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Acros Organics & Maybridge - D

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D<br />

Dimethylamin http://www.maybridge.com<br />

3-Dimethylaminopropylchloride hydrochloride, 99%<br />

<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />

115911000 Glass bottle 100 g INR 710<br />

115915000 Glass bottle 500 g INR 2,830<br />

R22 R36/37/38 R52/<br />

53<br />

S26 S37/39 S61<br />

Hygroscopic<br />

C 5 H 12 ClN.HCl (CH 3 ) 2 N(CH 2 ) 3 Cl.HCl<br />

CAS: 5407-04-5<br />

MFCD00012521<br />

FW: 158.07<br />

mp: 139-145 °C<br />

1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride<br />

APPLICATION GUIDE<br />

Coupling Chemistry<br />

* Coupling agent Amide formation. S 1979, 709<br />

* Coupling agent Ester formation. JOC 1982, 47, 1962<br />

* Coupling agent Peptide coupling. JACS 1973, 95, 875<br />

1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride<br />

, 98+%<br />

<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />

171440010 Glass bottle 1 g INR 1,430<br />

171440100 Glass bottle 10 g INR 6,850<br />

171440500 Glass bottle 50 g INR 21,880<br />

171441000 Glass bottle 100 g INR 41,660<br />

171445000 Glass bottle 500 g INR 145,870<br />

R20/21/22 R37/38<br />

R41<br />

S26 S36/37/39<br />

Moisture sensitive<br />

Store below -20ºC<br />

C 8 H 17 N 3 .HCl (CH 3 ) 2 NCH 2 CH 2 CH 2 N=C=NCH 2 CH 3<br />

CAS: 25952-53-8<br />

MFCD00012503<br />

FW: 191.71<br />

mp: 111-116 °C<br />

1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide methiodide<br />

APPLICATION GUIDE<br />

Coupling Chemistry<br />

* Coupling agent Alternative form of EDCI (hydrochloride) used for amide formation. S 1979, 709<br />

* Coupling agent Alternative form of EDCI (hydrochloride) used for ester formation. JOC 1982, 47,<br />

1962<br />

* Coupling agent Alternative form of EDCI (hydrochloride) used for peptide coupling. JACS 1973, 95,<br />

875<br />

1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide methiodide<br />

, 98%<br />

<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />

334120010 Glass bottle 1 g INR 1,500<br />

334120100 Glass bottle 10 g INR 7,310<br />

R20/21/22 R36/37/<br />

38<br />

S26 S36/37/39<br />

C 9 H 20 IN 3<br />

CAS: 22572-40-3<br />

MFCD00011833<br />

FW: 297.18<br />

mp: 92-97 °C<br />

1-(3-Dimethylaminopropyl)piperazine, 97%<br />

<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />

391070010 Glass bottle 1 g INR 1,450<br />

391070050 Glass bottle 5 g INR 4,160<br />

R21 R34<br />

S26 S36/37/39 S45<br />

C9H21N3 CAS: 877-96-3<br />

FW: 171.29<br />

d: 0.917<br />

n 20<br />

D : 1.477 -1.479<br />

HNN 858 Please enquire for bulk quantities<br />

N<br />

1-Dimethylamino-2-propyne, 97%<br />

<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />

162250050 Glass bottle 5 g INR 750<br />

R11 R34<br />

S16 S26 S36/37/39<br />

S45<br />

Store below +4ºC<br />

C 5 H 9 N HCCCH 2 N(CH 3 ) 2<br />

CAS: 7223-38-3<br />

MFCD00008575<br />

FW: 83.13<br />

bp: 80-81 °C<br />

Fp: -7 °C<br />

d: 0.772<br />

n 20<br />

D : 1.419 -1.422<br />

4-[3-(Dimethylamino)prop-1-ynyl]benzaldehyde oxime, 97%<br />

<strong>Maybridge</strong> Product code Packaging Pack size Price<br />

MO08250DA Glass bottle 1 g INR 9,000<br />

MO08250EA Glass bottle 10 g INR 47,600<br />

R20/21/22 R34<br />

S22 S26 S36/37/39<br />

S45<br />

C12H14N2O CAS: 209919-81-3<br />

MFCD00210152<br />

FW: 202.26<br />

mp: 130.5-132 °C<br />

N,N-Dimethyl-9H-purin-6-amine, 97%<br />

<strong>Maybridge</strong> Product code Packaging Pack size Price<br />

AC22646CB Glass bottle 250 mg INR 7,000<br />

AC22646DA Glass bottle 1 g INR 16,700<br />

S24/25 C 7 H 9 N 5<br />

CAS: 938-55-6<br />

MFCD00079113<br />

FW: 163.18<br />

mp: 258-263 °C<br />

N OH<br />

4-Dimethylaminopyridine<br />

APPLICATION GUIDE<br />

Acylation<br />

* N-Acylation DMAP catalyses the acylation of amines. DOK 1969, 244, 1125<br />

* O-Acylation Catalysis of the acylation of alcohols. CSR 1983, 12, 129<br />

Interconversion of functional groups<br />

* Carboxylic acid to ester One pot formation of ester employing DCC and DMAP. AG(E) 1978, 17, 522<br />

Protecting Group Chemistry<br />

* Protection of alcohols Silylation of alcohols proceeds readily in presence of DMAP. TL 1979, 3811<br />

* Protection of amides Catalyst in the BOC protection of amides. JOC 1983, 48, 2424<br />

Reduction<br />

* a-amino acids into a-amino ketones Dakin-West Reaction occurs at RT when catalysed by DMAP.<br />

CSR 1988, 17, 91<br />

* dealkoxycarbonylation Decarboxylation of -keto ester using 1 eq. of DMAP in aqueous toluene.<br />

JOC 1989, 54, 3474<br />

N<br />

N<br />

N<br />

N<br />

N<br />

H<br />

N

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