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IEA Solar Heating and Cooling Programm - NachhaltigWirtschaften.at

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<strong>IEA</strong> SHC Task 38 <strong>Solar</strong> Air Conditioning <strong>and</strong> Refriger<strong>at</strong>ion Subtask C2-A, November 9, 2009<br />

As st<strong>at</strong>ed in equ<strong>at</strong>ion (14) above, the mass flow of weak solution is set constant. In equ<strong>at</strong>ion<br />

(12) it is assumed th<strong>at</strong> the mass flow entering the absorber tube bundle <strong>at</strong> time interval i<br />

equals the mass flow which has left the gener<strong>at</strong>or c 1 time intervals ago. Doing so, the<br />

physical incompressibility of the solution in the piping between gener<strong>at</strong>or <strong>and</strong> absorber is not<br />

modelled correctly. In reality, the mass flow entering the tube <strong>at</strong> time interval i should equal<br />

the mass flow leaving the tube <strong>at</strong> time interval i. The assumption, however, had to be made<br />

in order to achieve a correct salt balance in equ<strong>at</strong>ion (22). The result is a hidden mass<br />

storage term in the solution tube. However, the amount of stored solution in the tube is only<br />

0.6 % of the total amount of stored solution in the sumps [3]. The error introduced by this<br />

assumption is therefore negligible.<br />

Mass balances<br />

The vessel sumps (see Figure 2) are assumed to be fully mixed <strong>at</strong> each time interval. Thus<br />

vessel sump <strong>and</strong> solution leaving the vessel are assumed to have the same salt<br />

concentr<strong>at</strong>ion, x sA,i <strong>and</strong> x wG,i , respectively. The outlet of each tube bundle is assumed to<br />

exhibit the equilibrium concentr<strong>at</strong>ion x sG,i <strong>and</strong> x wA,i . The total solution mass stored in<br />

gener<strong>at</strong>or <strong>and</strong> absorber sump <strong>at</strong> time i is expressed by<br />

M<br />

sol st,<br />

G,<br />

i<br />

M<br />

,<br />

,<br />

<strong>and</strong><br />

sol, st,<br />

A i<br />

, respectively.<br />

We know th<strong>at</strong> the total mass (or salt mass, respectively) in the sump <strong>at</strong> time interval i equals<br />

the total mass (or salt mass) <strong>at</strong> time interval (i-1) plus the difference of ingoing <strong>and</strong> outgoing<br />

solution (or salt) flows <strong>at</strong> time interval i. The balances for the total solution contents in the<br />

sumps are given in equ<strong>at</strong>ions (15) <strong>and</strong> (16).<br />

∆ t is the time between two simul<strong>at</strong>ion intervals.<br />

M<br />

sol,<br />

, G,<br />

i<br />

− M<br />

sol,<br />

, G,<br />

i−1<br />

Gener<strong>at</strong>or: m& , , ,<br />

− m&<br />

, ,<br />

−<br />

st<br />

st<br />

sol tb G i sol sG i<br />

= 0<br />

(15)<br />

∆t<br />

M<br />

sol,<br />

st,<br />

A,<br />

i<br />

− M<br />

sol,<br />

st,<br />

A,<br />

i−1<br />

Absorber: m& , , ,<br />

− m&<br />

sol tb A i sol,<br />

wA,<br />

i<br />

−<br />

= 0<br />

(16)<br />

∆t<br />

The fraction term in equ<strong>at</strong>ions (15 <strong>and</strong> 16) is the amount of solution which is added to the<br />

solution stored in either gener<strong>at</strong>or or absorber sump during the time<br />

simul<strong>at</strong>ion intervals i <strong>and</strong> (i-1).<br />

∆ t between consecutive<br />

The salt flow balance, analogously, in both sumps can be written as:<br />

Gener<strong>at</strong>or<br />

M<br />

sol,<br />

, G,<br />

i<br />

⋅ xsA,<br />

i<br />

− M<br />

sol,<br />

, G,<br />

i−1<br />

⋅ xsA,<br />

i−1<br />

m& , , ,<br />

⋅ x<br />

,<br />

− m&<br />

, ,<br />

⋅ x<br />

,<br />

−<br />

st<br />

st<br />

= 0 (17<br />

sol tb G i sG i sol sG i sA i<br />

∆t<br />

:<br />

)<br />

Absorber<br />

:<br />

M<br />

sol,<br />

st,<br />

A,<br />

i<br />

⋅ xwG<br />

, i<br />

− M<br />

sol,<br />

st,<br />

A,<br />

i−1<br />

⋅ xwG<br />

, i−1<br />

m& , , ,<br />

⋅ x<br />

,<br />

− m&<br />

sol tb A i wA i sol,<br />

wA,<br />

i<br />

⋅ xwG<br />

, i<br />

−<br />

= 0 (18<br />

∆t<br />

)<br />

page 68

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