Liquefaction co-processing of coal shale oil at - Argonne National ...

TABLE 1
EXPERIMENTAL CONDITIONS AND PRODUCT YIELDS
Conditions Yields, wt %
Experiment Feed O i l Acetone/ Dewaxed Mass
No. I.D. T, OC Oil, v/v Wax Oi 1 Balance
---
Urea Adduction Method
2 #1
Ketone Method
4 #1
5 #1
Room 5.0 88.8 93.8
-20 2.0 9.1 90.7 99.8
-50 3.3 20.6 79.3 99.9
14 #2 -50 3.0 47.4 52.0 99.4
7 #3 -20 3.0 14.5 83.2 97.7
13
9
#3(a)
#4
-50
-20
3.0
3.0
32.7
5.2
66.5
93.9
99.1
99.1
10
11
#4
#5
-50
-50
3.0
3.0
9.2
3.2
90.0
96.3
99.1
99.5
12
#6 -50 (C) 7.9 90.7 98.6
(a) Redistilled to 1000°F- immediately before experiment (98.3% distillate).
(b) Urea phod used, see Experimental section.
(c) 85OOF residual oil used as feed, see Experimental section.
Experiment
No.
2
4
5
14
7
13
TABLE 2
MICROAUTOCLAVE TEST RESULTS
Coal Conversion, wt % MAF Waxes
Feed Oil Dewaxed Oil -
80.9
80.9
80.9
84.9
87.1
88.2
70.8
80.1
87.1
83.7
55.1
-
79.2
55.7
55.7
63.3
86.2
55.4157.2
60.5
65.6
62.5
-
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