Liquefaction co-processing of coal shale oil at - Argonne National ...

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REFERENCES Tallb, A., 0. Gray, and M. Neuworth. Assessment of H-Coal@ Process Developments, MITRE Corporation Report MTR-83W199. January 1984. "H-Coal@ Process Improvement Study - Bench Unit Baseline Run With preheater/Reactor", Hydrocarbon Research, hC., FE-10152-65, May 1981. "Bench Unit Preheater Study To Determine Optimum Preheater Conditions for High Coal Conversion", Hydrocarbon Research, Inc., FE-10152-86, October 1982. "Two-Stage Bench Run on Illinois No. 6 Coal - Runs 227-2 and 227-3. Hydrocarbon Research, Inc., FE-10152-87. August 1982. (Not Issued) "Two-Stage Liquefaction of Kyodak Coal - Runs 227-5 and 227-6". Hydrocarbon Research, Inc., FE-10152-90, September 1982. (Not Issued) "Two-Stage Liquefaction Study Using Illinois No. 6 Coal and Equal Volume Reactors - Run 227-7". Hydrocarbon Research Inc.. FE-10152-92. September 1982. (Not Issued) "New Technology Concept for Two-Stage Liquefaction of Coal - Illinois No. 6 Coal", Hydrocarbon Research, Inc.. DE-60017-TOP-1, August 1985. "New Technology Concept for Two-Stage Liquefaction of Coal - Wyoming (Wyodak) Coal Study", Hydrocarbon Research, Inc.. DE-60017-TOP-3. February 1986. "New Technology Concept for Two-Stage Liquefaction of Coal - Final Summary Report", Hydrocarbon Research, Inc., DE-60017-10, February 1986. "HRI's Catalytic Two-Stage Liquefaction Process - Performance Comparison For Illinois No. 6 and Wyodak Coals", McLean, J. E., A. G. Comolli, and J. 8. MacArthur. Presented at the American Chemical Society's Division of Petroleum Chemistry Symposium. September 1985. "The Catalytic Two-Stage Liquefaction Process", McLean, J. 8. A. G. Comolli, J. E. Duddy ?nd T. 0. Smith. Department of Energy's Direct Liquefaction Contractors Conference, November 1985. "Technical and Economic Impacts of Staged Liquefaction Configurations". Mitre Corporation. Contract No. 21-5262 (Final Report to be issued April 1986). "Recent Developments With The Lumus-Crest Integrated Two-Stage Liquefaction Process", M. Peluso. et al. Proceedings of 9th Annual EPRI Contractors' Conference on Coal Liquefaction, May 1984. "Process Studies of Integrated Two-Stage Liquefaction of Wilsonvi 1 le", M. J. Moniz, et al. Proceedings of 9th Annual EPRI Contractors' Conference on Coal Liquefaction. May 1984. 273
FIRST STAGE HRI'S CATALYTIC TWO STAGE LIQUEFACTION PROCESS "Low" Temperature ( 8OO0F) Hydroconversion Catalyst (e.9. Amocat 1A. CoMo) Functions: Complete Coal Conversion (Thenal in an improved solvent envirorment) Residuum Conversion to Distillate Products Heteroatom Removal Avoi d Dehy d r oge n at i on OTHER PROCESS FEATURES Reaction Stages are Oi rect-Coupled €bullated Bed Technology Scaleable Based on H-Coal@/H-Oil@ Experience Highest Conversion to Distillates of any Direct Liquefaction Process More Aliphatic/Petroleum-Like Products than other Direct Liquefaction Processes 2 74
Page 1 and 2:
ABSTRACT LIQUEFACTION CO-PROCESSING
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eaction temperature, 1000-1500 psig
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6. 7. 8. 9. 10. 11. 12. 13. 14. 15
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I 0" 100- I I I WyO-3 P 3: 1500 psi
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11.3 A-6 yJ 600 OF, 1500 psig CO, 3
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Experimental UDqradinq and Cooroces
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catalytic to the thermal hydrogenat
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the reaction with oil production re
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TET did not promote the production
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MICROAUTOCLAVE DESCRIPTION AND PROC
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FEEDSTOCK PROPERTIES Some propertie
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CONCLUSIONS HRI's microautoclave ha
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176
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100. 2 8%. M = ?8. 38. .... . . . .
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CATALYTIC CO-PROCESSINS OF OHIO NO.
