cc<br />
TABLE 6<br />
Continuous Bench-Scale Oper<strong>at</strong>ions<br />
Effect <strong>of</strong> Residence Time<br />
Base + 4<br />
0.62<br />
Product Distribution<br />
Hetero Gases + HvO, wt-% 6.3<br />
Hcbn. Gas C4-, wt-% 3.1<br />
C - 371"C, wt-% 42.0<br />
391 - 510°C, wt-% 43.4<br />
510°C + 4.1<br />
MAF Coal<br />
Total, wt-%<br />
3.3<br />
102.2<br />
Conversion<br />
Coal, wt-% MAF Coal 90.5<br />
C Insolubles, wt-% 69.9<br />
51OoC+, wt-% 67.7<br />
371"C+, wt-% 38.7<br />
H2 Consumption, wt-% 2.19<br />
Base + 6<br />
0.78<br />
8.9<br />
2.5<br />
38.0<br />
40.1<br />
10.1<br />
3.0<br />
102.6<br />
91.8<br />
82.2<br />
64.2<br />
40.1<br />
2.58<br />
Base +5<br />
1.01<br />
8.4<br />
2.3<br />
31.1<br />
41.9<br />
13.9<br />
4.7<br />
102.3<br />
86.8<br />
75.7<br />
56.8<br />
33.2<br />
2.29
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