Acros Organics & Maybridge - D
Acros Organics & Maybridge - D
Acros Organics & Maybridge - D
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Diethyl 1,3-acetonedicarboxylate, 95%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
325630500 Glass bottle 50 ml INR 1,190<br />
325632500 Glass bottle 250 ml INR 5,380<br />
S24/25<br />
Moisture sensitive<br />
Store below +4ºC<br />
C9H14O5 CAS: 105-50-0<br />
MFCD00009200<br />
FW: 202.21<br />
C 2 H 5 O 2 CCH 2 COCH 2 CO 2 C 2 H 5<br />
bp: 250 °C<br />
Fp: 86 °C<br />
d: 1.112<br />
Diethyl acetylenedicarboxylate, 97%<br />
n 20<br />
D : 1.438 -1.442<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
296350250 Glass bottle 25 g INR 1,570<br />
296351000 Glass bottle 100 g INR 5,940<br />
R34<br />
S25 S36/37/39 S45<br />
Lachrymator<br />
Light sensitive<br />
Store below +4ºC<br />
C8H10O4 CAS: 762-21-0<br />
MFCD00009186<br />
FW: 170.17<br />
mp: 1-3 °C<br />
bp: 107-110 °C (11<br />
mmHg)<br />
Fp: 94 °C<br />
d: 1.060<br />
n20 D : 1.441 -1.443<br />
Diethyl acetylsuccinate, 99%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
113950250 Glass bottle 25 g INR 3,750<br />
113951000 Glass bottle 100 g INR 11,700<br />
113955000 Glass bottle 500 g INR 46,190<br />
S24/25 C 10 H 16 O 5 C 2 H 5 O 2 CCH 2 CH(COCH 3 )CO 2 C 2 H 5<br />
CAS: 1115-30-6<br />
MFCD00009157<br />
FW: 216.23<br />
Diethyl adipate, 99%<br />
mp: -8 °C<br />
bp: 180-183 °C (50<br />
mmHg)<br />
Fp: >112 °C<br />
d: 1.080<br />
n 20<br />
D : 1.434 -1.436<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
407171000 Glass bottle 100 g INR 730<br />
407175000 Glass bottle 500 g INR 1,430<br />
S24/25 C 10 H 18 O 4 CH 3 CH 2 OCO(CH 2 ) 4 COOCH 3 CH 2<br />
CAS: 141-28-6<br />
MFCD00009215<br />
FW: 202.25<br />
mp: -18 °C<br />
bp: 132 °C (15 mm Hg)<br />
Fp: >110 °C<br />
O O<br />
d: 1.000<br />
n 20<br />
D : 1.426 -1.428<br />
Diethyl allylmalonate<br />
APPLICATION GUIDE<br />
Protecting Group Chemistry<br />
Used as a protected form of diethyl malonate - only one alkylation can occur at the active methine.<br />
JOC 1996, 61, 2266<br />
O<br />
O<br />
http://www.acros.com Diethylaceto<br />
Diethyl allylmalonate, 97%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
113960050 Glass bottle 5 g INR 550<br />
113961000 Glass bottle 100 g INR 5,160<br />
113965000 Glass bottle 500 g INR 22,310<br />
R36/37/38<br />
S26 S37/39<br />
C10H16O4 CAS: 2049-80-1<br />
MFCD00009155<br />
FW: 200.23<br />
Diethyl allylphosphonate, 97%<br />
C 2 H 5 O 2 CCH(CH 2 CH=CH 2 )CO 2 C 2 H 5<br />
bp: 222-223 °C<br />
Fp: 92 °C<br />
d: 1.010<br />
n 20<br />
D : 1.43 -1.432<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
336110050 Glass bottle 5 g INR 3,780<br />
336110250 Glass bottle 25 g INR 14,920<br />
S24/25 C 7 H 15 O 3 P (O)P(CH 3 CH 2 O) 2 CH 2 CHCH 2<br />
CAS: 1067-87-4<br />
MFCD00015134<br />
FW: 178.17<br />
bp: 97 °C<br />
n 20<br />
D : 1.4325 -1.4345<br />
Diethylaluminium chloride, 1M solution in hexanes<br />
APPLICATION GUIDE<br />
Asymmetric synthesis<br />
* Michael Addition High level of asymmetric induction in the conjugate addition of an ethyl group. S<br />
1993, 1018<br />
Lewis acid catalysts<br />
* Diels Alder Cycloaddition Catalyses Diels Alder reactions that use aldehydes as dienophiles. JACS<br />
1989, 111, 4368<br />
* Diels Alder Cycloaddition Catalyses inverse electron demand Diels Alder reactions. JACS 1987,<br />
109, 921<br />
* Diels Alder Cycloaddition To catalyse intermolecular Diels-Alder reactions. JOC 1983, 48, 407<br />
* Diels Alder Cycloaddition To catalyse intramolecular Diels-Alder reactions. JACS 1986, 108, 7791<br />
* Ene Reactions Catalyses Ene reactions of aldehydes. JOC 1985, 50, 4144<br />
* Ene Reactions Catalyses intramolecular Ene reactions of ,-unsaturated esters. T 1984, 40, 1391<br />
Rearrangements<br />
* Claisen Catalyses Claisen rearrangement of aryl allyl ethers. JOC 1983, 48, 2709<br />
Diethylaluminium chloride<br />
1M solution in hexanes, AcroSeal®<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
199521000 AcroSeal 100 ml INR 6,600<br />
199528000 AcroSeal 800 ml INR 24,940<br />
R11 R14/15 R34<br />
R48/20 R51/53 R62<br />
R65 R67<br />
S2 S8 S9 S16 S26<br />
S29 S33 S36/37/39<br />
S43B S45 S61 S62<br />
Moisture sensitive<br />
Air sensitive<br />
C 4 H 10 AlCl (C 2 H 5 ) 2 AICl<br />
CAS: 96-10-6<br />
MFCD00000459<br />
FW: 120.56<br />
Fp: -22 °C<br />
d: 0.711<br />
Please enquire for bulk quantities 773<br />
D
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