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A Brief Review of Elasticity and Viscoelasticity for Solids 1 Introduction

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H. T. Banks, S. H. Hu <strong>and</strong> Z. R. Kenz / Adv. Appl. Math. Mech., 3 (2011), pp. 1-51 37<br />

3.2.4 Nonlinear viscoelasticity: constitutive relationships<br />

For many materials the linear models given in Section 3.2.3 are inadequate to describe<br />

experimental data. In particular, shape memory alloys such as Nitinol (a nickeltitanium)<br />

<strong>and</strong> CuZnAl (a cooper zinc aluminum aloy), biological s<strong>of</strong>t tissue <strong>and</strong> highly<br />

filled rubber exhibit significant nonlinear hysteric behavior such as that depicted by<br />

the experimental data <strong>for</strong> highly filled rubber given in Fig. 18. Nonlinear viscoelastic<br />

behavior is usually exhibited when the de<strong>for</strong>mation is large or if the material changes<br />

its properties under de<strong>for</strong>mations.<br />

Figure 18: Experimental stress-strain curves <strong>for</strong> (1) unfilled, (2) lightly filled <strong>and</strong> (3) highly filled rubber in<br />

tensile de<strong>for</strong>mations.<br />

The theory <strong>of</strong> nonlinear viscoelasticity has attracted the attention <strong>of</strong> a large number<br />

<strong>of</strong> investigators over the past century (e.g., [19, 20, 23, 25, 37, 42, 53, 58]). Two types<br />

<strong>of</strong> models <strong>for</strong> stress-strain relationships can be found in the literature. One is based<br />

on the phenomenological mechanical behavior <strong>of</strong> the materials (that is, the <strong>for</strong>m <strong>of</strong><br />

constitutive equations is not based on the explanation <strong>of</strong> how these properties arise<br />

from the underlying microscopic structure). For example, Green <strong>and</strong> Rivlin in [27]<br />

constructed a multiple integral constitutive equation, which is arranged as a series<br />

in which the nth term is <strong>of</strong> degree n in the strain components. A multiple integral<br />

constitutive equation, arranged in a series, was also developed by Pipkin <strong>and</strong> Rogers<br />

in [46], in which the first term gives the results <strong>of</strong> a one-step test (the stress due to<br />

a step change <strong>of</strong> strain), <strong>and</strong> whose nth term represents a correction due to the nth<br />

step. The interested reader can refer to [20,61] <strong>for</strong> recent historical overviews on these<br />

phenomenological models as well as the mathematical issues underlying the <strong>for</strong>mulations<br />

<strong>of</strong> these models. The other type <strong>of</strong> model entails <strong>for</strong>mulations based on the<br />

molecular mechanisms underlying the response. For example, in [19] Doi <strong>and</strong> Edwards<br />

developed a ”reptation” model <strong>for</strong> concentrated solutions <strong>and</strong> polymer melts<br />

which is based on the assumption that an entangled polymer molecule, the chain,

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