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Petroleum Systems of Deep-Water Basins - Gulf Coast Section SEPM

Petroleum Systems of Deep-Water Basins - Gulf Coast Section SEPM

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Sea Floor Vents, Seeps, and Gas Hydrate:<br />

Relation to Flux Rate from the<br />

<strong>Deep</strong> <strong>Gulf</strong> <strong>of</strong> Mexico <strong>Petroleum</strong> System<br />

Roger Sassen<br />

Geochemical and Environmental Research Group<br />

Texas A&M University<br />

College Station, Texas 77845<br />

Harry H. Roberts<br />

Department <strong>of</strong> Oceanography and <strong>Coast</strong>al Sciences<br />

Louisiana State University<br />

Baton Rouge, Louisiana 70803<br />

Alexei V. Milkov<br />

Debra A. DeFreitas<br />

Geochemical and Environmental Research Group<br />

Texas A&M University<br />

College Station, Texas 77845<br />

Abstract<br />

A deep, hot subsurface petroleum system in the Green Canyon area <strong>of</strong> the <strong>Gulf</strong> slope has generated oil and gas<br />

synchronously with salt deformation and fault activation, producing vertical migration conduits that charge traps in<br />

the subsurface. Trapping efficiency is poor. Much oil and gas is lost to venting and seepage at the sea floor. Sea floor<br />

vent and seep environments show hydrocarbon flux that ranges from rapid venting to slow seepage, affecting hydrocarbon<br />

geochemistry and gas hydrate abundance. Active mud volcanoes that vent oil and gas are the high flux endmember.<br />

Oil and gas rapidly bypass the sediment and enter the water column. The oil from the active vent sites shows<br />

only limited bacterial oxidation. Venting is episodic and may cease altogether, and warm brines may be present,<br />

potentially destabilizing gas hydrate. It appears that gas hydrate is only indirectly associated with high flux mud volcanoes.<br />

Massive gas hydrate is most <strong>of</strong>ten found at sites <strong>of</strong> moderate flux. Gas hydrate is associated with smaller but<br />

steady vents <strong>of</strong> relatively unaltered thermogenic gas, chemosynthetic communities, and authigenic carbonate rock.<br />

Oil-related structure II gas hydrate is most abundant. Oil and free gas in sediment are bacterially oxidized in moderate<br />

flux environments, leading to accumulation <strong>of</strong> abundant authigenic carbonate rock and to H 2 S, favoring complex<br />

chemosynthetic communities. Exposed gas hydrate is transiently unstable because <strong>of</strong> changes in seawater temperature,<br />

but this is a thin-skin process and more deeply buried gas hydrate appears to be stable and accumulating.<br />

Mineralized seep sites with low hydrocarbon flux do not appear to be important with respect to gas hydrate<br />

accumulation.<br />

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