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IEA Solar Heating and Cooling Programm - NachhaltigWirtschaften.at

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<strong>IEA</strong> SHC Task 38 <strong>Solar</strong> Air Conditioning <strong>and</strong> Refriger<strong>at</strong>ion Subtask C1 Report, 31 October 2010<br />

Lowenstein [86] presented the applic<strong>at</strong>ions of LDS coupled with cooling processes th<strong>at</strong> can<br />

be used for:<br />

● comfort air-conditioning in offices, public <strong>and</strong> residential buildings<br />

● warehouses <strong>and</strong> production halls for preserv<strong>at</strong>ion <strong>and</strong> archiving purposes<br />

● condens<strong>at</strong>ion protection to prevent mould <strong>and</strong> rust destruction from equipment<br />

● production processes e.g. in the food production, pharmaceutical production, semiconductor<br />

production, rubber industry, confectioneries.<br />

The air stream from the absorber can be used directly for:<br />

● high efficiency he<strong>at</strong> recovery <strong>and</strong> indirect air he<strong>at</strong>ing in low energy buildings, Kerskes [92]<br />

● low temper<strong>at</strong>ure drying of agricultural goods <strong>and</strong> industrial products (“gentle drying”), Rane<br />

[93]<br />

● high efficiency he<strong>at</strong> recovery <strong>and</strong> humidity control for indoor swimming pools <strong>and</strong><br />

greenhouses, Waldenmaier [94].<br />

4.4 Technology st<strong>at</strong>us<br />

In the last years, significant progress has been made in the basic components of desiccant<br />

technology. These include:<br />

4.4.1 Desiccant m<strong>at</strong>erials<br />

The behaviour of all desiccant system components is profoundly influenced by the oper<strong>at</strong>ing<br />

characteristics of the desiccant m<strong>at</strong>erials they contain. Recognizing this fact, research<br />

institutions <strong>and</strong> manufacturers have focused on m<strong>at</strong>erial science to develop desiccants which<br />

are especially suited to air-conditioning applic<strong>at</strong>ions.<br />

These efforts have had two primary goals; to develop desiccants which:<br />

1. Use less energy for reactiv<strong>at</strong>ion <strong>and</strong> therefore need less energy for cooling<br />

2. Are more stable <strong>and</strong> fault-tolerant <strong>and</strong> therefore require less maintenance<br />

Al-Farayedhi et al. [95] listed several important consider<strong>at</strong>ions in choosing or designing the<br />

optimal liquid desiccant solution for a dehumidific<strong>at</strong>ion applic<strong>at</strong>ion:<br />

• High vapor pressure of w<strong>at</strong>er in solution<br />

• Low vapor pressure of solute<br />

• Performance of solution steady over large concentr<strong>at</strong>ion range<br />

• Non-corrosive <strong>and</strong> chemically stable<br />

• Low viscosity<br />

• High solubility<br />

• Low regener<strong>at</strong>ion temper<strong>at</strong>ure<br />

• Non-toxic, harmless<br />

• Low cost<br />

Lithium chloride (LiCl), Calcium Chloride (CaCl2), Lithium Bromide (LiBr), <strong>and</strong> tri-ethylene<br />

glycol (TEG) are common liquid desiccant m<strong>at</strong>erials meeting the above performance<br />

characteristics to varying degrees. LiCl <strong>and</strong> CaCl2 domin<strong>at</strong>e the most recent research efforts<br />

into liquid desiccant dehumidific<strong>at</strong>ion systems. Wimby <strong>and</strong> Berntsson [96] investig<strong>at</strong>ed<br />

aqueous solutions of various desiccants, including LiCl <strong>and</strong> CaCl2, producing experimental<br />

d<strong>at</strong>a of density as a function of temper<strong>at</strong>ure <strong>and</strong> mass fraction. This d<strong>at</strong>a is of critical<br />

importance when experimenting with liquid desiccant m<strong>at</strong>erials, providing concentr<strong>at</strong>ion as a<br />

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