Improving Global Quality of Life
Improving Global Quality of Life
Improving Global Quality of Life
Create successful ePaper yourself
Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.
9.7.2 Welding in the minerals processing industry – Alumina case study<br />
General process description<br />
Alumina refining in general consists <strong>of</strong> the Bayer process, followed by calcination. In the Bayer process,<br />
caustic soda is used to dissolve (digest) the aluminium oxides and hydroxides in the bauxite ore at an elevated<br />
temperature <strong>of</strong> between 150 and 290 °C, the liquor is then separated from the sand and mud residue and<br />
precipitated, at reduced temperature <strong>of</strong> about 70 °C, as pure aluminium hydroxide. This is then calcined<br />
to convert the hydroxide to aluminium oxide, at a temperature <strong>of</strong> about 1,000 °C. A large number <strong>of</strong> heat<br />
exchangers are used to heat the liquor and slurry using both steam and process vapour, and to recover heat.<br />
General vessel description<br />
The alumina refining process uses a large number <strong>of</strong> holding tanks, thickeners and washers at atmospheric<br />
pressure, with tank diameters ranging up to 45 m. Precipitation tanks, also open to atmosphere, are typically<br />
30 m high by 12 m diameter. Digestion vessels, and flash vessels used to flash down to atmospheric pressure,<br />
can have design pressures <strong>of</strong> up to 5 MPa. Heat exchangers typically operate at similar pressures.<br />
The materials <strong>of</strong> construction for most tanks, vessels and pipes are various grades <strong>of</strong> mild steel, except for<br />
the calcination plant where high nickel superalloys are used, and the acid cleaning system (used to remove<br />
sodalite scale from heat exchanger tubes) which is made from different grades <strong>of</strong> stainless steel. Vessel wall<br />
thicknesses are usually 20 mm or less, but can range up to 40 mm at the bottom <strong>of</strong> high tanks.<br />
Common welding procedures employed<br />
Mild steel tanks, vessels and pipe spools are fabricated using conventional welding techniques and procedures.<br />
There are no special requirements apart from compliance with the normal quality and equipment codes,<br />
such as those for pressure vessels, piping, and tankage. There is one exception that post weld stress relief is<br />
required to guard against caustic embrittlement, a form <strong>of</strong> stress corrosion cracking, which can occur under<br />
certain process conditions.<br />
Repair welding on site is usually done with MMAW and GMAW. There is also considerable interest in<br />
productivity improvement techniques that could be employed to reduce turnaround time in vessel and tank<br />
repair, eg FCAW. Some bauxite ore bodies contain large amounts <strong>of</strong> quartz, rendering the process slurries<br />
highly abrasive. In these cases there is a need for selective hardfacing <strong>of</strong> some process equipment, and it is<br />
common practice to use hardfacing consumable category 2560 for these. Tungsten carbide in a NiSiB matrix<br />
(with or without Cr) is also used.<br />
Issues, Needs and Challenges<br />
With regard to caustic embrittlement, there are issues with the quality <strong>of</strong> field thermal stress relief, and with<br />
the logistics as the codes prohibit the use <strong>of</strong> spot stress relief. If reliable alternative stress relief methods<br />
were available, they would find application. There are issues if welding in the presence <strong>of</strong> caustic residue, as<br />
this leads to cracking. There is a general interest in low stress welding procedures in the industry. As more<br />
duplex stainless steels are becoming commercially viable, such as 2906, 2003 and 2101, there will be a need<br />
for robust welding procedures for these alloys as there is potential application for these alloys in the alumina<br />
industry due to their resistance to caustic. There are occasional issues with preferential weld corrosion.<br />
122 <strong>Improving</strong> <strong>Global</strong> <strong>Quality</strong> <strong>of</strong> <strong>Life</strong> Through Optimum Use and Innovation <strong>of</strong> Welding and Joining Technologies