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CATALYST COMPARISON STUDY The premi
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fractions and a decrease of heavier
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TABLE 2 Coal Analyses I1 1 i noi s
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Temperature WHSV, G/hr/cc TABLE 6 C
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z FIGURE 3 COAL REACTIVITY SCREENIN
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COPROCESSING USING HzS AS A PROMOTE
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- 3 - that product yields depend on
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- 5 - occurs in the yields of aspha
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Table 1 Analysis of Feedstocks Fore
Page 49 and 50:
THO-STAGE COPROCESSING OF SUBBITUMI
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esult in retrogressive reactions ta
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8. 6. Ignasiak, L. Lewkowicz, G. Ko
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Table 4 OVERALL MASS BALANCE FOR TH
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BACKGROUND COAL LIQUEFACTION/RESID
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system, which could be operated wit
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TABLE 1 EFFECT OF LC-FINING~"' TEMP
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Figure 1. SCHEMATIC OF LCI CO-PROCE
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SIMULATION OF A COAL/PETROLEuII RES
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20 pseudocomponents was developed t
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ottoms is less sensitive to the num
Page 71 and 72: Low Pressure Separator A temperatur
Page 73 and 74: 7. Gallier, P.W., Boston, J.F., Wu,
Page 75 and 76: I I I I I I I I I 100- --- Experime
Page 77 and 78: Coprocessing Schemes The coprocessi
Page 79 and 80: processing 25,000 and 150,000 bbl/d
Page 81 and 82: FIGURE 1 I DISTRIBUTION OF REFINERI
Page 83 and 84: Table 1. Samples Analyzed PNLNumber
Page 85 and 86: the coal itself. The chemical compo
Page 87 and 88: - - ITSL PAH Fraction PAH Fraction
Page 89 and 90: PROCESS DEVELOPMENT STUDIES OF TWO-
Page 91 and 92: SUMMARY e The major effect of close
Page 93 and 94: omw '??h 4NO WNID ?N? 000 wmm c9'1'
Page 95 and 96: tl f 246
Page 97 and 98: 248
Page 99 and 100: qkCqQ r! o! 0 0 0 0 0 0 0 I-UH ')I
Page 101 and 102: Materials The catalyst was shell 32
Page 103 and 104: CONCLUSIONS Separation of a light h
Page 105 and 106: Table 3. Results of activity testin
Page 107 and 108: feed coal and plant configuration a
Page 109 and 110: P1 #2 #3 114 115 #6 ITSL subbitumin
Page 111 and 112: temperature, time and solvent power
Page 113 and 114: TABLE 1 EXPERIMENTAL CONDITIONS AND
Page 115 and 116: la Figure 1. lH-NMR spectra of samp
Page 117 and 118: PERFORMANCE OF THE LOW TEMPERATURE
Page 119 and 120: BENCH UNIT DESCRIPTION Process deve
Page 121: Recycle Residuum Hydrogenati On Res
Page 125 and 126: FIRST-STAQ COAL CONVERSION (W I IIA
Page 127 and 128: REACTOR SOLIOS HTOROGEN/CARBON ATOl
Page 129 and 130: TRANSPORTATION FUELS FROM TWO-STAGE
Page 131 and 132: Process Identification LV% Of AS- R
Page 133 and 134: Table I11 HYDROTREATING TESTS WITH
Page 135 and 136: Table IV HYDROTREATING TO 0.2 PPM N
Page 137 and 138: Table VI EFFECT OF BOILING RANGE ON
Page 139 and 140: (4) In all cases studied, the jet f
Page 141 and 142: 292
Page 143 and 144: INTEGRATED TWO-STAGE LIQUEFACTION:
Page 145 and 146: are over-riding features in its fav
Page 147 and 148: Complementary fundamental studies o
Page 149 and 150: Comparative Economics of Two-Stage
Page 151 and 152: The variation in hydrotreating cost
Page 153 and 154: FIGURE 1: COMPARISONS OF ILLINOIS N
Page 155 and 156: Process TABLE 1: TWO-STAGE PROCESSE
Page 157 and 158: Abstract Temperature-Staged Catalyt
Page 159 and 160: Results and Discussion Reactions in
Page 161 and 162: 2. 3. 4. 5. 6. Derbyshire, F. J. an
Page 163 and 164: I LL a rJJW ., .. ;> 0 i s W 8 a 31
Page 165 and 166: Materials Feeds to the WGS-solvent
Page 167 and 168: products. Thus, coupling the WGS an
Page 169 and 170: 5. R. J. Xottenstette, Sandia Natio
Page 171 and 172: ENHANCED COAL LIQUEFACTION WITH STE
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change in weight being compared to
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I I aromatic ring. The group of sig
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T,\llI.l< I ASAI,YSIS OP \\YOl)Al\:
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00 3000 2000 le00 1600 1400 1200 IO
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THE EFFECT OF REACTION CONDITIONS O
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and may ultiontely form methyl-subs
Page 185 and 186:
! 5. Narain, N.K., Utz, B.R., Appel
Page 187:
4 (u I t + 9 (u I 337 - Q 0
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